• 제목/요약/키워드: Temperature transition

검색결과 2,880건 처리시간 0.034초

SUS304강의 사이클의존형에서 시간의존형균열성장으로의 천이에 관한 연구 (A Study on Transition From Cycle-dependent to Time-dependent Crack Growth in SUS304 Stainless Steel)

  • 주원식;조석수
    • Journal of Welding and Joining
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    • 제14권1호
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    • pp.38-46
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    • 1996
  • High temperature low cycle fatigue crack growth behavior is investigated over a range of two temperatures and various frequencies in SUS 304 stainless steel. It is found that low frequency and temperature can enhance time-dependent crack growth. With high temperature, low frequency and long crack length, ${\Delta}J_c/{\Delta}J_ f$, the ratio of creep J integral range to fatigue J integral range is increased and time-dependent crack growth is accelerated. Interaction between ${\Delta}J_f$ and ${\Delta}J_c$ is occured at high frequency and low temparature and ${\Delta}J_c$, creep J integral range is fracture mechanical parameter on transition from cycle-dependent to time dependent crack growth in creep temperature region.

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바인더 유리전이온도에 따른 그린시트의 물리적 특성 (Physical Properties of Green Sheets According to Glass Transition Temperature of Binder)

  • 권혁중;여동훈;신효순
    • 한국전기전자재료학회논문지
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    • 제26권1호
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    • pp.33-37
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    • 2013
  • The properties of LTCC green sheets formed by the MLS-22 powder of NEG Inc. were investigated for acrylic binders with different PVB and Tg in the variation of temperature. The elongation of the green sheets showed large variation depending on the temperature, and was rapidly decreased near the Tg of the sheets. With the increase of the ratio of plasticizer/binder (P/B), large elongation of the sheets was observed due to the decrease of the Tg. In the stacking process of the multilayer ceramic, the optimal control of the temperature is highly required depending on the Tg of the binder and the ratio of P/Buniform coating.

Dielectric relaxation properties in the lead scandium niobate

  • Yeon Jung Kim
    • 한국표면공학회지
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    • 제56권4호
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    • pp.227-232
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    • 2023
  • In this study, complex admittance as a function of temperature and frequency was measured to analyze the important relaxation properties of lead scandium niobate, which is physically important, although it is not an environmentally friendly electrical and electronic material, including lead. Lead scandium niobate was synthesized by heat treating the solid oxide, and the conductance, susceptance and capacitance were measured as a function of temperature and frequency from the temperature dependence of the RLC circuit. The relaxation characteristics of lead scandium niobate were found to be affected by contributions such as grain size, grain boundary characteristics, space charge, and dipole arrangement. As the temperature rises, the maximum admittance and susceptance increase in one direction, but the resonance frequency decreases below the transition temperature but increases after the phase transition.

전자 포텐셜 변형과 포논 상호작용에 의한 준 이차원 Si 구조의 전도 현상 해석 (Quantum Transition Properties of Quasi-Two Dimensional Si System in Electron Deformation Potential Phonon Interacting)

  • 이수호;김영문;김해재;주석민
    • 전기학회논문지P
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    • 제66권3호
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    • pp.129-134
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    • 2017
  • We investigated theoretically the quantum optical transition properties of Si, in quasi 2-Dimensinal Landau splitting system, based on quantum transport theory. We apply the quantum transport theory (QTR) to the system in the confinement of electrons by square well confinement potential under linearly polarized oscillating field. We use the projected Liouville equation method with Equilibrium Average Projection Scheme (EAPS). In order to analyze the quantum transition, we compare the temperature and the magnetic field dependencies of the QTLW and the QTLS on four transition processes, namely, the intra-leval transition process, the inter-leval transition process, the phonon emission transition process and the phonon absorption transition process.

Metal-insulator Transition in Low Dimensional $La_{0.75}Sr_{0.25}VO_3$ Thin Films

  • Huynh, Sa Hoang;Dao, Tran M.;Mondal, Partha S.;Takamura, Y.;Arenholz, E.;Lee, Jai-Chan
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.19.1-19.1
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    • 2011
  • We report on the metal-insulator transition that occurs as a function of film thickness in ultrathin $La_{0.75}Sr_{0.25}VO_3$ films. The metal-insulator transition displays a critical thickness of 5 unit cell. Above the critical thickness, metallic films exhibit a temperature driven metal-insulator transition with weak localization behavior. With decreasing film thickness, oxygen octahedron rotation in the films increases, causing enhanced electron-electron correlation. The electron-electron correlations in ultrathin films induce the transition from metal to insulator in addition to Anderson localization.

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(Pb, Ba) (Zr, Ti)O3계의 확산된 상전이에 있어서 Strain Energy의 역할 (Role of the Strain Energy in Diffuse Phase Transition of (Pb, Ba)(Zr, Ti)O3)

  • 이재찬;주웅길
    • 한국세라믹학회지
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    • 제24권6호
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    • pp.586-592
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    • 1987
  • The role of the strain energy and phase stability in the diffuse phase transition have been investigated in the highly disordered solid solution, (Pb1-xBax)(Zr0.4Ti0.6)O3 (0.2 x 0.4). X-ray diffraction analysis indicates that tetragonality (c/a) decreases with the increasing Ba content. Also as the Ba content increases, phase transition becomes more diffuse and at the same time dielectric relaxation as a function of measured frequencies in the 1KHz-10MHz range occurs very pronouncedly. In the Ba content range, 0.2 x 0.35, hysteresis loops are routinely observed and the loop is observed to narrow shape as the Ba content increases but becomes very slim at 40mol% Ba content. Moreover thermal analysis shows that there is no abrupt change in the thermal expansion coefficient below the apparent transition temperature at which dielectric constant becomes maximum. From the above results, it has been concluded that creation of the strain energy due to the distorthion that occurred during the phase transition suppresses diffuse phase transition.

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RESPONSES OF THE TRANSITION REGION TO DOWNWARD AND UPWARD FLOWS

  • YUN H. S.;CHAE J.-C.;POLAN A. I.
    • 천문학회지
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    • 제29권spc1호
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    • pp.339-340
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    • 1996
  • In the present study we examine physical characteristics of a thin and rigid magnetic flux tube with a steady flow inside, which is embedded vertically upward in the solar atmosphere. We found from this study that (1) The downward material flow gives rise to a dominant heating in the flux tube which works with the conductive heating in the same direction. However, the upflow flow creates a dominant cooling which works against the conductive heating, resulting in a steeper temperature gradient with a shallower transition region. (2) Since the thickness of the transition region determines the material content in the transition region, a broader transition region of the downflow tube produces a larger differential measure.

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벼 냉해의 초기 기작으로서 생체막과 세포질 사이의 대사 불균형 (Metabolic Imbalance between Glycolysis and Mitochondrial Respiration Induced by Low Temperature in Rice Plants)

  • 이근표;부용출;정진
    • Applied Biological Chemistry
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    • 제43권4호
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    • pp.236-240
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    • 2000
  • 식물의 저온 스트레스 및 방어체계에 대한 기작론적 연구의 일환으로서, 저온에서 보이는 벼 유묘의 생장력 상실과 생체막의 상전이 및 세포질 대사 변화 간의 상관관계를 조사하였다. 주변환경의 온도가 내려감에 따라 유묘의 생장속도는 점차 감소하여 약 $13^{\circ}C$ 이하에서는 생장이 실질적으로 정지하였다. 이 온도는 미토콘드리아 내막의 물리적 상전이 온도 및 기능적 상전이 온도와 일치하였다. 또한 해당과정의 중간생성물인 glucose 6-phosphate(G6P), fructose 6-phosphate(F6P)의 함량과 온도간의 상관곡선에서 보여주는 변곡점도 $13^{\circ}C$ 부근에서 나타났다. 이들-세포생리의 생화학적, 생물물리적 특성들의 불연속적 변화를 나타내는-온도들의 일치는 저온하에서의 생장정지가 우선적으로 미토콘드리아막의 상전이에 기인하며, 이 상전이가 세포 대사의 불균형을 일으키는 주요인임을 시사한다. 저온처리된 벼를 다시 상온으로 옮겼을 때 축적된 G6P와 F6P함량의 급격한 감소가 관찰되었다. 이는 상온환원시 TCA cycle을 거쳐 호흡전자전달에 필요한 전자공여체를 짧은 시간에 과다생성시키는 요인이 되어 결과적으로 세포의 산화적 스트레스를 일으키는 원인이 되는 것으로 해석하였다.

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페롭스카이트 La1/3Sr2/3FeO2.96의 결정학적 및 자기적 성질에 관한 연구 (Crystallographic and Magnetic Properties of a Perovskite La1/3Sr2/3FeO2.96)

  • 윤성현
    • 한국자기학회지
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    • 제15권3호
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    • pp.167-171
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    • 2005
  • 다결정질 $La_{1/3}Sr_{2/3}FeO_{2.96}$의 전하불균형(charge disproportionation, CD) 전이현상과 그 전이온도를 전후로 한 자기적 상호작용의 변화양상을 X-선 회절, $M\ddot{o}ssbauer$ 분광계, 그리고 SQUID 자기력계를 이용하여 연구하였다. X선 분석결과, 시료의 결정구조는 공간군 R/3c인 rhombohedral 구조이며, 격자상수는 $a_{R}=5.4874\;\AA,\;a_R=60.07^{\circ}$이었다. $M\ddot{o}ssbauer$ 스펙트럼은 4.2 K에서부터 실온까지의 범위에서 취하였다 분석결과 저온에서는 각각 $Fe^{3+}$$Fe^{5+}$에 기인하는 두개의 6-선 스펙트럼이 중첩되어 나타났으며 Fe 이온의 원자가가 두개의 상이한 전하 상태로 분리된 반강자성 혼합원자가 상태임을 알 수 있었다. 반면 고온에서는 $Fe^{3.6+}$에 기인하는 단일 흡수선이 관측되어 상자성의 평균원자가 상태임을 알 수 있었다. 175K부터 200K의 온도 범위에서는 이 두 상태가 혼재되어 나타났으며 이 온도 범위에서 CD전이가 발생함을 알 수 있었다. CD전이의 근원은 열적으로 발생한 전하의 도약현상으로 설명할 수 있었다. 측정된 자기이력곡선의 분석 결과, 자성원자 사이에는 강한 반강자성 상호작용이 존재하며, 온도가 CD 전이온도를 넘어 상승하면서 $Fe^{3+}-Fe^{5+}$간의 상호작용이 한층 더 강한 상호작용으로 대치됨을 알 수 있었다.

산업 발생 노르말헥산과 벤젠 증기의 저온 분해 (Low-Temperature Thermal Decomposition of Industrial N-Hexane and Benzene Vapors)

  • 조완근;이준엽;강정환;신승호;권기동;김모근
    • 한국환경과학회지
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    • 제15권7호
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    • pp.635-642
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    • 2006
  • Present study evaluated the low-temperature destruction of n-hexane and benzene using mesh-type transition-metal platinum(Pt)/stainless steel(SS) catalyst. The parameters tested for the evaluation of catalytic destruction efficiencies of the two volatile organic compounds(VOC) included input concentration, reaction time, reaction temperature, and surface area of catalyst. It was found that the input concentration affected the destruction efficiencies of n-hexane and benzene, but that this input-concentration effect depended upon VOC type. The destruction efficiencies increased as the reaction time increased, but they were similar between two reaction times for benzene(50 and 60 sec), thereby suggesting that high temperatures are not always proper for thermal destruction of VOCs, when considering the destruction efficiency and operation costs of thermal catalytic system together. Similar to the effects of the input concentration on destruction efficiency of VOCs, the reaction temperature influenced the destruction efficiencies of n-hexane and benzene, but this temperature effect depended upon VOC type. As expected, the destruction efficiencies of n-hexane increased as the surface area of catalyst, but for benzene, the increase rate was not significant, thereby suggesting that similar to the effects of the re- action temperature on destruction efficiency of VOCs, high catalyst surface areas are not always proper for economical thermal destruction of VOCs. Depending upon the inlet concentrations and reaction temperatures, almost 100% of both n-hexane and benzene could be destructed, The current results also suggested that when applying the mesh type transition Metal Pt/SS catalyst for the better catalytic pyrolysis of VOC, VOC type should be considered, along with reaction temperature, surface area of catalyst, reaction time and input concentration.