• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.891-894
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• 2008

This study was performed to investigate how to design, where to construct, why to degrade, what plan to use systematically the underground structures such as underpass, underground passageways. About 50% of the underground structures are located on Seoul, Kyungi-Do. In design of the underground structures such as underpass, underground passageways, the required conditions are defined. And also in construction stage, the conditions of soil, required structure depth, site characteristics, reasonable construction method, are investigated. In the selection of details for underground structure, the items mainly considered, are the wall and column type, the sidewalk type, anchoring-system type, the water-proofing method, entranc shape. The reason and the adequate measures for the degradation of concrete structure are also investigated. The initial cracking properties due to the thermal characteristic are considered. The state of the art report on the new technologies are reviewed. The recent project for the systematically application to the underground structures is reviewed.

• Journal of the Korea Concrete Institute
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• v.19 no.2
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• pp.189-197
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• 2007

Concrete tunnel lining must be designed to having the fireproof performance because the lining are sometimes exposed to very high temperature due to traffic accident. Such fire temperature may cause explosion of concrete, or collapse of tunnel structure. The purpose of this study is to obtain the fundamental fireproof behavior of fire resistance-engineered cementitious composites(FR-ECC) under fire temperature in order to use the fire protection material in tunnel lining system. The present study conducted the experiment to simulate fire temperature by employing 2 types of FR-ECC and investigated experimentally the explosion and cracks in heated surface of these FR-ECC. Employed temperature curve were hydro carbon(HC, ECl) criterion, which are severe in various criterion of fire temperature. The numerical analysis is carried out the nonlinear transient heat flow analysis and verified against the experimental data. The complex features of behavior in fire conditions, such as thermal expansion, plasticity, cracking or crushing, and material properties changing with temperature are considered. By the use of analytical model, the concrete tunnel subjected to fire loads were analyzed and discussed. With comparison of current concrete materials and FR-ECC, the experimental and analytical results of FR-ECC shows the better fire resistance performance than the other.

• Clean Technology
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• v.12 no.3
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• pp.113-127
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• 2006

Waste lubricating oil(WLO)s have been recycled as energy source through direct fuel in cement kilns and fossil power plants, or as fuel oils, or re-refined lubricating base oils. In our country, they have been recycled as low grade fuel oil through chemical treatment process. In 2003, extended producer responsibility (EPR) system was adopted from deposit system on sale of lubricating oils in order to promote their recycleing rate. However, our recycling rate of WLOs have been stagnant(below 70%) for last 5 years. And there has been no research work on recycling of WLOs as re-refined base oil until now in this country. Stabilization technology of thermally cracked oils to reduce tar and malodor and to improve their color for production of high grade fuel oil, and a novel process production of high grade re-refined lubricating base oil from WLOs have been developed and commercialized recently in Canada and U.S.A., respectively. Several countries like Australia, Italy, Germany and U.S.A., etc. are encouraging recycling companies to recycle WLOs as re-refined lubricating oil by giving greater subsidies or benefits compared to other recycling methods. They also adopt a policy to purchase re-refined lubricating oil preferentially in the federal or local governments and to recommend consumers to purchase it willingly. Based on the facts that several advanced countries have adopted a policy to recycle WLOs as re-refined base oil for saving of petroleum resource and reduction of environmental pollution, it is right time to be considered that our present policy for recycling of WLOs should be reevaluated and the new policy of their environmental-friendly and sustainable recycling should be established.

• Applied Chemistry for Engineering
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• v.19 no.6
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• pp.592-599
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• 2008

Oil sands had not received enough attention due to high production cost. However, as oil price significantly increases, oil sands are receiving more and more interest as unconventional crude oil. The value and applicability of oil sands can be enhanced by upgrading oil sands bitumen to produce synthetic crude oil (SCO). This study analyzed 213 oil sands upgrading patents applied between 1969 and 2006 in US, Canada, Japan, Europe, and Korea. The upgrading technologies could be classified into 9 detailed technologies; hydrocracking, coking, thermal cracking, deasphalting, supercritical technology, bio-technology, hydrotreating, gasification, and others. The number of patents applied for oil sands upgrading increased after 1970, reached a maximum in the early 1980, and slowly increases again in recent years. Korea has a lack of technologies for oil sands. Therefore, the technologies for oil sands production and application, specially, upgrading technologies based on accumulated oil refinery technologies need to be developed to increase self-development ratio of energy resource.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.100-100
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• 2009

This paper is concerned with numerical analyses of residual stresses in welds and material's susceptibility to stress corrosion cracking (SCC) for the primary piping system in nuclear power plants: Both the dissimilar metal weld (DMW) for stainless steel to low alloy steel joints and the similar metal weld (SMW) for forged stainless steel to cast stainless steel joints are considered. Thermal elasto-plastic analyses using the finite element method (FEM) are performed to predict residual stresses generated in fabrication welding and its related processes for both the DMW and SMW, including effects of quenching for cast stainless steel piping, machining of the DMW root, and grinding of the SMW root. As a result, the effect of quenching should be included in the evaluation of residual stresses in the SMW for the cast stainless steel piping. It is deemed that residual stresses in both the DMW and SMW would not affect the SCC susceptibility of the welds providing that the welding processes are completed without any weld repair on the inside wall of the joint. However, the grinding process if performed on the safe-end to piping weld, would produce a high level of residual stresses in the inner surface region and thus a stress improvement process (e.g. buffing) should be considered to reduce susceptibilities to SCC.

• Journal of the Korean Society for Railway
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• v.17 no.4
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• pp.270-280
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• 2014

In this study, to examine the causes of cracks in continuously reinforced concrete tracks (CRCTs) and the main factors affecting cracking, a field survey on the status of cracks and crack patterns in the Gyeong-bu high speed line was conducted, and the crack patterns of CRCT due to the temperature difference between the top of the slab (TCL) and the bottom of the subbase (HSB) and the drying shrinkage of concrete were predicted by a nonlinear finite element model considering the structure of CRCT. The results of the numerical analysis show that cracks will be developed at the interface between the sleeper and the TCL, and under the sleeper due to the temperature difference and concrete shrinkage. This corresponds well to the crack locations found in the field. Also, it is found that the most significant factors are the coefficient of thermal expansion with respect to the temperature difference, and the drying shrinkage strain with respect to shrinkage. According to the results, the reinforcement ratio should be carefully determined considering the structures of CRCT because the crack spacing is not always proportional to the reinforcement ratio due to the sleepers embedded in the TCL.

• Journal of the Korean Geosynthetics Society
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• v.17 no.4
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• pp.169-177
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• 2018

Glass fiber reinforced polyester (GFRP) composites are widely used as structural materials in harsh environment such as underground pipes, tanks and boat hulls, which requires long-term water resistance. Especially, these materials might be damaged due to delamination between gelcoat and composites through an osmotic process when they are immersed in water. In this study, GFRP laminates were prepared by surface treatment of UPE (unsaturated polyester) gelcoat by vacuum infusion process to improve the durability of composite materials used in underground pipes. The composite surface coated with gelcoat was examined for surface defects, cracking, and hardness change characteristics in water-immersion environments (different temperatures of $60^{\circ}C$, $75^{\circ}C$, and $85^{\circ}C$). The penetration depth of cracks was investigated by micro CT imaging according to water immersion temperature. It was confirmed that cracks developed into the composites material at $75^{\circ}C$ and $85^{\circ}C$ causing loss of durability of the materials. The point at which the initial crack initiated was defined as the failure time and the life expectancy at $23^{\circ}C$ was measured using the Arrhenius equation. The results from this study is expected to be applied to reliability evaluation of various industrial fields where gelcoat is applied such as civil engineering, construction, and marine industry.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.6
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• pp.786-794
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• 2022

Green ammonia is a promising renewable energy carrier. Green ammonia can be used in various energy conversion devices (e.g., engine, fuel cell, etc.). Ammonia has to be fed with hydrogen for start-up and failure protection of some energy conversion devices. Ammonia can be converted into hydrogen by decomposition and partial oxidation. Especially, partial oxidation has the advantages of fast start-up, thermally self-sustaining operation and compact size. In this paper, thermodynamics, start-up and operation characteristics of ammonia partial oxidation were investigated. O₂/NH₃ ratio, ammonia flow rate and catalyst volume were varied as operation parameters. In thermodynamic analysis, ammonia conversion was maximized in the O₂/NH₃ range from 0.10 to 0.15. Ammonia partial oxidation reactor was successfully started using 12 V glow plug. At 0.13 of O₂/HN₃ ratio and 10 LPM of ammonia flow rate, ammonia partial oxidation reactor showed 90% of ammonia conversion over commercial Ru catalyst. In addition, Increasing O₂/NH₃ ratio from 0.10 to 0.13 was more effective for high ammonia conversion than increasing catalyst volume at 0.10 of O₂/NH₃.

• The Korean Journal of Petroleum Geology
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• v.11 no.1 s.12
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• pp.1-8
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• 2005

Seventeen exploratory wells have been drilled in the Block VI-1 of offshore Korea, which is located in the southern part or the Ulleung Basin. Gas show has been recognized from most of the wells, and gas and condensate have been accompanied in some wells. Commercial discovery of gas, accompanied by condensate, has been made from Gorae V well. The reservoir gases or the Dolgorae III, Gorae I, and Gorae V wells in the Ulleung Basin mainly consists of hydrocarbon gases (>93%). These gases are thermogenic wet gases which contain more than 96% of the methane and result from the cracking of petroleum or kerogen. Based on the chemistry and composition of the gases and stable isotope data, they seem to be generated from different source rocks. The condensates from the Gorae I and V wells are mostly generated from terrestrial organic matter. Lacustrine organic matter may not play an important role for the generation of these condensates. The condensates from the Gorae V wells consist predominantly of terrestrial organic matter but with minor subsidiary input from marine organic matter. The condensates from Gorse I and V wells may be generated from different source rocks. The thermal maturity level of the condensates from the Gorae V well ranges from early to middle oil generation zone and condensate from Gorae I reaches middle oil window. Correlation or the thermal maturation level of the condensates and organic matter in the sediments reveals that a depth of the generation of liquid hydrocarbons can be inferred to 3,000 m and 3,900 m for the Gorae V and I wells, respectively. Gorae V well, however, did not reach the target depth and the geochemical data of the Gorae I well were obscured due to the severe sediment caving in.