• Title/Summary/Keyword: Temperature dependency

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A Study on Microstructural Evolution of Hot Rolled AZ31 Magnesium Alloy Sheets (열간 압연한 AZ31 마그네슘합금 판재의 미세조직 발달에 관한 연구)

  • Kim S. H.;Yim C. D.;You B. S.;Seo Y. M.;Chung I. S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.08a
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    • pp.63-71
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    • 2004
  • Recently, a sheet forming process of Mg alloys is highlighted again due to increasing demand for Mg wrought alloys in the applications of casings of mobile electronics and outer-skins of light-weight transportation. Microstructure control is essential for the enhancement of workability and formability of Mg alloy sheets. In this research, AZ31 Mg alloy sheets were prepared by hot rolling process and the rolling condition dependency of the microstructure and texture evolution was studied by employing a conventional rolling mill as well as an asymmetric rolling mill. When rolled through multiple passes with a small reduction per pass, fine-grained and homogeneous microstructure evolved by repetitive dynamic and static recrystallization. With higher rolling temperature, dynamic recrystallization was initiated in lower reduction. However with increasing reduction per pass, deformation was locallized in band-like regions, which provided favorable nucleation sites f3r dynamic recrystallization. Through post annealing process, the microstructures could be transformed to more equiaxed and homogeneous grain structures. Textures of the rolled sheets were characterized by $\{0002\}$ basal plane textures and retained even after post annealing. On the other hand, asymmetrically rolled and subsequently annealed sheets exhibited unique annealing texture, where $\{0002\}$ orientation was rotated to some extent to the rolling direction and its intensity was reduced.

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Dielectric Properties of Al2O3 Thick Films Grown by Aerosol Deposition Method (에어로졸 데포지션법으로 성막된 Al2O3 후막의 유전특성)

  • Park, Jae-Chang;Yoon, Young-Joon;Kim, Hyo-Tae;Koo, Eun-Hae;Nam, Song-Min;Kim, Jong-Hee;Shim, Kwang-Bo
    • Journal of the Korean Ceramic Society
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    • v.45 no.7
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    • pp.411-417
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    • 2008
  • Aerosol Deposition Method (ADM) is a novel technique to grow ceramic thick films with high density and nano-crystal structure at room temperature. $^{1,2)}$ For these unique advantages of ADM, it would be applied to the fabrication process of 3-D integration ceramic modules effectively. However, it is critical to control the properties of starting powders, because a film formation through ADM is achieved by impaction and consolidation of starting powders on the substrates. We fabricated alumina thick films by ADM for the application to integral substrates for RF modules. When the as-received alumina powders were used as a starting material without any treatments, it was observed that the dielectric properties of as-deposited alumina films, such as relative permittivity and loss tangent, showed high dependency on the frequency. In this study, some techniques of powder pre-treatments to improve the dielectric properties of alumina thick films will be shown and the effects of starting powders on the properties of AD films will be discussed.

Evaluation of Different Culture Conditions of Clostridium bifermentans DPH-1 for Cost Effective PCE Degradation

  • Humayra Afroze Syeda;Hasegawa Yuki;Nomura Izumi;Chang Young C.;Sato Takeshi;Takamizawa Kazuhiro
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.10 no.1
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    • pp.40-46
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    • 2005
  • Clostridium bifermentans strain DPH-1 has already been found to dechlorinate perchloroethylene (PCE) to cis-dichloroethylene (cis-DCE) via trichloroethylene (TCE). In this study, our investigation on different culture conditions of this DPH-1 strain was extended to find a more efficient and cost effective growth medium composition for this DPH-1 strain in bioremediation practices. Temperature dependency of strain DPH-1 showed that the growth starting time and PCE degradation at $15^{\circ}C$ was very slow compared to that of $30^{\circ}C$, but complete PCE degradation occurred in both cases. For the proper utilization of strain DPH-1 in more cost effective bioremediation practices, a simpler composition of an effective media was studied. One component of the culture medium, yeast extract, had been substituted by molasses, which served as a good source of electron donor. The DPH-1 strain in the medium containing molasses, in the presence of $K_{2}HPO_4\;and\;KH_{2}PO_4$, showed identical bacterial multiplication (0.135 mg protein $mL^{-1}h^{-1}$) and PCE degradation rates ($0.38\;{\mu}M/h$) to those of the yeast extract containing medium.

Theory of a Current-Type Electromagnetic Flowmeter for Two-Phase Flow and Numerical Computation of the 3D Virtual Potential Distributions for Annular Flow (2상류용 전류형식 전자기유량계 이론 및 환상류에서의 3차원 가상포텐셜 분포의 수치적 계산)

  • Oh, Byung-Do;Kim, Moo-Hwan;Ahn, Yeh-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.6
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    • pp.714-725
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    • 2003
  • The theory of the current-type electromagnetic flowmeter for a high temporal resolution was developed for two-phase flow measurements. To predict the output of the current-type flowmeter, the three-dimensional virtual potential distribution C and the newly introduced flow pattern coefficient f were derived and computed. The output of flowmeter depends on the liquid conductivity (sensitive to temperature) and flow configurations of the two-phase flow with the sinusoidal excitation over 100 Hz. The flow pattern coefficient was specially devised to separate the dependency on the flow configuration of the two-phase flow from that on the liquid conductivity which can be expressed with the calibration of single-phase flow. Using the finite difference method, the three-dimensional virtual potential distributions were computed for the electrode of finite size. By taking derivative of the virtual potential, the weight functions were evaluated and compared with existing analytic series solution for the point-electrode. There was a reasonable correspondence between the present and existing results. In addition, the flow pattern coefficients were evaluated for annular flows with various film thicknesses, and compared with the experimental results by the impedance spectroscopy. The numerical results agreed well with the experimental data.

Thermophysical Properties of the Soybean Curd and Prediction of its Thermal Conductivity 2. The 'intrinsic' thermal conductivity of soybean protein and prediction of the thermal conductivity of soybean curd (두부의 전열물성 및 유효열전도도의 추정 2. 대두단상질의 고유열전도도 측정과 두부의 유효열전도도의 추정)

  • KONG Jai-Yul
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.15 no.3
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    • pp.219-225
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    • 1982
  • Four heat conduction models were examined for defatted soy-protein curds in order to get the 'intrinsic' thermal conductivity of soy-protein. As the result of examination, the 'intrinsic', thermal conductivities of soy-protein, frozen and unfrozen states, were determined on the basis of series model to be 0.488 W/m.K and 0.300 W/m.K, respectively. By using the 'intrinsic' thermal conductivity values of soybean protein and the series model, the effective thermal conductivity of soybean curds, with and without fat, at frozen and unfrozen states, was predicted satisfactorily, The temperature dependency of the effective thermal conductivity of soybean curd was mostly observed to correlate with the thermal conductivity of water and ice.

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자동차용 강판의 온도에 따른 기계적 특성

  • Hyeon, Ju-Sik;Lee, Bo-Ryong;Mun, Man-Bin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.39.1-39.1
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    • 2010
  • 겨울철 혹한지방에서의 차량운행 또는 여름철 혹서지방에서의 장시간 차량 운행시 차체를 구성하고 있는 강판에는 약 $-50^{\circ}C{\sim}150^{\circ}C$의 온도환경에 처하게 된다. 따라서 이러한 저온 고온 환경하에서 차체 충돌상품성 예측 및 충돌안전 설계를 위해 온도에 따른 차체 강판의 기계적 물성평가가 요구된다. 이를 위해 본 연구에서는 자동차용 충돌부재에 주로 쓰이는 HS440MPa, HS590MPa급 냉연 고장력 강판에 대해 $-60^{\circ}C{\sim}200^{\circ}C$의 온도범위로 저온 고온 인장시험을 수행 하였다. 각각의 인장시험 결과로부터 온도 별 항복강도, 인장강도, 연신율, 가공경화지수 등 기계적 물성 변화를 평가하였다. 저온 고온 인장시험은 ZWICK Z250 만능재료시험기를 사용하였고 KS5호 규격의 인장시편을 사용하였으며, 시편에 충분한 온도를 가하기 위하여 목표온도 도달 후 20분간 유지한 뒤 인장시험을 수행하였다. 인장시험결과 HS440MPa, HS590MPa급 두 강종 모두 온도가 낮아질수록 강도 및 연신율 등이 증가하였고, 온도가 증가할수록 강도 및 연신율 등 기계적 물성이 저하 되었다. 즉, 우리가 주로 평가해왔던 상온($25^{\circ}C$)에 비해 저온 고온 환경하에서는 강판의 기계적 물성 변화가 큰 것을 알 수 있다. 따라서 혹한 또는 혹서 지방 등 온도차이가 큰 운행환경하에서의 차체 강도 및 충돌안전성 확보를 위해 온도에 따른 강판의 정확한 물성평가가 필요하고 차체 설계시 온도에 따른 강도변화를 충분히 고려하여야 한다.

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Phase Transfer Catalytic Effects for Thiocyanate Displacement on Benzyl Chloride (티오시안산 염에 의한 염화벤질의 치환반응에 미치는 상이동 촉매효과)

  • Seung Hyun Chang;Mu Hong Yoon;Chang Su Kim;Kwang Bo Chung;Jae Hu Shim
    • Journal of the Korean Chemical Society
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    • v.33 no.6
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    • pp.651-656
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    • 1989
  • The catalytic effects of several phase-transfer catalysts (PTC) on the liquid-liquid heterogeneous nucleophilic displacement reaction of thiocyanate on benzyl chloride have been determined. Reactions followed a pseudo-first order dependency on the benzyl chloride concentration and the observed rate constant $(k_{obsd})$ were linearly related to the concentration of catalyst and varied with variables such as reaction temperature and solvent. The sequences of catalytic activity of the displacement were $NH_4Cl$ < BTMAC < 18-crown-6 < BTEAC < PEG < TBAC < CTMAB. Enthalpies and entropies of activation associated with the displacement were 15∼20 Kcal$mo^{l-1}$, -12∼-29 eu. respectively and the reaction occurs in the interphase comprising of microemulsion.

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A Sensitivity Study of the Number of Parcels to the Numerical Simulation of Sprinkler Sprays (통계적 액적군집수에 따른 스프링클러 분무해석의 민감도에 관한 연구)

  • Kim, Sung-Chan;Lee, Sang-Woo;Park, Won-Ju
    • Fire Science and Engineering
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    • v.23 no.1
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    • pp.48-54
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    • 2009
  • The present study has been performed to investigate the effect of statistical number of droplets on the simulation of the sprinkler spray using fire field model. In order to simulate the sprinkler spray characteristics, the present study uses NIST Fire Dynamics Simulator version 5.2. A group of Lagrangian particles with similar droplet characteristics, such as diameter, velocity, temperature and so on, is represented by parcel concept to decrease the total number of droplets tracked in the simulation. The present study introduces a new parameter to represent the ratio between real number of droplets and computational parcels. The dependency of the number of parcels on the fire suppression characteristics and spray patterns is quantitatively examined for different ratio between the real number of droplets and computational parcels.

Immobilization of Fungal Laccase on Keratin-Coated Soil and Glass Matrices

  • Ginalska, G.;Lobarzewski, J.;Cho, Nam-Seok;Choi, T.H.;Ohga, S.;Jaszek, M.;Leonowicz, A.
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.3
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    • pp.112-122
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    • 2001
  • Laccase enzymes from Cerrena unicolor and Trametes versicolor were immobilized on the activated glass beads (CPG), silica gel (SG) and soil (SL). The heterogeneous matrices were activated by ${\gamma}$-aminopropyltriethoxysilane (APTES) and glutaraldehyde (GA), and their surfaces were coated by keratin (KER) on activated or non-activated CPG, SG and SL. The laccase activities were tested in the aqueous solution for the native and immobilized preparations using different pH and temperature conditions. By keratin coating on supports, in the cases of CPG-KER and SL-KER, the immobilization yield was increased from about 80% to 90%. Moreover, much less protein was immobilized in keratin coated matrices than in inorganic ones alone (e.g. on CPG-KER 57.6%, whereas on CPG alone 80.6%). Laccase immobilization on keratin coated inorganic matrices was generally more effective than that of non-coated matrices. Concerned to pH dependency, the optima pH for immobilized laccases generally shifted towards to higher values, 5.5-5.8 and even 5.9 in the case of keratin for C. unicolor and from 5.3 to 5.7 for T. versicolor, respectively, and decreased less gradually both in acidic and alkaline regions. The immobilized laccase was more stable against thermal denaturation. This seems particularly true at $75^{\circ}C$ in the case of C. unicolor, where the activity of immobilized enzyme is > 50% higher than that of the free enzyme. For T. versicolor the respective values were $65^{\circ}C$, and 50%.

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Development of High Density Inductively Coupled Plasma Sources for SiH4/O2/Ar Discharge (고밀도 유도 결합 플라즈마 장치의 SiH4/O2/Ar 방전에 대한 공간 평균 시뮬레이터 개발)

  • Bae, S.H.;Kwon, D.C.;Yoon, N.S.
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.426-434
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    • 2008
  • A space averaged $SiH_4/O_2/Ar$ simulator for the high density inductively coupled plasma sources for $SiH_4/O_2/Ar$ discharge is developed. The developed simulator uses space averaged fluid equations for electrons, positive ions, negative ions, neutral species, and radicals in $SiH_4/O_2/Ar$ plasma discharge, and the electron heating model including the anomalous skin effect. Using the developed simulator, the dependency of the density of charged particles, neutral particles, and radicals, the electron temperature, the plasma resistance, and the power absorption coefficient for the RF power and pressure is calculated.