Browse > Article
http://dx.doi.org/10.5572/KOSAE.2008.24.3.357

The Analysis of Airborne Trimethylamine Using a Headspace (HS)-SPME Method  

Ahn, Ji-Won (Department of Earth & Environmental Sciences, Sejong University)
Kim, Ki-Hyun (Department of Earth & Environmental Sciences, Sejong University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.24, no.3, 2008 , pp. 357-366 More about this Journal
Abstract
In this study, the analytical performance of trimethylamine (TMA) were investigated with respect to headspace-solid phase microextraction (HS-SPME) method. In order to induce the elution of aqueous TMA to headspace, NaOH was added as a decomposition reagent to aqueous TMA standard. By controlling the combination of three major variables for TMA extraction, the extent of extraction was compared between the two contrasting conditions for each variable (i.e., reaction time (long (L) vs short (S)), exposure temperature (30 vs $50^{\circ}C$), and exposure time (10 vs 30 min)). The results of this comparative analysis showed that the extraction efficiency for all eight types of HS-SPME combinations decreased on the order: L-30-30>L-50-10>L-30-10>L-50-30>S-30-30>S-50-30>S-50-10>S-30-10. The effect of reaction time appeared to exert significant influences on the relative recovery rate of HS-SPME at 90% confidence level. However, the effects of exposure temperature or exposure time were not so significant as reaction time. When the recovery rate of HS-SPME is compared against the direct injection of liquid standard into GC injector, it recorded as 2%. According to this comparative study, the reaction conditions for HS-SPME application can exert significant influences on the analysis of TMA.
Keywords
TMA; Decomposition reagent; Headspace; SPME; Direct injection;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 김만구, 박수미, 정탁교, 장미옥, 이철원, 이민도, 한진석(2006) 헤드스페이스-GC/FID를 이용한 대기 중 트리메틸아민 분석법 개발, 한국냄새환경학회지, 5(4), 226-236
2 장순응(2007) 고체상미량분석법(SPME)에 의한 NDMA(N-Nitrodimethylamine) 최적 분석법 개발, 한국환경분석학회지, 10(1), 1-7
3 환경부(2007) 악취공정시험방법
4 Chien, Y.-C., S.-N. Uang, C.-T. Kuo, T.-S. Shih, and J.-F. Jen (2000) Analytical method for monitoring airborne trimethylamine using solid phase micro-extration and gas chromatography-flame ionization detection, Analytica Chimica Acta, 419, 73-79   DOI   ScienceOn
5 Kataoka, H., H.L. Lord, and J. Pawliszyn (2000) Application of solid-phase microextraction in food analysis, Journal of Chromatography A, 880, 35-62   DOI   ScienceOn
6 Stashenko, E.E. and J.R. Martinez (2004) Derivatization and solid-phase microextraction, Trends in Analytical Chemistry, 23(8), 553-561   DOI   ScienceOn
7 안지원, 송희남, 임문순, 김재민, 이지원(2007) GC/NPD를 이용한 Trimethylamine 검량특성에 대한 연구, 한국환경분석학회지, 10(2), 105-113
8 양성봉, 김석만(1999) 악취관리제도의 국가간 비교연구, 한국대기환경학회지, 16(1), 79-87
9 허귀석, 유연미, 김용두(2004) SPME-Capillary/GC-NPD에 의한 공기중 극미량 트리메틸아민 악취측정법 개발, 한국냄새환경학회지, 3(2), 99-108
10 Nagata, Y. (2003) Measurement of odor threshold by triangle odor bag method, Japan MOE, 118-127
11 Chang, C.-T., B.-Y. Chen, I.S. Shiu, and F.-T. Jeng (2004) Biofil-tration of trimethylamine-containing waste gas by entrapped mixed microbial cells, Chemosphere, 55, 751-756   DOI   ScienceOn
12 Gostelow, P., S.A. Parsons, and R.M. Stuetz (2001) Odour measurement for sewage treatment works, Water research, 35(3), 579-597   DOI   ScienceOn
13 Penalver, A., E. Pocurull, F. Borrull, and R.M. Marce (1999) Trends in solid-phase microextraction for determining organic pollutants in environmental samples, Trends in Analytical Chemistry, 18(8), 557-568   DOI   ScienceOn
14 정경훈, 서병량, 정만호, 전준민, 박귀환, 이영재(2005) SPME 법을 이용한 트라이베틸아민의 분석재현성 향상에 대한 연구, 한국냄새환경학회지, 4(3), 141-147
15 Mitsubayashi, K., Y. Kubotera, K. Yano, Y. Hashimoto, T. Kon, S. Nakakura, Y. Nishi, and H. Endo (2004) Trimethylamine biosensor with flavin-containing monooxygenase type 3 (FMO3) for fish-freshness analysis, Sensor and Actuators B, 103, 463-467   DOI   ScienceOn
16 임문순, 송희남, 김기현, 사재환(2007) SPME에 기초한 VOC 및 주요 악취물질들의 상대적 검량특성에 대한연구, 한국대기환경학회지, 23(1), 39-49   과학기술학회마을   DOI
17 최여진, 전의찬, 김기현(2005) 반월공단의 대기배출시설을 대상으로 한 악취성 황화합물의 측정과 배출특성에 대한 연구, 한국대기환경학회지, 21(5), 515-524   과학기술학회마을