• Tribology and Lubricants
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• v.25 no.6
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• pp.432-437
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• 2009

The effect of oxidation in SAE 5W30 engine oils on friction and wear characteristics was investigated using reciprocating bench tester and shell 4-ball tester. Commercial engine oils were collected and oxidized using the KS M 2021 method modifying the oxidation time. Kinematic viscosity, total acid number(TAN), FT-IR spectrum and total base number(TBN) also measured to examine the chemical change of oils with oxidation. The results showed that TAN was slightly changed and Kinematic viscosity was suddenly increased during the oxidation stage. however, TBN results keep a constant slope after TBN linearly decreased with oxidation time. Spectroscopy results showed that spectrums were orderly increased at $1710cm^{-1}$ during the oxidation time. Friction test results showed that oxidation of oils formed unstable friction layers causing higher fluctuating friction. however, the wear resistance was independent of oxidized time due to the different friction characteristics by oxidation. We found several factors in relation to lubrication properties with oxidation time. This factors were Viscosity, TBN, change of FT-IR spectrum, friction coefficient using reciprocating bench tester and wear scar.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1997.10a
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• pp.152-160
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• 1997

A diesel engine oil which was formulated and a commercial diesel engine oil (API CG4) made from same base oil were tested by car and analyzed of their physical, chemical and mechanical properties. The tested oil to be analyzed were sampled from engine every 1000 km until 8000 km and determined the kinematic viscosity, TAN, TBN, metal content in oil, additive depletion, antiwear property and IR analysis. From the study, both the tested oils were almost same properties for the change of TAN and TBN, but the change of kinematic viscosity of formulated oil was slightly higher than that of commercial oil. But the concentration of metal in the formulated oil, especially iron, were increased much less during test. The iron content of the commercial oil was increase rapidly from 7000 km while the formulated oil was still low. These results were conformed by the antiwear test by 4-ball wear test machine for the samples. Also for the commercial oil, the depletion factor of the Zn-DTP which was added as an antiwear property was not change any more after 7000 km. But the formulated oil was change continuously until 8000 km, which mean that the ability of wear protection of the sliding parts exists for the formulated oil. With the results which were analyzed of the properties of oils by field test, it was found that the commercial oil could be used only within 7000 km, but the formulated oil can use more than 8000 km without severe wear of the sliding parts in the diesel engine.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.7
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• pp.48-56
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• 2014

Engine oil is an oil used for lubrication of various internal combustion engines. The main function is to reduce wear on moving parts; it also cleans, inhibits corrosion, improves sealing, and cools the engine by carrying heat away from moving parts. In engines, there are parts which move against each other. Otherwise, the friction wastes the useful power by converting the kinetic energy to heat. Those parts were worn away, which could lead to lower efficiency and degradation of the engine. It increases fuel consumption, decreases power output, and can induce the engine failure. This study was conducted to evaluate the relation between engine oil property changes and engine performance for the diesel engine. This test was performed by using 12L, 6 cylinder, heavy duty engines. Low SAPS 10W30 engine oil (two type engine oils) was used. Test procedure and method was in accordance with the modified CEC L-57-T97 (OM441LA) method. In this study, TAN, TBN, KV and metal components, engine power, blowby gas, A_F were presented to evaluate the relation with engine oil property changes and engine performance. TAN, TBN, KV and metal We found that the components were generally increased but engine performance did not change. This results mean that property changes did not affect on engine performance because those were not enough to affect engine performance.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.3
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• pp.51-59
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• 2001

A diesel engine oil formulated in KRICT and a commercial diesel engine oil (API CG-4) were tested by car and their Kinematic Viscosity, TAN, TBN, metal content, additive depletion, anti-wear property and IR analysis were analyzed. From the research, both of the tested oils had almost the same properties f3r the change of TAN and TBN, but the change of Kinematic Viscosity of formulated oil was slightly higher than that of commercial oil. The iron content in the commercial oil increased rapidly from 7000 km while that of the formulated oil was still low. These results were confirmed by the anti-wear test with a 4-ball wear test machine for the each samples. Also, for the commercial oil, the depletion factor of the Zn-DTP which was added as an anti-wear property did not change any more after 7000 km. But, that of the formulated oil changed continuously to 8000 km, which means that the ability to prevent wear of the sliding pairs exists for the formulated oil. From the analysis results of oil properties obtained by field test, it was found that the commercial oil could be used only within 7000 km, but the formulated oil could be used more than 8000 km without severe wear of the sliding parts in the diesel engine.

• Tribology and Lubricants
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• v.10 no.4
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• pp.59-68
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• 1994

This study is concerned with the change of physical and chemical properties of the used oil in gasoline and LPG engine. The used oils of engine were sampled from dynamometer and cars. The field tests of car were done in city and on highway. The properties of oil were TAN, TBN, visocity, oxidation, ZDTP depletion factor and etc. Also the relation between the chemical change and antiwear property was studied. From the study, it was shown that the decrease of antiwear property of used oil was depended on the changes of ZDTP depletion factor as well as TAN (total acid number). Also, it was found that the oil used by LPG car was deteriorated within the shortest distance among the other gasoline cars. The antiwear property of oil decreased as the running distance increased. The gasoline engine oil drove mainly on highway was the least deteriorate of properities for the same running distance.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1995.06a
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• pp.18-24
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• 1995

본 연구에서는 두가지 엔진에 사용된 엔진오일의 성상변화를 측정하였다. 따라서 금속 마모입자 분석, 동점도 측정과 TAN 및 TBN 분석을 통한 물리적 성상과 화학적 성질 분석 그리고 적외선 분광 분석과 정량 폐로그라피 분석 등을 통하여 Table 1에 나타난 기준에 의해 오일의 수명을 판정하였다. 아울러 RPD를 이용하여 마모입자의 형상 등을 분석하고 엔진에서 발생하는 마모기구를 살펴보았다. 물론 본 연구는 주위 환경이 양호한 실험실에서 엔진 동력계에 의한 실험에 의존하였으므로 실제 주행실험 결과보다는 오일의 수명이 더 길게 나타날 것으로 예측된다. 더욱이 농경지에서 주로 사용되는 경운기의 경우는 오일이 먼지나 모래, 진흙 등에 의해 오손되기 쉬우므로 실제 오일의 수명은 훨씬 더 짧을 것으로 생각되므로 실차 주행실험 결과와의 비료는 앞으로 더 연구할 분야로 생각된다.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.11a
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• pp.347-352
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• 2000

Before investigating the performance of NA-Q additive oil, we have studied the properties of the commercial reference oil by using an engine dynamometer. Experimemts were conducted for 300 hours with 2,950rpm and 22kw and every 50 hours the used oil was sampled for analyzing its physical and chemical propreties. The reference oil shows stable but slightly increasing viscosities during the experiment. It has good agreements with the change of its TAN and TBN. Friction coefficients and anti-wear characteristics are compared with its ZDTP depletion factor and the diameters of wear scar. The concentrations of metal particles are analyzed with the results of ICP and spectrometer, However it is found that the concentrations by filtration method shows large difference with those by standard method in spectrometer.

• Tribology and Lubricants
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• v.30 no.3
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• pp.156-167
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• 2014

This paper presents the test results of small dipstick-gage-type engine-oil-deterioration-detection sensor. The measured sensor signal characteristics for the capacitance and temperature are analyzed. The engine oil deterioration condition correlates with the electrical property of the dielectric constant that comprised with physical properties such as TAN (Total Acid Number), TBN (Total Base Number) and viscosity. Several problems encontered during the test of the sensor system are improved. The results of vehicle tests show that the capacitance signal is stable after the engine stops. Therefore, the sensor should start measuring the parameters for monitoring the engine oil condition after the engine stops. The engine is considered to be in a stopped state if the difference between the maximum and minimum values of the oil capacitance measured every 1 min is below 0.02 pF. The key test results in this paper will help in the development of an engine oil change warning algorithm.

• Tribology and Lubricants
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• v.30 no.3
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• pp.168-176
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• 2014

This paper presents an engine oil change warning algorithm based on the test results of a small dip-stick-gage-type engine-oil-deterioration-detection sensor, software to realize the algorithm and a display device to apply the software. The algorithm determines the engine oil deterioration condition from the rate of change in the dielectric constant based on the average measured capacitance at $80^{\circ}C$ after the engine stops. The rate of change in the dielectric constant at the time for oil change correlates with the time that one of recommended warning limits for engine oil physical properties such as TAN (Total Acid Number), TBN (Total Base Number) and viscosity is first reached. At this point, a warning signal for oil change appears on the display device like a smart-phone or individual display device. The frames of smartphone app have three stages. The user can directly input all of the thresholds into the frame of the smartphone app. The screen of the display device comprises one frame for each warning signature with the related message. The user can input the thresholds to the device through a USB cable connected to a personal computer.

• Tribology and Lubricants
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• v.30 no.4
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• pp.224-233
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• 2014

We prepared polyester-polyamines to improve the effect of carbon black dispersibility for use in thermal transfer ink, and synthesized polymeric dispersing agents by two-step reactions. In the first step, we made polyester by polycondensing 1,6-hexanediol and adipic acid. The resulting polymers had carboxylic acid, which was linked with polyamine via an acid-base reaction. We then characterized the polyester-polyamine structure by NMR spectroscopy and Fourier transform infrared spectroscopy (FT-IR). We also determined the basic characterizations such as total acid numbers (TAN) (5.0-67.5 mgKOH/g), hydroxyl values (27.1-67.5 mgKOH/g), and molar masses ($M_n=1.6-8.4kg\;mol^{-1}$) for the polyester and total base numbers (TBN) (15.3-57.1 mgKOH/g), hydroxyl values (33.0-79.8 mgKOH/g), and nitrogen contents (1.02-3.48%) for the polyester-polyamine polymers. We thus prepared thermal transfer ink using carbon blacks and the polyester-polyamine dispersing agents, and evaluated the resulting mixtures for printability, adhesive force, storage stability, ink appearance, ink gloss, and processability. These mixtures showed significant dispersibility for carbon black in the ink. Thus, we concluded that the dispersibility of the polymeric materials depended on the polyamine structure and the hydrophilicity-hydrophobicity distribution of the polymeric dispersants.