• Title/Summary/Keyword: TMP

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Membrane Concentrate Thickening by Hollow-fiber Microfilter in Drinkin Water Treatment Processes

  • Lee, Byung-Ho
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.100-105
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    • 1999
  • A novel system to thicken the concentrated colloidal solution from membrane water treat-ment processes was developed. A hollow-fiber microfilter(hydrophilic polyethylene nominal pore size 0.1 ${\mu}$m total surface area 0.42 m2) was installed in an acrylic housing that has an aeration port 5 cm below the membrane and a clarifier in the bottom. The concentrate was uniformly supplied from the top of the housing. Bacuum filtration caused downward flow of concentrate and as a result thickening interface. The addition of poly-aluminum chloride (PAC) resulted in rapid increase of trans-membrane pressure (TMP) and in no improvement of the filtered water turbidity and thickening process. Two types of con-centrate and concentrate turbidity had little effect on the increase of TMP and concentrate thickening. It was observed that for the same height of membrane housing membrane surface area to housing volume (A/V) ratio had significant effect on the increase of TMP. When the housing volume was increased ten times the increasing rate of TMP was three times faster as compared to the original housing. A hydraulic model successfully simulated the formation and sedimentation of thickening interface.

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Characteristics of the Concentration Process of Lactobacillus Cell Using a Ceramic Membrane (세라믹막을 이용한 Lactobacillus cell의 농축 공정의 특성)

  • Lee Yong Taek;Song Min-Ho
    • Membrane Journal
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    • v.14 no.3
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    • pp.192-200
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    • 2004
  • It is an anaerobic germ that Lactobacillus cell concentrated using ceramic membrane has high stability and long lifetime as compared with polymeric membrane. The effects of operating pressure, temperature, crossflow velocity on cell harvesting have been studied. Also the variation of flux and transmembrane pressure (TMP) with increasing concentration ratio and the change of TMP at constant concentration ratio (volumetric concentration factor: VCF) regarding the optimization have been examined. It showed that the permeate flux increased gradually with the increasing of transmembrane pressure, crossflow velocity, and volumetric concentration factor. The higher initial flux was due to the reduction of viscosity at elevated temperature. However, as operating time progressed, the effect of temperature was negligible since the effect of viscosity became minor. As a result, that operate in a constant concentration ratio, decreased degree could know that become slowly although the flux decreases according as operating time progressed. The flux is a very stable in the condition of constant VCF range. The yield of Latobaciilus (PS 406) which was cultivated at $37^{\circ}C$ was concentrated about 4.9{\times}10^9$ after operation.

Cure Behavior and Thermal Stability of Difunctional/Trifunctional Epoxy Blend System Initiated by Thermal Latent Catalyst (열잠재성 촉매 개시제를 이용한 2관능성/3관능성 에폭시 블렌드계의 경화거동 및 열안정성)

  • Park, Soo-Jin;Kim, Taek-Jin;Lee, Jae-Rock
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.1046-1051
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    • 1999
  • Cure behavior and thermal stability of the different ratio of diglycidylether of bisphenol A(DGEBA)/trimethylolpropane triglycidylether(TMP) epoxy blends initiated by 1 wt % N-benzylpyrazinium hexafluoroantimonate (BPH) as a cationic latent catalyst were studied using DSC and TGA, respectively. Latent properties were performed by measurement of the conversion as a function of temperature using dynamic DSC. Dynamic DSC thermograms of DGEBA/TMP blends revealed that the weak peak was formed by complex formation between the hydroxyl groups in DGEBA and BPH, and between epoxides and BPH in low temperature ranges. The strong peak was considered as an exothermic reaction by the formation of three-dimensional network in high temperature ranges. Isothermal DSC revealed that the reaction rate of the blends was found to be higher than that of the neat TMP. The thermal stabilities in the cured resins were increased with increasing the DGEBA content. These results could be interpreted in terms of the stable aromatic structure, existence of hydroxyl group and high molecular weight of DGEBA.

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Removal of Hardness Ions by Crossflow Ceramic Ultrafiltration Process with Adding Lime-soda Ash (석회-소다회를 주입한 십자흐름 세라믹 한외여과공정을 이용한 경도 이온 제거)

  • Park, Jin-Yong;Park, Bo-Reum
    • Membrane Journal
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    • v.17 no.3
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    • pp.191-196
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    • 2007
  • In the study, excess of lime-soda ash(L-S) was added to groundwater for chemical precipitation of hardness ions. After formation of the coagulated flocs, sedimentation step was replaced with crossflow ultrafiltration(UF) process using tubular ceramic membrane. As results, our treated water was below total hardness(TH) 10 mg/L as $CaCO_3$ from groundwater using washing water in a soymilk factory. Then, we investigated the change of permeat flux(J) and dimensionless permeate flux($J/J_0$) during experiments for variations of TMP(Trans-membrane pressure) or flow rate, to see effect of TMP or flow rate on membrane fouling by the coagulated Inorganic flocs. In the result, membrane fouling and rejection rate of total hardness were not affected by TMP and flow rate variations in the range of our experiments.

A Study on the Properties of Two-Component Type Polyurethane Resins Mixing Polyol and 4,4'-diphenyl Methane Diisocynate (폴리올(polyol)과 4,4'-디페닐메탄디이소시아네이트(MDI)를 혼합한 2액형 폴리우레탄 수지의 물성에 관한 연구)

  • Lee, Bum-Chuli;Choi, Sang-Goo
    • Elastomers and Composites
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    • v.36 no.4
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    • pp.268-277
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    • 2001
  • The MDI(4,4'-diphenyl methane diisocyanate) was mixed with PPG, PEG and trimethylolpropane(TMP) respectively to prepare polyurethane resin. The various physical properties were measured for the mixtures. The gel-time was shortened by adding of PEG and TMP The molecular weight made a greater influence on the gel-time than the number of functional groups. The NCO-OH reaction was more active and faster than the NCO-NCO reaction. The hardness was influenced by crosslinking-density and molecular structure. The NCO-OH reactions yielded the flexible films and the NCO-NCO reactions yielded the brittle films. The increase of crystallinity and shrinkage induced the low adhesion ratio but the adding of TMP induced the high adhesion ratio. The flame-retardancy was influenced by quantity and kinds of flame-retardant. IXOL B-251 was the most excellent among the flame-retardants employed in this study. TCCP was partially separated because of the lack of solubility.

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Behavioral Analysis of Triaxial Micropile (TMP) through Field Loading Test and 3D-numerical Analysis (삼축 마이크로파일(TMP)의 현장수평재하시험과 3차원 수치해석을 통한 거동 분석)

  • Kim, Taehyun;Ahn, Kwangkuk;An, Sungyul
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.4
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    • pp.15-23
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    • 2021
  • Various micropiles have been developed through research related to micropiles, which have been carried out with the increased use of micropiles. Among the micropile construction methods being developed, the triaxial micropile (tmp), which is recently developed for the purpose of increasing the horizontal bearing capacity (seismic resistance), is representative. The three-axis micropile has the advantage of a method that can resist horizontal load more effectively because three micropiles installed inclined on each axis resist horizontal load. However, there is a problem in effectively using this pile method due to insufficient research on the support characteristics of the triaxial group micropile. In order to effectively utilize the triaxial group micropile (tmp), it is required to evaluate the bearing capacity for the factors that affect the horizontal bearing capacity of the pile. Therefore, in this study, field horizontal loading Tests were performed for each load direction, field loading Tests were verified through three-dimensional finite element analysis, behavioral characteristics of triaxial micropiles were evaluated, and appropriate horizontal bearing capacity was analyzed in consideration of horizontal load directions.

Adsorption Characteristics Analysis of Trimethoprim in Aqueous Solution by Magnetic Activated Carbon Prepared from Waste Citrus Peel Using Box-Behnken Design (Box-Behnken Design을 이용한 수용액 중의 Trimethoprim에 대한 폐감귤박 자성활성탄의 흡착 특성)

  • Lee, Chang-Han;Lee, Min-Gyu;Hu, Chul-Goo;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.31 no.8
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    • pp.691-706
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    • 2022
  • Magnetic activated carbon was prepared by adding a magnetic material to activated carbon that had been prepared from waste citrus peel in Jeju. The adsorption characteristics of an aqueous solution of the antibiotic trimethoprim (TMP) were investigated using the magnetic activated carbon, as an adsorbent, and response surface methodology (RSM). Batch experiments were carried out according to a four-factor Box-Behnken experimental design affecting TMP adsorption with their input parameters (TMP concentration: 50~150 mg/L; pH: 4~10; temperature: 293~323 K; adsorbent dose: 0.05~0.15 g). The significance of the independent variables and their interaction was assessed by ANOVA and t-test statistical techniques. Statistical results showed that TMP concentration was the most effective parameter, compared with others. The adsorption process can be well described by the pseudo-second-order kinetic model. The experimental isotherm data followed the Langmuir isotherm model. The maximum adsorption capacities of TMP, estimated with the Langmuir isotherm model were 115.9-130.5 mg/g at 293-323 K. Also, both the thermodynamic parameters, ΔH and ΔG, have both positive values, indicating that the adsorption of TMP by the magnetic activated carbon is an endothermic reaction and proceeds via an involuntary process.

Study on the Adsorption of Antibiotics Trimethoprim in Aqueous Solution by Activated Carbon Prepared from Waste Citrus Peel Using Box-Behnken Design (박스-벤켄 설계법을 이용한 폐감귤박 활성탄에 의한 수용액 중의 항생제 Trimethoprim의 흡착 연구)

  • Lee, Min-Gyu;Kam, Sang-Kyu
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.568-576
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    • 2018
  • In order to investigate the adsorption characteristics of the antibiotics trimethoprim (TMP) by activated carbon (WCAC) prepared from waste citrus peel, the effects of operating parameters on the TMP adsorption were investigated by using a response surface methodology (RSM). Batch experiments were carried out according to a four-factor Box-Behnken experimental design with four input parameters : concentration ($X_1$: 50-150 mg/L), pH ($X_2$: 4-10), temperature ($X_3$: 293-323 K), adsorbent dose ($X_4$: 0.05-0.15 g). The experimental data were fitted to a second-order polynomial equation by the multiple regression analysis and examined using statistical methods. The significance of the independent variables and their interactions was assessed by ANOVA and t-test statistical techniques. Statistical results showed that concentration of TMP was the most effective parameter in comparison with others. The adsorption process can be well described by the pseudo-second order kinetic model. The experimental data of isotherm followed the Langmuir isotherm model. The maximum adsorption amount of TMP by WCAC calculated from the Langmuir isotherm model was 144.9 mg/g at 293 K.

Effect of $N_2$-back-flushing Time and TMP in Lake Water Treatment Using Multichannel Ceramic Microfiltration Membranes (다채널 세라믹 정밀여과막으로 호소수 처리시 질소 역세척 시간 및 막간 압력차의 영향)

  • Park, Jin-Yong;Park, Bo-Reum
    • Membrane Journal
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    • v.17 no.2
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    • pp.124-133
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    • 2007
  • In this study, we treated lake water by 2 kinds of multichannel ceramic micro filtration membranes. We could investigate effects of $N_2-back-flushing$ time (BT) and transmembrane pressure (TMP), and find optimal operating conditions. The BT were changed in $10{\sim}60$ sec, TMP in $0.6{\sim}2.0$ bar at fixed filtration time (FT) 8 min, flow rate 2.0 L/min and back-flushing pressure 2.0 bar. Also, the optimal conditions were discussed in the viewpoints of resistance of membrane fouling $(R_f)$, dimensionless permeate flux $(J/J_o)$, permeate flux (J) and total permeate volume $(V_T)$. As result, optimal back-flushing conditions for HC04 ($0.4{\mu}m$ pore size) and HC10 membrane $(1.0{\mu}m)$ were BT=10 sec and BT=20 sec, respectively. Then, higher TMP should increase the driving force, and could produce more VT. Average rejection rates of pollutants were higher than 95.4% for turbidity, $12.7{\sim}20.1%\;for\;COD_{Mn},\;0.0{\sim}6.4%\;for\;NH_3-N,\;1.9{\sim}4.6%$ for T-N and $34.9{\sim}88.4%$ for T-P.

Anti-Proliferation Effects and Molecular Mechanisms of Action of Tetramethypyrazine on Human SGC-7901 Gastric Carcinoma Cells

  • Ji, Ai-Jun;Liu, Sheng-Lin;Ju, Wen-Zheng;Huang, Xin-En
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.8
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    • pp.3581-3586
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    • 2014
  • Aim: To investigate the effects of tetramethypyrazine (TMP) on proliferation and apoptosis of the human gastric carcinoma cell line 7901 and its possible mechanism of action. Methods: The viability of TMP-treated 7901 cells was measured with a 3-(4, 5-dimethyl-thiazol-2-yl)-2,5-diphenyltetrazolium bromide assay (MTT) and cell apoptosis was analyzed by flow cytometry. The distribution of cells in different phases of cell cycle after exposure of TMPs was analyzed with flow cytometry. To investigate the molecular mechanisms of TMP-mediated apoptosis, the expression of NF-${\kappa}Bp65$, cyclinD1 and p16 in SGC-7901 cells was analyzed by reverse transcription-polymerase chain reaction (RT-PCR) and western blotting. Results: TMP inhibited the proliferation of human gastric carcinoma cell line 7901 in dose and time dependent manners. Cell growth was suppressed by TMP at different concentrations (0.25, 0.5, 1.0, 2.0 mg/ml), the inhibition rate is 0.46%, 4.36%, 14.8%, 76.1% (48h) and 15.5%, 18.5%, 41.2%, 89.8% (72h) respectively. When the concentration of TMPs was 2.0mg/ml, G1-phase arrest in the SGC-7901 cells was significant based on the data for cell cycle distribution. RT-PCR demonstrated that NF-${\kappa}Bp65$ and cyclin D1 mRNA expression was significantly down-regulated in 7901 cells treated with 2.0 mg/ml TMP for 72h (p<0.05), while the p16 mRNA level was up-regulated (p<0.05). The protein expression of NF-${\kappa}Bp65$ and cyclin D1 decreased gradually with the increase in TMP concentration, compared with control cells (p<0.05), while expression of protein p16 was up-regulated (p<0.01). Conclusion: TMP exhibits significant anti-proliferative and pro-apoptotic effects on the human gastric carcinoma cell line SGC-7901. NF-${\kappa}Bp65$, cyclinD1 and p16 may also play important roles in the regulation mechanisms.