• 제목/요약/키워드: TMA

검색결과 584건 처리시간 0.027초

첨가제를 포함한 TMA포접화합물의 열물성에 관한 기초적 연구 (A Basic Study on Thermal Properties of TMA Clathrate with Additives)

  • 고광옥;정낙규;김진홍
    • 설비공학논문집
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    • 제13권11호
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    • pp.1097-1105
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    • 2001
  • The purpose of this study is to investigate the propriety of TMA clathrate as a cold storage medium. Particularly, this is to examine the extent of subcooling improvement when the additives are added to the TMA clathrate, because water used cold storage material has low phase change temperature and subcooling. This study has been analysed and compared with TMA 30 wt% clathrate how phase change temperature, subcooling and specific heat in the various concentrations are changed. This results view to be improved phase change temperature and subcooling of TMA 30 wt% as a cold storage medium, when it had some additive. Additional1y, it is found that the additive must be controlled under available solution limit and study for new additive must be lasted to know its effect.

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A review on thermomechanical properties of polymers and fibers reinforced polymer composites

  • Saba, N.;Jawaid, M.
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.1-11
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    • 2018
  • Polymer composites offered broad engineered applications, however their diversity get restricted owing to fluctuations in thermomechanical properties during heating or cooling hence great concern required prior their applications through thermomechanical analysis (TMA). Traditionally, TMA or dilatometry found to be simple, ideal, reliable, sensitive, excellent and basic thermal analytical technique. TMA provides valuable information on thermal expansion, glass transitions temperature (Tg), softening points, composition and phase changes on material of having different geometries simply by applying a constant force as a function of temperature. This compilation highlights the basics and experimental of TMA for both research and technical applications and also provide literature on TMA of polymers, hybrid composites, nanocomposites and their diverse applications.

헤드스페이스-SPME 방법을 이용한 트리메틸아민의 분석방법 연구 (The Analysis of Airborne Trimethylamine Using a Headspace (HS)-SPME Method)

  • 안지원;김기현
    • 한국대기환경학회지
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    • 제24권3호
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    • pp.357-366
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    • 2008
  • In this study, the analytical performance of trimethylamine (TMA) were investigated with respect to headspace-solid phase microextraction (HS-SPME) method. In order to induce the elution of aqueous TMA to headspace, NaOH was added as a decomposition reagent to aqueous TMA standard. By controlling the combination of three major variables for TMA extraction, the extent of extraction was compared between the two contrasting conditions for each variable (i.e., reaction time (long (L) vs short (S)), exposure temperature (30 vs $50^{\circ}C$), and exposure time (10 vs 30 min)). The results of this comparative analysis showed that the extraction efficiency for all eight types of HS-SPME combinations decreased on the order: L-30-30>L-50-10>L-30-10>L-50-30>S-30-30>S-50-30>S-50-10>S-30-10. The effect of reaction time appeared to exert significant influences on the relative recovery rate of HS-SPME at 90% confidence level. However, the effects of exposure temperature or exposure time were not so significant as reaction time. When the recovery rate of HS-SPME is compared against the direct injection of liquid standard into GC injector, it recorded as 2%. According to this comparative study, the reaction conditions for HS-SPME application can exert significant influences on the analysis of TMA.

혈전성 미세혈관병증의 병리 (Pathology of Thrombotic Microangiopathy)

  • 설미영
    • Childhood Kidney Diseases
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    • 제17권1호
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    • pp.6-12
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    • 2013
  • 사구체에 면역글로불린은 음성이면서 C3 만 침착되는 경우, 다른 원인이 없는 경우 C3GN을 의심하여야 한다. 광학현미경으로는 세포의 증식이 있는 경우와 없는 경우가 있지만, 전자현미경으로는 EDD가 내피세포 밑으로 혹은 메산지움 등에 침착함을 확인하여야 한다. 대체보체경로의 조절이상이 원인임으로 혈청 C3 치를 비롯하여 CFH, CFI, CFB 등을 측정하여야 하며, C3 nephritic factor, antifactor H 자가항체 등을 조사하는 것이 필요하다. 보체 조절이상을 일으키는 유전자 돌연변이를 조사해 보아야 한다. 예후는 안정적이지만, 치료는 대증적이다. 이론적으로 보체의 활성화를 저지하는 약으로 가능할 것으로 생각되며, C5 항체인 eculizumab으로 치유된 보고도 있다.

냉장 및 냉동어육의 화학적 선도지표 측정 (Determination of Chemical Freshness Indices for Chilled and Frozen Fish)

  • 김동경;박인선;김남수
    • 한국식품과학회지
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    • 제30권5호
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    • pp.993-999
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    • 1998
  • 어육의 화학적 선도지표로는 사후의 경과 시간에 따라 $K_i$값과 biogenic amines, trimethylamine (TMA), 휘발성 염기질소(VBN) 등의 함량이 이용되고 있다. 이 중 $K_i$값은 초기 선도지표로 활용가능하며 신뢰성이 우수하여 어육 등의 선도측정에 간편하게 사용할 수 있다. 본 실험에서는 2종의 냉장 및 냉동어육에 대하여 $K_i$값과 biogenic amines, TMA 및 VBN 함량을 측정하였다. 대개의 시료에서 $K_i$값은 $7.8{\sim}43.6%$범위에 있었으며, 오징어, 굴, 대구, 수조기, 우럭은 $K_i$값이 높은 어종으로 나타났다. 한편 putrescine 등의 biogenic amines은 시료 중에서 검출되지 않았고, TMA 함량과 휘발성 염기질소 함량 사이에는 양의 상관관계(r=0.894)가 인정되었다.

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The Cooling Characteristics of Clathrate Compound according to Concentration of TMA

  • Lee, Jong-In;Kim, Chang-Oh;Chung, Nak-Kyu
    • International Journal of Air-Conditioning and Refrigeration
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    • 제17권1호
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    • pp.32-36
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    • 2009
  • The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N$) of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25 wt% has the average phase change tempera ture of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

Highly Sensitive and Selective Trimethylamine Sensor Using Yolk-shell Structured Mo-doped Co3O4 Spheres

  • Kim, Tae-Hyung;Kim, Ki Beom;Lee, Jong-Heun
    • 센서학회지
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    • 제28권5호
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    • pp.271-276
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    • 2019
  • Pure and 0.5, 1, 2, 5, and 10 at% of Mo-doped $Co_3O_4$ yolk-shell spheres were synthesized by ultrasonic spray pyrolysis of droplets containing Co nitrate, ammonium molybdate, and sucrose and their gas sensing characteristics to 5 ppm trimethylamine (TMA), ethanol, p-xylene, toluene, ammonia, carbon monoxide, and benzene were measured at $225-325^{\circ}C$. The sensor using pure $Co_3O_4$ yolk-shell spheres showed the highest response to p-xylene and very low response to TMA at $250^{\circ}C$, while the doping of Mo into $Co_3O_4$ tended to increase the overall responses of gas sensors. In particular, the sensor using 5 at% Mo-doped $Co_3O_4$ yolk-shell spheres exhibited the high response to TMA with low cross-responses to other interfering gases. The high response and selectivity of Mo-doped $Co_3O_4$ yolk-shell spheres to TMA are attributed to the electronic sensitization by higher valent Mo doping and acid-base interaction between TMA and Mo components.

모발분석 및 처리를 위한 한국형 의료 정보 시스템 구축 (Implementation of Medical Information System for Korean by Tissue Mineral Analysis)

  • 조영임
    • 한국멀티미디어학회논문지
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    • 제6권1호
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    • pp.148-160
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    • 2003
  • 현재 세계 48개국의 의료기관에서 임상을 위해 널리 사용 중인 모발분석(TMA)은 중요 미네랄 비율을 분석하여 체내에 과잉, 결핍 및 불균형 상태를 평가하고 인체에 미치는 영향을 예측하여 건강유지 방향을 제시하는 임상 영양학 및 독성학 검사방법을 말한다. 그러나 국내 모발분석방법에는 몇 가지 문제점이 있다. 즉, 모발분석결과를 처리하고 해석할 수 있는 한국형 의료정보 데이터베이스가 없으므로 미국에 의뢰하고 있는데, 외화낭비는 물론 보내오는 모발분석 검사결과지가 영문이고 철저한 보안 위주파일이므로 국내의료 기관에서의 활용도가 매우 낮다. 또한 모발분석 결과가 서구식 데이터베이스로부터 분석된 것이므로 검사결과의 신뢰성 문제도 발생한다. 따라서 본 논문에서는 이러한 문제점을 해결하기 위해 국내 최초로 TMA 기반 한국형 의료정보시스템을 구축하였다. 이 시스템은 복잡한 모발분석 자료의 분류를 다단계 통계분석 방법에 의한 결정트리 분류기를 통해 수행하고, 다중 퍼지 규칙방식의 데이터베이스를 구축하여 지능형 퍼지추론 방법에 의해 모발분석 자료를 분석한다. 본 시스템의 성능을 실제 작업 환경에서 측정한 결과, 시스템을 사용하는 경우가 사용하지 않았을 경우보다 업무능률과 사용자 만족도가 각각 86%, 92% 증가하였다.

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발효식품에서 분리된 Saccharomyces cerevisiae를 이용한 Trimethylamine 저감화 (Reduction of Trimethylamine by Saccharomyces cerevisiae Isolated from Fermented Food)

  • 박슬기;이재화;조두민;강민균;장유미;조연진;홍동리;김영목
    • 한국수산과학회지
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    • 제52권2호
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    • pp.121-126
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    • 2019
  • Trimethylamine (TMA) is a nitrogen-based aliphatic organic compound. It is a major odorous component of fish and fishery products and is often used as an indicator of fish quality. The efficacy of TMA removal by various yeast strains was investigated. The five yeast strains found to be most effective in removing TMA were isolated from fermented foods and were identified as Saccharomyces cerevisiae based on biochemical and 18S rRNA sequence analyses. These strains were designated as S. cerevisiae SK1511, SK1512, SK1513, SK1514 and SK1515. Yeast cultures were treated with a TMA solution (0.3%, v/v), and the level of TMA reduction was analyzed by headspace gas chromatography. The five S. cerevisiae strains removed 32.02-50.34% of the TMA from the solution. This study is the first to demonstrate TMA reduction by microbial treatment.

ZnO 막막 센서의 TMA 가스 검지 특성 분석 (The analysis on TMA gas-sensing characteristics of ZnO thin film sensors)

  • 류지열;박성현;최혁환;김진섭;이명교;권태하
    • 전자공학회논문지D
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    • 제34D권12호
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    • pp.46-53
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    • 1997
  • The TMA gas sensors are fabricated with the ZnO-based thin films grown by a RF magnetron sputtering method. The hall effect measurement and AES analysis are carried out to investigate the effects of the sputtering gases and dopants which effect on the electrical resistivity and sensitivity to TMA gas. We measure the cfhanges of the surface carrier concentration, haall electron mobility, electrical resistivity, surface condition, and depth profile of the films. The ZnO-based thin film sensors sputtered in oxygen, or added with dopants showed a high sruface carrier concentration, film sensors sputtered in oxygen and doped with 4.0 wt.% $Al_{2}$O$_{3}$, 1.0 wt.% TiO$_{2}$, and 0.2 wt% v$_{2}$O$_{5}$ showed the highest surface carrier concentration of 5.952 * 10$^{20}$ cm$^{-3}$ , hall electron mobility of 176.7 cm$^{2}$/V.s, lowest electrical resistivity of 6*10$^{-5}$ .ohm.cm and highest sensitivity of 12. These results were measured at a working temperature of 300.deg. C to 8 ppm TMA gas.

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