• Title/Summary/Keyword: TE 5

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Synthesis and Characterization of New Intermetallic Compounds $M_3(AsTe_3)_2$ (M=Cr, Fe, Co)

  • 정진승;김현학;강석구;채원식;김돈;이성한
    • Bulletin of the Korean Chemical Society
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    • v.18 no.10
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    • pp.1105-1108
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    • 1997
  • The new amorphous intermetallic compounds, M3(AsTe3)2: M=Cr, Co, Fe, were synthesized by the precipitation reaction of the Zintl anion AsTe33- with the divalent transition metal halides in aqueous solution and analyzed by EDS equipped with SEM and PIXE. The empirical formula of the specimens was found to be Fe3.0As1.8Te5.9, Co3.0As2.1Te6.5, and Cr3.0As2.0Te6.9 by the quantitative elemental analysis. The dc specific resistivity of the materials was measured as a function of temperature in the range from 20 to 300 K, in which their resistivity of Cr3(AsTe3)2 was largely dependent on temperature, while those of Co3(AsTe3)2 and Fe3(AsTe3)2 were only slightly dependent on temperature. To characterize the spin glass state of the specimens, the ac and dc magnetic susceptibility were measured and it was found that Co3(AsTe3)2 and Fe3(AsTe3)2 undergo a transition to a spin glass state at 6 K and 38 K, respectively. Magnetization data are reported as both thermal remanent magnetization (TRM) and isothermal remanent magnetization (IRM) as a function of magnetizing field and temperature.

Photovoltaic Properties of Sintered Cd$_{1-x}$ZnxS/CdTe Heterojunction Solar Cells (소결체 Cd$_{1-x}$ZnxS/DdTe 이종접합 태양전기의 특성)

  • 설여송;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1989.06a
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    • pp.56-58
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    • 1989
  • All-polycrystalline Cd$_1$-xZnxS/CdTe solar cells have been fabricated by coating CdTe slurries with 4.5 wt% of CdCl$_2$on the sintered Cd$_1$-xZnxS films and by sintering CdTe layer at 6$25^{\circ}C$ for lh in nitrogen atmosphere. Solar efficiency of the sintered Cd$_1$-xZnxS/CdTe solar cells increases as the Zn content increases up to x=0.06 and then decreases with further increase in the Zn content. A solar efficiency of 12.5% under a solar intensity of 76mW/$\textrm{cm}^2$ was observed in a Cd 0.94 Zn0.06S/CdTe solar cell. By optimizing the amount of CdCl$_2$in the slurry and sintering conditions, it is possible to produce Cd$_1$-xZnxS/CdTe solar cells with efficiency higher than 12%.

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Preparation and Characteristics of Te Fine Particles Doped SiO2 Glass Thin Films by Sol-gel Method (졸-겔법에 의한 Te 미립자 분산 SiO2 유리 박막의 제조와 특성)

  • Mun, Chong-Soo;Kang, Bong-Sang
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.24-29
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    • 2004
  • Nanocomposite of Te doped $SiO_2$ films was prepared for the new functional materials like non-linear optic materials, selective absorption and transmission films. The effects of particle size and morphology with different hydrolysis conditions on the properties were examined with TGA/DTA. XRD. UV-spectrometer, SPM, SEM and EDS. It was found that Te/$SiO_2$ films showed high absorption peak at 550nm visible region by plasma resonance of Te fine particles. The Rm surface roughness of the films was about 2.5 nm and the size of Te particles was 5~10nm.

How are the Lower Lying Atoms Imaged Brighter than the Higher Lying Once in the STM Experiments?

  • Jeong, Dong Un
    • Bulletin of the Korean Chemical Society
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    • v.22 no.5
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    • pp.499-502
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    • 2001
  • Unexpectedly, the brightest row was known to represents the lowest lying Te atoms in the STM image of NbTe2. Projected density of states and crystal orbital overlap population show that the 5pz orbital of the lowest lying Te(2) atom doe s not interact with the 4d orbital of Nb strongly so that the 5pz band remains in the vicinity of the Fermi energy. Consequently the lowest lying Te(2) atoms contribute higher electron density near the Fermi energy which in turn exhibits brightest image in the STM experiments.

Switching Phenomena of AsTe Glass Semiconductor (AsTe계 유리반도체의 스위칭현상)

  • 박창엽
    • 전기의세계
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    • v.21 no.1
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    • pp.17-21
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    • 1972
  • Electrical resistivity and switching phenomena in glass semiconductor of AsTe and AsTeGa is studied. Samples sliced from ingot which is air quenched or water quenched, show high resistivity at room temperature. The resistivity of the AsTe and AsTeGa is 1*10$^{6}$ .ohm.-cm and 5*10$^{6}$ .ohm.-cm at 27.deg. C. Switching phenomena take place in thin the thick samples. Holding voltage is different with the thickness of the samples and the characteristics of switching in the thin and thick samhles are similar. When square wave pulse voltage is applied, delay time is detected to 5.mu.sec by oscilloscpoe.

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Phase Transformation Effect on Mechanical Properties of Ge2Sb2Te5 Thin Film (Ge2Sb2Te5 박막의 상변화에 의한 기계적 물성 변화)

  • Hong, Sung-Duk;Jeong, Seong-Min;Kim, Sung-Soon;Lee, Hong-Lim
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.326-332
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    • 2005
  • Phase transformation effects on mechanical properties of $Ge_2Sb_2Te_5$, which is a promising candidate material for Phase Change Random Access Memory (PRAM), were studied. $Ge_2Sb_2Te_5$ thin films, which was thermally annealed with different conditions, were analyzed using XRD, AFM, 4-point probe method and reflectance measurement. As the temperature and the dwelling time increased, crystallity and grain size increased, which enhanced elastic modulus and hardness. Furthermore, N2 doping, which was used for better electrical properties, was proved to decrease elastic modulus and hardness of $Ge_2Sb_2Te_5$.

Intermediate band solar cells with ZnTe:Cr thin films grown on p-Si substrate by pulsed laser deposition

  • Lee, Kyoung Su;Oh, Gyujin;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.247.1-247.1
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    • 2016
  • Low-cost, high efficiency solar cells are tremendous interests for the realization of a renewable and clean energy source. ZnTe based solar cells have a possibility of high efficiency with formation of an intermediated energy band structure by impurity doping. In this work, ZnO/ZnTe:Cr and ZnO/i-ZnTe structures were fabricated by pulsed laser deposition (PLD) technique. A pulsed (10 Hz) Nd:YAG laser operating at a wavelength of 266 nm was used to produce a plasma plume from an ablated a ZnTe target, whose density of laser energy was 10 J/cm2. The base pressure of the chamber was kept at approximately $4{\times}10-7Torr$. ZnTe:Cr and i-ZnTe thin films with thickness of 210 nm were grown on p-Si substrate, respectively, and then ZnO thin films with thickness of 150 nm were grown on ZnTe:Cr layer under oxygen partial pressure of 3 mTorr. Growth temperature of all the films was set to $250^{\circ}C$. For fabricating ZnO/i-ZnTe and ZnO/ZnTe:Cr solar cells, indium metal and Ti/Au grid patterns were deposited on back and front side of the solar cells by using thermal evaporator, respectively. From the fabricated ZnO/ZnTe:Cr and ZnO/i-ZnTe solar cell, dark currents were measured by using Keithley 2600. Solar cell parameters were obtained under Air Mass 1.5 Global solar simulator with an irradiation intensity of 100 mW/cm2, and then the photoelectric conversion efficiency values of ZnO/ZnTe:Cr and ZnO/i-ZnTe solar cells were measured at 1.5 % and 0.3 %, respectively.

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The Study for the Characteristics of Microwave Coupled $V_2$$O_5$-PbO-$TeO_2$Glass System (마이크로파 발열된 $V_2$$O_5$-PbO-$TeO_2$ 유리의 특성에 관한 연구)

  • 박희찬;이상은;김병우;박성수
    • Journal of the Korean Ceramic Society
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    • v.38 no.5
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    • pp.438-445
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    • 2001
  • 600 W의 마이크로파 출력 하에서 PbO, V$_2$O$_{5}$, TeO$_2$ 및 V$_2$O$_{5}$-PbO-TeO$_2$성분들의 마이크로파 발열 특성을 조사하였다. V$_2$O$_{5}$ 성분의 높은 마이크로파 흡수능에 기인하여 V$_2$O$_{5}$-PbO-TeO$_2$유리상 시편들은 마이크로파를 흡수하여 주어진 온도까지 직접 가열되었다. XRD, OM, SEM 및 고전압 발생 측정기를 통하여 재래식 열 및 마이크로파 공정에서 열처리된 시편들의 결정화 및 전기 전도도의 특성을 비교 조사하였다. PbV$_2$O$_{6}$ 및 Pb$_4$V$_2$O$_{9}$ 결정상들이 마이크로파 열처리된 시편에서는 존재하였다. 그러나, 재래식 열처리된 시편들에서는 존재하지 않는다는 것을 확인하였고, 재래식 열처리된 시편들에 비하여 마이크로파 열처리된 시편들의 전기 전도도 값이 상대적으로 높았다.

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Electrochemical Characterization of Multilayered CdTe/PSS Films Prepared by Electrostatic Self-assembly Method

  • Rabbani, Mohammad Mahbub;Yeum, Jeong Hyun;Kim, Jungsoo;Nam, Dae-Geun;Oh, Weontae
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.5
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    • pp.257-261
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    • 2014
  • Multilayered CdTe/PSS films were prepared by the electrostatic self-assembly method in an aqueous medium. Positively-charged cadmium telluride (CdTe) nanoparticles and anionic polyelectrolyte, poly (sodium 4-styrene sulfonate) (PSS) were assembled alternately in order to build up a multilayered film structure. A linear proportion of absorbance to the number of bilayers suggests that an equal amount of CdTe was adsorbed after each dipping cycle, which resulted in the buildup of a homogenous film. The binding energies of elements (Cd and Te) in multilayered CdTe/PSS film shifted from those of the CdTe nanoparticles in the pure state. This result indicates that the interfacial electron densities were redistributed by the strong electrostatic interaction between the oppositely-charged CdTe and PSS. Electrochemical properties of the multilayered CdTe/PSS films were studied in detail by cyclic voltammetry (CV).

MOVPE GROWTH OF HgCdTe EPILAYER WITH ARSENIC DOPING

  • Suh, Sang-Hee;Kim, Jin-Sang;Song, Jong-Hyeong;Kim, Je-Won
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.325-329
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    • 1996
  • We report on p-type arsenic doping of metalorganic vapor phase epitaxially (MOVPE) grown HgCdTe on (100) GaAs. HgCdTe was grown at $370^{\circ}C$ in a horizontal reactor with using dimethy-cadmium, diisoprophyltelluride, and elemental Hg. We used tris-dimethylaminoarsenic (DMAAs) as the metalorganic for p-doping. 4micron thick CdTe and subsequently 10micron thick HgCdTe were grown on (100) GaAs substrate. Interdiffused multilayer process in which thin CdTe and HgTe layers are grown alternately and interdiffused to obtain homogeneous HgCdTe alloys was used. Arsenic was doped during CdTe growth cycle. After growth HgCdTe was annealed at $415^{\circ}C$ for 15 min and then annealed again at $220^{\circ}C$ for 3 hr, both with Hg-saturate condition. We could obtain p-doping from 2.5$\times$$10^{16}$ to 6.6$\times$$10^{17}$$cm^{-3}$, depending on the DMAAs partial pressure. With the dual Hg-annealing, activation of arsenic was aboutt 90%, which was confirmed by SIMS measurement. With only low temperature annealing at $220^{\circ}C$ for 3hr, activation efficiency was about 50%.

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