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Study on Sonochemical Synthesis and Characterization of CdTe Quatum Dot (초음파 방법을 이용한 CdTe 양자점의 합성 및 특성에 관한 연구)

  • Yoo, Jeong-yeol;Kim, Woo-seok;Park, Seon-A;Kim, Jong-Gyu
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.571-575
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    • 2017
  • In this study, cadmium telluride (CdTe) quantum dots were synthesized by using ultrasonic irradiation method. Optical properties and structural characteristics of the CdTe quantum dots were analyzed by two main variables; the ratio of the precursor and the synthesis time. As the synthesis time increased, the band gap reduction was observed with the growth of CdTe quantum dots. As for the luminescence properties, the red shift appeared at 510~610 nm wavelength range. Also, it was confirmed that the red shift occurs rapidly as the ratio of Te increases. According to PL peak intensity, the highest intensity was shown at 180 to 240 min. Structural characteristics of CdTe quantum dots were investigated through XRD and TEM, and the cubic zinc blend structure was observed. The size of quantum dots was about 2.5 nm and uniformly dispersed when the synthesis time took 210 min. In addition, the apparent crystallinity was discovered in FFT image.

Thermoelectric properties of Bi2Te2.7Se0.3 grown by traveling heater method (Traveling heater method에 의해 성장된 Bi2Te2.7Se0.3의 열전특성)

  • Roh, Im-Jun;Hyun, Dow-Bin;Kim, Jin-Sang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.135-139
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    • 2015
  • $Bi_2Te_3-Bi_2Se_3$ alloy which is typical n-type thermoelectric material were grown by traveling heater method (THM) technique. We investigate the effect of the composition of $100-x(Bi_2Te_3)-x(Bi_2Se_3)$ and doping of n-type dopants such as $SbI_3$ and $CdCl_2$. Maximum figure of merit of $Bi_2Te_3-Bi_2Se_3$ alloy was observed with $CdCl_2$ 0.1 wt% (Z: $2.73{\times}10^{-3}/K$) and $SbI_3$ 0.05 wt% (Z: $2.29{\times}10^{-3}/K$). Deviation along the length of $Bi_2Te_3-Bi_2Se_3$ ingot grown by THM method is low, which indicates that the ingot is very homogenized. Also we observed the close relationship of between anisotropy ratio and dopant in the $90(Bi_2Te_3)-10(Bi_2Se_3)$ alloys. And we confirmed the fact that anisotropy ratio exerts thermoelectric performance in $Bi_2Te_3$ based n-type thermoelectric material.

Thermal Analysis of $Bi_2Te_3$ Based Thernoelectric Compound Powder Produced by Mechanical Alloying (기계적 합금화법으로 제조된 $Bi_2Te_3$계 열전화합물 분말의 열분석)

  • Kim, Bong-Seo;Yang, Jun-Hyeok;Oh, Min-Wook;Park, Su-Dong;Lee, Hee-Woong;Park, Kyu-Seop;Bae, Dong-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.151-152
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    • 2006
  • Bi-Te thermoelectric powder was fabricated by mechanical alloying method for 1 to 10 hours under vacuum in planetary mill. We investigated the properties of mechanically alloyed Bi-Te powder by thermal analysis, X-ray diffractometer and FESEM with EDS Bi-Te raw material was formed to $Bi_2Te_3$ phase at condition over 3.5 hours of mechanical alloying time.

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The Optical Characteristics og Te$_{85}Ge_{15}$ Alloy According to Phase Transition (Te$_{85}Ge_{15}$ alloy의 상변화에 따른 광학적 연구)

  • 김병훈;모연한;이영종;정홍배;김종빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1989.06a
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    • pp.111-113
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    • 1989
  • This paper reports the optical characteristics of TeS$_{5}$ Ge$_{5}$ thin film. In phase diagram, TeS$_{5}$ Ge$_{5}$ has the eutetic point with the loweat melting point. Therfore, TeS$_{5}$ Ge$_{5}$ thin film will be melted by Diode Laser with low energy. TeS$_{5}$ Ge$_{5}$ thin films start to change the phase from amorphous to crystalline near 10$0^{\circ}C$, but perfectly change the phase at 28$0^{\circ}C$. As-deposit TeS$_{5}$ Ge$_{5}$ thin film start to change the phase to crystalline in enviroment og 66$^{\circ}C$ 80%RH.circ}C$ 80%RH.

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X-ray Response Characteristic of Zn in the Polycrystalline Cd1-xZnxTe Detector for Digital Radiography

  • Kang, Sang-Sik
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.2
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    • pp.28-31
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    • 2002
  • The Cdl-xZnxTe film was fabricated by thermal evaporation for the flat-panel X-ray detector. The stoichimetric ratio and the crystal structure of a polycrystalline Cd$_{1-x}$ Zn$_{x}$Te were investigated by EPMA and XRD, respectively. The leakage current and X-ray sensitivity of the fabricated films were measured to analyze the X-ray response characteristic of Zn in the polycrystalline CdZnTe thin film. The leakage current and the output charge density of Cd$_{0.7}$Zn$_{0.3}$Te thin film were measured to 0.37 nA/cm$^2$ and 260 pc/cm$^2$ at an applied voltage of 2.5 V/${\mu}{\textrm}{m}$, respectively. Experimental results showed that the increase of Zn doping rates in Cd$_{1-x}$ Zn$_{x}$Te detectors reduced the leakage current and improved the signal to noise ratio significantly.

Behavior of Pt, Sb, Te during Crystallization of Ore Magma (광화마그마에서의 백금, 안티모니, 테루리움 거동에 관한 연구 (II))

  • 김원사
    • Korean Journal of Crystallography
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    • v.9 no.2
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    • pp.153-158
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    • 1998
  • 백금족 원소의 광화 마그마 내에서의 지화학적·결정학적 거동을 밝히기 위하여 백금, 안티모니, 테루리움계를 선택하여 800℃에서 안정한 광물 또는 화합물의 종류와 이들의 공생군, 원소간의 고용한계 등에 대해 실험적으로 연구하였다. 순도가 높은 각 원소를 초기 반응 물질로 하였으며, 고순도 석영관을 용기로 사용하였으며, 화학 반응 생성물은 반사현미경의, X선회절분석기, 전자현미분석기 등을 사용하여 분석하였다. 800℃에서 안정한 화합물로는, 백금(Pt), PtSb(stumpflite), PtSb2(geversite), PtTe, Pt3Te4, Pt2Te3, PtTe2(moncheite)이다. 이 연구 결과로부터 800℃에서의 상평형다이아그램을 정립하였다. 이 온도에서는 stumpflite와 geversite 및 moncheite가 현저히 치환고용체를 이루는데 그 한계는 각각 10 at.% Te, 28.5 at.% Te, 19.5 at.% Sb이다. 특히 원소광물인 백금과 stumpflite 및 moncheite는 화학성분은 이들 광물을 포함하고 있는 광상의 생성온도를 제시해 주는 지질온도계 역할을 할 수 있다.

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Growth of ZnTe Thin Films by Oxygen-plasma Assisted Pulsed Laser Deposition

  • Pak, Sang-Woo;Suh, Joo-Young;Lee, Dong-Uk;Kim, Eun-Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.185-185
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    • 2011
  • ZnTe semiconductor is very attractive materials for optoelectronic devices in the visible green spectral region because of it has direct bandgap of 2.26 eV. The prototypes of ZnTe light emitting diodes (LEDs) have been reported [1], showing that their green emission peak closely matches the most sensitive region of the human eye. Another application to photovoltaics proved that ZnTe is useful for the production of high-efficiency multi-junction solar cells [2,3]. By using the pulse laser deposition system, ZnTe thin films were deposited on ZnO thin layer, which is grown on (0001) Al2O3substrates. To produce the plasma plume from an ablated ZnO and ZnTe target, a pulsed (10 Hz) YGA:Nd laser with energy density of 95 mJ/$cm^2$ and wavelength of 266 nm by a nonlinear fourth harmonic generator was used. The laser spot focused on the surface of the ZnO and ZnTe target by using an optical lens was approximately 1 mm2. The base pressure of the chamber was kept at a pressure around $10^{-6}$ Torr by using a turbo molecular pump. The oxygen gas flow was controlled around 3 sccm by using a mass flow controller system. During the ZnTe deposition, the substrate temperature was $400^{\circ}C$ and the ambient gas pressure was $10^{-2}$ Torr. The structural properties of the samples were analyzed by XRD measurement. The optical properties were investigated by using the photoluminescence spectra obtained with a 325 nm wavelength He-Cd laser. The film surface and carrier concentration were analyzed by an atomic force microscope and Hall measurement system.

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Comparison of Muscle Activities of Thoracic and Lumbar Extensors during Trunk Lift Exercises According to Exercise Position (운동 자세에 따른 몸통 들기 운동 시 가슴과 허리 폄 근육의 근활성도 비교)

  • Koh, Eun-Kyung;Jung, Do-Young
    • Korean Journal of Applied Biomechanics
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    • v.22 no.3
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    • pp.341-348
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    • 2012
  • The purpose of this study was to compare the muscle activities of the thoracic extensor(TE) and lumbar extensor(LE) during trunk lift (TL) exercise according to exercise position. Seventeen healthy subjects with no medial history of back pain were recruited for this study. Subjects performed the TL exercise in prone, quadruped and heel-sitting positions. The activities of the TE and LE were measured using surface electromyography during TL exercise in each exercise position. A one-way repeated-measures analysis of variance (ANOVA) was used to compare the normalized muscle activities of the TE and LE and the TE/LE ratio. The results showed that there was not significant effect of exercise position on the muscle activities of TE(p>.05). However, there was significant effect of exercise position on the muscle activities of LE and the TE/LE ratio(p>.05). Post hoc pair-wise comparisons with Bonferroni correction showed that both muscle activities of LE and TE/LE ratio in prone position were significantly different in those in heel-sitting and quadruped positions, during TL exercise, respectively. The TE/LE ratio was the greatest for TL exercise in heel-sitting position. Therefore, for selective activation of the TE muscle, we recommend performing the TL exercise in heel-sitting or quadruped position.

Fabrication of CdTe thin films by sputtering and its application on CdTe/CdS solar cells (Sputtering에 의한 CdTe박막제조 및 CdTe/CdS태양전지에의 응용)

  • Jung, H.W.;Lee, C.;Kim, S.;Shin, S.H.;Park, K.J.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1645-1647
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    • 1996
  • Polycrystalline CdTe thin films -have been studied for photovoltaic application because of their high absorption coefficient and optimal band gap energy (1.54 eV) for solar energy conversion. In this study, we prepared CdTe films using RF-magnetron sputtering method and investigated structural, optical and electrical properties with spectrophotometer, XRD, EDX, and resistivity meter. CdTe films at $200\;^{\circ}C$ showed a mixture of zinc blend (Cubic) and wurtzite (hexagonal) phase. On the other hand, the films at $400\;^{\circ}C$ showed highly oriented structure having hexagonal structure. The resistivity of CdTe films deposited on $SiO_2$ substrates was about $10_7\;{\Omega}cm$. The value of resistivity decreased with the increase of the substrate temperature. CdTe were sputtered on CdS thin films prepared by chemical bath deposition for the formation of the heterojunction. I-V characteristics of these cells were measured at a light density of $100mw/cm^2$, AM. 1.0. The present thin film solar cells showed a conversion efficiency of about 5%.

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Effect of Sputtering Conditions for CdTe Thin Films on CdTe/CdS Solar Cell Characteristics (스퍼터링에 의한 CdTe 박막 제조 조건이 CdTe/CdS 태양전지의 특성에 미치는 영향)

  • Jung, Hae-Won;Lee, Cheon;Shin, Jae-Heyg;Shin, Sung-Ho;Park, Kwang-Ja
    • Electrical & Electronic Materials
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    • v.10 no.9
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    • pp.930-937
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    • 1997
  • Polycrystalline CdTe thin films have been studied for photovoltaic application because of their high absorption coefficient and optimal band energy(1.45 eV) for solar energy conversion. In this study CdTe thin films were deposited on CdS(chemical bath deposition)/ITO(indium tin oxide) substrate by rf-magnetron sputtering under various conditions. Structural optical and electrical properties are investigated with XRD UV-Visible spectrophotometer SEM and solar simulator respectively. The fabricated CdTe/CdS solar cell exhibited open circuit voltage( $V_{oc}$ ) of 610 mV short circuit current density( $J_{sc}$ ) of 17.2 mA/c $m^2$and conversion efficiency of about 5% at optimal sputtering conditions.

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