• Journal of Microbiology and Biotechnology
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• 제12권4호
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• pp.695-698
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• 2002

The biodegradation of 2,4,6-trinitrotoluene (TNT) was performed on a laboratory scale using P. putida originally isolated from explosive-contaminated soil. One hundred mg/1 of TNT was completely degraded within 20 h under optimum conditions. Various supplemental energy sources (carbon sources, nitrogen sources, and surfactant) were tested, with the main objective of identifying an inexpensive source and enhancing the degradation rate for large-scale biodegradation. Based on the degradation rate, molasses was selected as a possible supplemental carbon source, along with NH$_4$Cl and Tween 80 as a nitrogen source and surfactant, respectively. The degradation rate increased about 3.3 fo1d when supplemental energy sources were added and the degradation rate constant increased from 0.068 h$\^$-1/ to 0.224 h$\^$-1/. These results appear to be promising in application of the process to TNT-contaminated soil applications.

• 한국지하수토양환경학회지:지하수토양환경
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• 제19권3호
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• pp.56-65
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• 2014

Contamination of explosive compounds in the soils of military shooting range may pose risks to human and ecosystems. As shooting ranges are located at remote places, active remediation processes with hardwares and equipments are less practical to implement than natural solutions such as bioremediaton. In this study, a series of experiments was conducted to select a suitable carbon source and to optimize dosing rate for the enhanced bioremediation of explosive compounds in surface soils and sediments of shooting ranges with indigenous microorganisms activated by external carbon source. Treatability study using slurry phase reactors showed that the presence of indigenous microbial community capable of explosive compounds degradation in the shooting range soils, and starch was a more effective carbon source than glucose and acetic acid in the removal of TNT. However, at higher starch/soil ratio, i.e., 2.0, the acute toxicity of the liquid phase increased possibly due to transformation products of TNT. RDX degradation by indigenous microorganisms was also stimulated by the addition of starch but the acute toxicity of the liquid phase decreased with the increase of starch/soil ratio. Taken together, the optimum range of starch/soil ratio for the degradation of explosive compounds without significant increase in acute toxicity was found to be 0.2 of starch/soil.

• 한국지하수토양환경학회지:지하수토양환경
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• 제19권3호
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• pp.82-93
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• 2014

A starch ball was devised to conveniently supply carbon source to indigenous microorganisms and to enhance biotransformation of explosive compounds(TNT and RDX) in the sediments of settling basins installed in military shooting ranges. To identify optimum dose/sediment ratio for degradation of explosives in the basin, a series of bench scale settling basin experiments were performed for 30 days while monitoring supernatant pH, DO, concentrations of nitrite, nitrate, sulfate, explosive compounds, and acute toxicity measured by bacterial luminescence. Addition of starch ball induced changes in oxidation conditions from oxic to anoxic in the benthic zone of the basin, which resulted in subsequent reductive degradation of both TNT and RDX in the liquid and solid phase of basin. However, fermentation products of excess starch, acetic acid and formic acid, caused acute toxicity in the liquid phase. The optimum ratio of starch ball/sediment for explosive compounds degradation by inducing changes in bio-geochemical environments without increase in acute toxicity, was found to be 0.009~0.017.

• Mycobiology
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• 제37권1호
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• pp.17-20
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• 2009

White-rot fungus Irpex lacteus degraded TNT significantly in proportion to the culture time. After 48 h incubation, about 95% of TNT was degraded. Two reduced metabolites were identified as 4-amino-2,6-dinitrotoluene (4-ADNT) and 2-amino-4,6-dinitrotoluene (2-ADNT) which was further degraded.

• 화약ㆍ발파
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• 제29권1호
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• pp.27-33
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• 2011

일반구조용 압연강재인 SS400과 용접구조용 압연강재인 SM490에 대하여 폭발위력의 기준 약으로 사용되는 TNT를 이용한 붙이기 폭파절단실험을 실시하였으며, TNT 약량에 따른 강재의 절단 및 강종별 절단 특성에 대하여 검토하였다. 그 결과로서 SM490 강재의 폭파저항성이 SS400 강재 보다 약량기준 약 30% 이상임을 확인 할 수 있었다.

• 한국안전학회지
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• 제8권4호
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• pp.127-132
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• 1993

Porphyrin-catalyzed reduction of TNT to triaminotoluene was performed in both batch reactions and a continuous process. Packed-bed reactors were used to study porphyrin-catalyzed reduction in a continuous process. A reactor was packed with DEAD(diethylaminoethyl)-substituted glass beads on which $Co^{+3}$_centered deuteroporpgyrin Ⅸ, -2, 4-disulfonic acid was immobilized, and another containing only DEAE glass beads was used as a control. The porphyrin exhibited catalytic activity in its immobilized state up to 100 hours of operation. Based on the successful abatement of nitrobodies by porphyrin-catalyzed reduction in both batch and continuous process, this process is recommended to be used as a pretreatment for biological treatment or carbon adsorption treatment of TNT wastes.

• 상하수도학회지
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• 제24권6호
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• pp.775-788
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• 2010

The decomposition of 2,4,6-trinitrotoluene (TNT) and the mass balance of nitrogen (N) species as products were investigated in a UV/H2O2system by varying pH, concentrations of $H_2O_2$, and $O_2$. All experiments were conducted in a semi-batch system employing a 50 mL reaction vessel and a coil-type quartz-tube reactor. In contrast with previous studies employing batch mode, TNT decomposition in the semi-batch mode was proportionally enhanced by increasing $H_2O_2$ concentration to 10 mM (0.034%), indicatingthat an inhibitory effect of excess $H_2O_2$on hydroxyl radical (${\cdot}OH$) can be negligible. N compounds are released as $NO_2^-$ in the early stages of the reaction, but $NO_2^-$ is rapidly oxidized to $NO_3^-$ by means of ${\cdot}OH$. $NH_4^+$ was also detected in this study and showed gradually the increase with increasing reaction time. In this study, $NH_4^+$ production can involve the reduction of nitro group of TNT concurrent with the production of $NO_3^-$. Of the N species originating from TNT decomposition, 12 ~ 72% were inorganic forms (i.e. [$NO_3^-$] + [$NO_2^-$] + [$NH_4^+$]). This result suggests that the large remaining N portions indicate that unidentified N compounds can exist.

• 한국응용과학기술학회지
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• 제30권1호
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• pp.49-56
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• 2013

Excellent electron transport properties with enhanced light scattering ability for light harvesting have made well-ordered one dimensional $TiO_2$ nanotube(TNT) arrays an alternative candidate over $TiO_2$ nanoparticles in the area of solar energy conversion applications. The principal drawback of TNT arrays being activated only by UV light has been addressed by coupling the TNT with secondary materials which are visible light-triggered. As well as extending the absorption region of sunlight, the introduction of these foreign components is also found to influence the charge separation and electron lifetime of TNT. In this study, a novel method to fabricate the TNT-based composite photoelectrodes employing visible responsive $CuInS_2$ (CIS) nanoparticles is presented. The developed method is a square wave pulse-assisted electrochemical deposition approach to wrap the inner and outer walls of a TNT array with CIS nanoparticles. Instead of coating as a dense compact layer of CIS by a conventional non-pulsed-electrochemical deposition method, the nanoparticles pack relatively loosely to form a rough surface which increases the surface area of the composite and results in a higher degree of light scattering within the tubular channels and hence a greater chance of absorption. The excellence coverage of CIS on the tubular $TiO_2$ allows the construction of an effective heterojunction that exhibits enhanced photoelectrochemical performance.

• 디지털콘텐츠학회 논문지
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• 제19권2호
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• pp.415-423
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• 2018

최근, 컴퓨터 분야의 기계 학습(Machine Learning)과 딥러닝(Deep Learning) 등 컴퓨터 관련 학습이 각광을 받고 있다. 이들은 인공 신경망(Artificial Neural Network)을 이용하여 가장 하위 레벨로부터 학습을 시작하여, 최상위 레벨까지 그 결과를 전달하여 최종 결과를 산출하는 방식이다. 하위레벨로부터의 체계적인 학습을 통한 효과적인 성장 및 교육 방안에 대한 연구는 다양한 분야에서 이루어지고 있으나, 체계적인 규칙과 방법에 기반한 모델은 찾아보기가 힘들다. 이에, 본 논문에서는 성장 및 융합 모델인, TNT 모델(Transitive Nested Triangle Model)을 처음으로 제안한다. 제안하는 모델은 기하학적인 형태를 통해 형성된 각 기능들이 유기적 계층 관계를 형성하여, 상위로 성장 및 융합하면서, 그 결과가 반복 사용되는 순환적 재귀 모델이다. 즉, '수평적 형제 병합에 이은 상위로의 융합(Horizontal Sibling Merges and Upward Convergence)'의 분석적 방법이다. 이러한 모델은 공학, 디지털공학, 인문학, 예술학 등에 모두 적용될 수 있는 기본기적 이론으로, 본 연구에서는 제안하는 TNT 모델을 설명하는 것에 그 초점을 둔다.

• 대한토목학회논문집
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• 제41권4호
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• pp.331-340
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• 2021

본 논문은 비예측 극한하중인 폭발하중에 노출된 RC building 구조물의 폭발손상평가를 위한 수치해석적 연구이다. 수치해석의 효율성 및 정확성을 높이기 위해, 폭발하중에 대한 정의, 유체-구조 연성을 위한 Euler-Lagrange 커플링 기법 적용, 그리고 고변형률 속도가 고려된 콘크리트 및 강재 재료구성모델이 제안된다. 특히 효율적인 폭발하중 정의를 위해, Euler-FCT 기법을 통하여 TNT 질량에 따른 시간별 압력하중 데이터가 확보되고, 이는 RC building 구조물 총 7 지점의 폭발위치에 적용되며, ANSYS-AUTODYN 솔버에 연결되어 수치 시뮬레이션이 수행된다. 해석결과, TNT 질량 및 폭발 위치에 따라 손상 차이가 발생하였으며, 먼저 TNT 질량 20 kg 일 경우 3 곳의 폭발손상 지점에서 주부재 중 슬래브에서만 중간 및 가벼운 손상이 발생되었고, TNT 질량 100 kg 일 경우 5 곳의 폭발손상 지점 중 3 곳은 슬래브 및 보 부재에서 중간 손상이 발생되었으며, 2 곳은 슬래브에서 심각한 손상이 발생되었다.