• Title/Summary/Keyword: TSC

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A Estimation of Ionic Space Charge Polarization in Polyimide by TSC (폴리이미드에서 TSC에 의한 이온성 공간전하분극의 평가)

  • Lee, Won-Jae;Lee, Sung-Il;Lee, Ho-Sik;Jang, Kyung-Uk;Choi, Myong-Kyu;Kim, Tae-Wan;Kang, Dou-Yol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.10a
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    • pp.15-20
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    • 2000
  • In this paper. Thermally Stimulated Current spectra have been measured in the Polypy - romellitimide (polyimide). As a result of the investigation. three peaks have been observed: $A(50^{\circ}C)$, $B(120^{\circ}C)$, $C(200^{\circ}C)$. Among three peaks, C peak has been observed in detail. The C peak is shown to be created due to the polarization of ionic space charge from the experimental results which were measured as a function of forming time, forming temperature. forming voltage and collecting voltage. As a result, we have measured the TSC in ion ($Na^+$) implanted - Polyimide, also found the peak at $215^{\circ}C$. Therefore, TSC characteristics in the C peak is probably caused by residual impurity. And The activation energy caculated by means of initial rising method 1.8eV, hopping distance. $90{\AA}$. and the mobility. $2.88{\times}10^{-11}cm^2/v.s$

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A study on the structural changes and the TSC characteristics of epoxy composites cured with acid-anhydride (산무수물 경화된 에폭시 복합체의 구조변화와 TSC특성에 관한 연구)

  • 왕종배;이준웅
    • Electrical & Electronic Materials
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    • v.7 no.1
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    • pp.32-41
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    • 1994
  • In this study, the TSC spectroscopy has been applied to investigate the influence of structural change due to a process of curing reaction on the electrical properties of epoxy composites cured with acid-anhydride. Five TSC peaks appeared in -160-250[.deg.C]: in the low temperature region below glass transition temperature(T$\_$g/), three relaxation mode peaks due to action of side chains, substitution group or terminal groups have been observed, a peak associated with T$\_$g/, appeared in 110[.deg. C] and p peak due to ionic space charges located in 150[.deg.C]. Each peak was separated into elementary peaks by the partial polarization procedure, and the distribution of activation energy and relaxation time were analized to clearify the origin of each peak. Also, overaboundantly added hardener separated a .betha. peak near 10[.deg. C] into two peaks of .betha.$\_$1/(10.deg. C) and .betha.$\_$2/(20.deg. C) according to increasement of forming field, and the separated hardener was oxidated thermally with increasing surrounding temperatures. The expansion of the free volume need in molecular motion and the reduction of the structural packing density through thermal oxidation process increased TSC between .alpha. peak and .betha. peak and decreased T$\_$g/.

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Numerical analysis of thermally stimulated current due to lonic space charge polarization by hopping method (호핑법에 의한 이온 공간전하 분극 열자극전류의 수치해석)

  • 김의균;국상훈
    • Electrical & Electronic Materials
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    • v.4 no.1
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    • pp.53-64
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    • 1991
  • 절연체중에 있는 하전입자의 거동은 절연재료의 특성에 많은 영향을 준다. 본 연구에서는 호핑모델에 의한 수치해석법을 TSC특성과 쌍극자분극에 대한 TSC특성은 차이가 있었다. 실험과 대응시켜 가동이온에 관한 물성정수의 평가를 하였다. 호핑모델에 의해서 불포화 TSC와 I-V특성의 수치계산을 하였다.

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Effects of copolymer on electrical conduction characters in polythylene (폴리에틸렌의 도전특성에 미치는 공중합의 영향)

  • 이규철;이종호;류근민
    • Electrical & Electronic Materials
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    • v.4 no.1
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    • pp.12-18
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    • 1991
  • 각종 monomer를 공중합시킨 고분자 필름의 X선 유기 TSC(thermally-stimulated current)를 측정하고 polyethylene(PE)의 절연성능 개선의 관점에서 공중합 monomer의 영향에 대하여 검토하였다. PE의 X선 유기 TSC 피이크는 결정화도가 높을 수록 고온측으로 이동하였다. X선 유기 TSC에서 피이크는 공중합에 의하여 Br 및 F원자가 0.2~0.4eV의 전자 trap이 도입된 것으로 생각된다.

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TSC Properties of Epoxy Composites due to Hardening Time (경화 시간에 따른 에폭시 복합체의 TSC특성)

  • 장인범;신철기;정일현;박건호;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.212-215
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    • 1995
  • The thermally stimulated currents (TSC) are measured to know the behaviour of charging particles of epoxy composites at the temperatures range -160~200[$^{\circ}C$] and to prove the various aspects due to hardening time in this study. It is composites at the narrower the magnititude of peak is and hardening time is a degradation from this.

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A Study on the Calculation of Escape Frequency Factor using TSC Equation (열자격전류식을 이용한 이탈주파수인자 계산에 관한 연구)

  • 김기준;김상진;전동근
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.135-138
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    • 1995
  • This paper presents a method to calculate the escape frequency factor and its verification from TSC(Thermally Stimulated Current) equation and cures. To apply calculation method of ν using asymptotic estimation, it utilized two sets of TSC data with 1K interval. This method enables one to get the exact value of ν and activation energy at the same time by using computer programming. So, it regards their calculation method as a useful process to obtain the value of physical behavior.

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Simulation of Corona Charging Process in Electret for Sensor Materials (센서재료용 일렉트렛트의 코로나 대전 과정 시뮬레이션)

  • Park, Geon-Ho
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2012.07a
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    • pp.421-422
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    • 2012
  • 본 연구에서는 코로나 대전된 고분자의 열자격전류(Thermally Stimulated Current; 이하 TSC) 데이터를 기반으로 코로나 대전 과정을 유한요소법(Finite Element Method; 이하 FEM)을 이용하여 시뮬레이션하였다. $DC -5{\sim}-8[kV]$의 고전압을 고분자에 인가하여 형성시킨 일렉트렛트를 온도 범위 $-100{\sim}+200[^{\circ}C]$에서 얻은 TSC 데이터의 대전 과정을 조사하기 위하여 FEM으로 시뮬레이션을 수행하여 공간에서 코로나 대전 과정을 추정하였다.

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Numerical Analysis of Thermally stimulated current of Ionic Space charge Polarijation by Hopping Model (Hopping 모델에 의한 이온 공간전하분극 숙련재전류의 수치해석)

  • 김의균;국상훈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1990.10a
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    • pp.91-94
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    • 1990
  • The behavior of charged particle in dielectrics have a many effects on characteristics of the insulating materials. In this paper, numerical analysis method by hopping model was investigated application of TSC. As the results, there was a difference between characteristics of TSC by dipole polarization. Physical constant of movable ion corresponding to the experimental results was evaluated and also. Numerical calculations of unsaturated TSC and I-V characteristics were carried out by was of hopping model.

Variation according to Curing Time in Epoxy Composites Using TSC Method (TSC방법을 이용한 에폭시 복합체의 경화 시간에 따른 변화)

  • 장인범;김성렬;박건호;이성일;김영천;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.260-263
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    • 1996
  • The thermally stimulated currents(TSC) are measured to know the behaviour of charging particles of epoxy composites at the temperature range of -160∼200[$^{\circ}C$] and to prove the variation according to curing time in this study. It is confirmed that the peak amplitude is inversely proportional to the curing time, and TSC are reduced is and T$\sub$m/ is moved to high temperature side according to the curing time because carboxyl radical is formed by thermal oxidation and motility becomes lack.

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Fatigue Behavior of Composite Beams with Pyramidal Shear Connector (입체트러스형 전단연결재를 갖는 합성판의 피로거동)

  • Lee, Kyeong-Dong;Han, Jae-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.6 no.2
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    • pp.211-216
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    • 2002
  • A steel plate-concrete composite slab with pyramidal shear connectors, named TSC composite slab, is expected to have sufficient bending strength and flexural rigidity for loads during and after construction. Fatigue problems play an important role in designing composite slab as bridge decks under traffic conditions. In this paper, a series of fatigue tests was carried out on TSC beam specimens under various loading conditions, in order to evaluate the fatigue strength of TSC composite slabs. The results are as follows : (1) the fatigue failure of TSC composite beams results from the tensile fracture of bottom steel plate and shear connector, and (2) fatigue strength of the steel plate for two million cycles can be estimated to be $1144kgf/cm^2$ from the S-N curves.