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Cathode materials advance in solid oxide fuel cells  

Son, Young-Mok (KISTI ReSEAT Program)
Cho, Mann (KISTI ReSEAT Program)
Nah, Do-Baek (KISTIInformation AnalysisDept)
Kil, Sang-Cheol (KISTIInformation AnalysisDept)
Kim, Sang-Woo (KISTIInformation AnalysisDept)
Publication Information
Journal of Energy Engineering / v.19, no.2, 2010 , pp. 73-80 More about this Journal
Abstract
A solid oxide fuel cells(SOFC) is a clean energy technology which directly converts chemical energy to electric energy. When the SOFC is used in cogeneration then the efficiency can reach higher than 80%. Also, it has flexibility in using various fuels like natural gases and bio gases, so it has an advantage over polymer electrolyte membrane fuel cells in terms of fuel selection. A typical cathode material of the SOFC in conjunction with yttria stabilized zirconia(YSZ) electrolyte is still Sr-doped $LaMnO_3$(LSM). Recently, application of mixed electronic and ionic conducting perovskites such as Sr-doped $LaCoO_3$(LSCo), $LaFeO_3$(LSF), and $LaFe_{0.8}Co_{0.2}O_3$(LSCF) has drawn much attention because these materials exhibit lower electrode impedance than LSM. However, chemical reaction occurs at the manufacturing temperature of the cathode when these materials directly contact with YSZ. In addition, thermal expansion coefficient(TEC) mismatch with YSZ is also a significant issue. It is important, therefore, to develop cathode materials with good chemical stability and matched TEC with the SOFC electrolyte, as well as with high electrochemical activity.
Keywords
Solid oxide fuel cell; cathode; perovskite; LSM; ferrite; cobaltite;
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