• Title/Summary/Keyword: Thermal Equilibrium

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Characteristics of Chlorinated VOCs Adsorption over Thermally Treated Silica Gel (열처리 실리카겔의 염소계 휘발성 유기화합물 흡착특성 연구)

  • Nam, Kyung Soo;Kwon, Sang Soog;Yoo, Kyung Seun
    • Applied Chemistry for Engineering
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    • v.18 no.3
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    • pp.245-250
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    • 2007
  • Adsorption characteristics of 1,2-dichlorobenzene on the surface of heat treated silica gel were determined by the moment analysis. The heat treatment of the silica gel was performed at temperatures of 150, 500, and $800^{\circ}C$ and pulse-response of 1,2-dichlorobenzene was measured in a gas chromatograph equipped with thermal conductivity detector (TCD) using the packed column. Equilibrium adsorption constants and isosteric heat of adsorption were recorded the highest value at $500^{\circ}C$. This might be due to the increase of interaction between silica surface and 1,2-dichlorobenzene as the decrease of OH concentration and moisture by increase of heating temperature. Axial dispersion coefficient calculated by the moment method was about $0.046{\times}10^{-4}{\sim}1.033{\times}10^{-4}m^2/sec$ and pore diffusivity of heat treated silica gel at $500^{\circ}C$ measured the lowest value. Because heat treating at $800^{\circ}C$ caused the specific surface area to reduce, equilibrium adsorption constants and isosteric heat of adsorption were decreased.

A Comparative Study on the Windchill Indices (체감온도이론의 비교 연구)

  • Park, Jeon-Hwan;Han, Uk;Park, Rae-Seol
    • Journal of the Korean earth science society
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    • v.23 no.8
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    • pp.676-682
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    • 2002
  • The concept of sensible temperature in winter is an attempt to quantify the sensation of cold by dry-bulb temperature combined with wind speed. Siple-Passel’s windchill equivalent temperature originated in experiments that are not conformable to various human conditions. Therefore, many investigators have found the flaws which are listed. Steadman’s model is based on the concept of thermal equilibrium and more sound and more representative of human conditions. But no classifications exist for Steadman’s windchill equivalent temperature, yet. The JAG/TI-model which was developed by US and Canada is more accurate, easy to understand and reflects human beings by conducting experiments using human volunteers but didn't take into account solar radiation, wet condition and physical state of the individual. Because of individual differences in people’s age, activity, health, metabolic rate, etc., no experimental evidence exists to suggest whether Siple-Passel’s, Steadman’s and JAG/TI-model’s windchill equivalent temperature is more applicable to the majority of people. Therefore we need the windchill model which is best applicable to Korean Army.

Study of the Kinetic Effects on Relativistic Unmagnetized Shocks using 3D PIC Simulations

  • Choi, Eun Jin;Min, Kyoung W.;Choi, Cheongrim;Nishikawa, Ken-Ichi
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.101.2-101.2
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    • 2012
  • Shocks are ubiquitous in astrophysical plasmas: bow shocks are formed by the interaction of solar wind with planetary magnetic fields, and supernova explosions and jets produce shocks in interstellar and intergalactic spaces. The global morphologies of these shocks are usually described by a set of magnetohydrodynamic (MHD) equations which tacitly assumes local thermal equilibrium, and the resulting Rankine-Hugoniot shock jump conditions are applied to obtain the relationship between the upstream and downstream physical quantities. While thermal equilibrium can be achieved easily in collisional fluids, it is generally believed that collisions are infrequent in astrophysical settings. In fact, shock widths are much smaller than collisional mean free paths and a variety of kinetic phenomena are seen at the shock fronts according to in situ observations of planetary shocks. Hence, both the MHD and kinetic equations have been adopted in theoretical and numerical studies to describe different aspects of the physical phenomena associated with astrophysical shocks. In this paper, we present the results of 3D relativistic particle-in-cell (PIC) simulations for ion-electron plasmas, with focus on the shock structures: when a jet propagates into an unmagnetized ambient plasma, a shock forms in the nonlinear stage of the Weibel instability. As the shock shows the structures that resemble those predicted in MHD systems, we compare the results with those predicted in the MHD shocks. We also discuss the thermalization processes of the upstream flows based on the time evolutions of the phase space and the velocity distribution, as well as the wave spectra analyses.

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A Study on Effect of Various Cooling Methods in Motion of High-Precision Ball Screw (고속 고정밀 볼 스크류 구동에 따른 강제 냉각방식의 효과에 관한 연구)

  • Kim, Su-Sang;Xu, Zhe-Zhu;Kim, Hyun-Koo;Lyu, Sung-Ki
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.3
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    • pp.254-259
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    • 2013
  • Ball screw system is widely used as a precision mechanical linear actuator that translates rotational motion to linear motion for its high efficiency, great stiffness and long life. Recently, according to the requirements of high accuracy and stiffness, the pre-load on the ball screw which means of remove the backlash in the ball screw is usually used. Because of the preload which means the frictional resistance between the screw and nut, becomes a dominating heat source and it generates thermal deformation of ball screw which is the reason for low accuracy of the positioning decision. There are several methods to solve the problem that includes temperature control, thermal stable design and error compensation. In the past years, researchers focused on the error compensation technique for its ability to correct ball screw error effectively rather than the capabilities of careful machine design and manufacturing. Significant amounts of researches have been done to real-time error compensation. But in this paper, we developed a series of cooling methods to get thermal equilibrium in the ball screw system. So we find the optimum cooling type for improving positioning error which caused by thermal deformation in the ball screw system.

Decomposition of Chlorinated Methane by Thermal Plasma (열플라즈마에 의한 클로로메탄의 분해)

  • Kim, Zhen Shu;Park, Dong Wha
    • Applied Chemistry for Engineering
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    • v.18 no.2
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    • pp.136-141
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    • 2007
  • The decomposition of chlorinated methanes including $CCl_4$, $CCl_3H$, and $CCl_2H_2$ was carried out using a thermal plasma process and the characteristics of the process were investigated. The thermal equilibrium composition was analyzed with temperature by Fcatsage program. The decomposition rates at various process parameters including the concentration of reactants, flow rate of carrier gas, and quenching rate, were evaluated, where sufficiently high conversion over 92% was achieved. The generation of main products was strongly influenced by the reaction atmosphere; carbon, chlorine, and hydrogen chloride at neutral condition; carbon dioxide, chlorine, and hydrogen chloride at oxidative condition. The decomposition mechanism was speculated considering the results from Factsage and the identification of generated radicals and ionic species. The main decomposition pathways were found to be dissociative electron attachment and oxidative by radicals formed in a plasma state.

Analysis on Thermomechanical Response to Tensile Deformation of GaN Nanowires (GaN 나노와이어의 인장 변형에 의한 열기계적 거동 해석)

  • Jung, Kwangsub;Zhou, Min;Cho, Maenghyo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.25 no.4
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    • pp.301-305
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    • 2012
  • In this work the mechanical behaviors of GaN nanowires are analyzed during tension, compression, and unloading deformations. The thermal conductivity of the nanowires at each deformed state is evaluated using an equilibrium Green-Kubo approach. Under tensile loading, the [0001]-oriented nanowires with hexagonal cross-sections undergo a phase transformation from wurtzite to a tetragonal structure. The phase transformation is not observed under compressive loading. The thermal conductivity decreases on going from compressive strains to tensile strains. The strain dependence of the thermal conductivity results from the relaxation time of phonon. A reverse transformation from the tetragonal structure to the wurtzite structure is observed during unloading. The thermal conductivities in the intermediate states are lower than the conductivity in the wurtzite structure at same strain. Such differences in the thermal conductivity between different atomic structures are mainly due to changes in the group velocity of phonon.

Determination of hey Fuel Ratio According to Fuel Composition (IV) - Overall Estimation of Methods- (연료 조성에 따른 공연비 산정 (IV) - 공연비 계산방식의 평가-)

  • Park Chanjun;Ohm Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.10
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    • pp.1155-1162
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    • 2004
  • This paper is the forth paper of several companion papers which compare the method of Air-Fuel ratio determination. In the previous work, various AFR calculations were performed for various fuels and the results were compared with each other. The comparison, however, were limited to numerical value and estimation of each equation or method was insufficient. In this paper, the overall estimation of the methods was attempted. Also, the method of trouble shooting of instrumentation was presented. Through the estimation of methods, it is concluded that the Eltinge method contains inherently the most perfect thermal dissociation model as far as the exhaust composition is concerned; therefore, this might be regarded as the most general equation of AFR determination among the existing ones. The others might be considered as approximate form. In addition, the mal-distribution factor in Eltinge method is qualitatively equivalent to thermal dissociation chemical equilibrium constant K. Lastly, it is illustrated that all instrumentation error, including the sampling line leakage, can be easily detected through the analyzing the exhaust component on the Eltinge chart.

Mathematical Modeling of Combustion Characteristics in HVOF Thermal Spray Processes(I): Chemical Composition of Combustion Products and Adiabatic Flame Temperature (HVOF 열용사 프로세스에서의 연소특성에 관한 수학적 모델링(I): 연소생성물의 화학조성 및 단열화염온도)

  • Yang, Young-Myung;Kim, Ho-Yeon
    • Journal of the Korean Society of Combustion
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    • v.3 no.1
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    • pp.21-29
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    • 1998
  • Mathematical modeling of combustion characteristics in HVOF thermal spray processes was carried out on the basis of equilibrium chemistry. The main objective of this work was the development of a computation code which allows to determine chemical composition of combustion products, adiabatic flame temperature, thermodynamic and transport properties. The free energy minimization method was employed with the descent Newton-Raphson technique for numerical solution of systems of nonlinear thermochemical equations. Adiabatic flame temperature was calculated by using a Newton#s iterative method incorporating the computation module of chemical composition. The performance of this code was verified by comparing computational results with data obtained by ChemKin code and in the literature. Comparisons between the calculated and measured flame temperatures showed a deviation less than 2%. It was observed that adiabatic flame temperature augments with increase in combustion pressure; the influence was significant in the region of low pressure but becomes weaker and weaker with increase in pressure. Relationships of adiabatic flame temperature, dissociation ratio and combustion pressure were also analyzed.

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Magneto-thermo-elastic response of a rotating functionally graded cylinder

  • Hosseini, Mohammad;Dini, Ali
    • Structural Engineering and Mechanics
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    • v.56 no.1
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    • pp.137-156
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    • 2015
  • In this paper, an analytical solution of displacement, strain and stress field for rotating thick-walled cylinder made of functionally graded material subjected to the uniform external magnetic field and thermal field in plane strain state has been studied. Stress, strain and displacement field as a function of radial coordinates considering magneto-thermo-elasticity are derived analytically. According to the Maxwell electro-dynamic equations, Lorentz force in term of displacement is obtained in cylindrical coordinates. Also, symmetric temperature distribution along the thickness of hollow cylinder is obtained by solving Fourier heat transfer equation in cylindrical coordinates. Using equation of equilibrium and thermo-mechanical constitutive equations associated with Lorentz force, a second-order inhomogeneous differential equation in term of displacement is obtained and will be solved analytically. Except Poisson's ratio, other mechanical properties such as elasticity modulus, density, magnetic permeability coefficient, heat conduction coefficient and thermal expansion coefficient are assumed to vary through the thickness according to a power law. In results analysis, non-homogeneity parameter has been chosen arbitrary and inner and outer surface of cylinder are assumed to be rich metal and rich ceramic, respectively. The effect of rotation, thermal, magnetic field and non-homogeneity parameter of functionally graded material which indicates percentages of cylinder's constituents are studied on displacement, Von Mises equivalent stress and Von Mises equivalent strain fields.

Thermal Stability of Nanostructured Synthetic Ferrimagnets under Applied Magnetic Fields in the 45˚ Direction

  • Han, C.W.;Han, J.K.;Lim, S.H.
    • Journal of Magnetics
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    • v.15 no.3
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    • pp.116-122
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    • 2010
  • An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.