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http://dx.doi.org/10.9725/kstle.2014.30.4.224

Synthesis of Polyester-Polyamine Dispersants and Their Carbon Dispersing Properties  

Son, Jeong-Mae (Integrated Chemistry Research Division, Industrial Bio-based Materials Research Group, KRICT)
Yuk, Jeong-Suk (Integrated Chemistry Research Division, Industrial Bio-based Materials Research Group, KRICT)
Lee, Sangjun (Department of Green Chemistry and Environmental Biotechnology, University of Science & Technology (UST))
Kim, Juhyun (Jeonnam Science High School)
Kim, Nam-Kyun (Integrated Chemistry Research Division, Industrial Bio-based Materials Research Group, KRICT)
Shin, Jihoon (Integrated Chemistry Research Division, Industrial Bio-based Materials Research Group, KRICT)
Kim, Young-Wun (Integrated Chemistry Research Division, Industrial Bio-based Materials Research Group, KRICT)
Publication Information
Tribology and Lubricants / v.30, no.4, 2014 , pp. 224-233 More about this Journal
Abstract
We prepared polyester-polyamines to improve the effect of carbon black dispersibility for use in thermal transfer ink, and synthesized polymeric dispersing agents by two-step reactions. In the first step, we made polyester by polycondensing 1,6-hexanediol and adipic acid. The resulting polymers had carboxylic acid, which was linked with polyamine via an acid-base reaction. We then characterized the polyester-polyamine structure by NMR spectroscopy and Fourier transform infrared spectroscopy (FT-IR). We also determined the basic characterizations such as total acid numbers (TAN) (5.0-67.5 mgKOH/g), hydroxyl values (27.1-67.5 mgKOH/g), and molar masses ($M_n=1.6-8.4kg\;mol^{-1}$) for the polyester and total base numbers (TBN) (15.3-57.1 mgKOH/g), hydroxyl values (33.0-79.8 mgKOH/g), and nitrogen contents (1.02-3.48%) for the polyester-polyamine polymers. We thus prepared thermal transfer ink using carbon blacks and the polyester-polyamine dispersing agents, and evaluated the resulting mixtures for printability, adhesive force, storage stability, ink appearance, ink gloss, and processability. These mixtures showed significant dispersibility for carbon black in the ink. Thus, we concluded that the dispersibility of the polymeric materials depended on the polyamine structure and the hydrophilicity-hydrophobicity distribution of the polymeric dispersants.
Keywords
carbon dispersion; polyester-polyamine dispersant; thermal transfer ink;
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Times Cited By KSCI : 5  (Citation Analysis)
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1 Merilampi, S., Laine-Ma, T., Ruuskanen, P., "The characterization of electrically conductive silver ink patterns on flexible substrates", Microelectronics Reliability, Vol. 49, No. 7, 2009. (782-790)   DOI   ScienceOn
2 Merilampi, S. L., Bjorninen, T., Vuorimaki, A., Ukkonen, L., Ruuskanen, P., Sydanheimo, L., "The Effect of Conductive Ink Layer Thickness on the Functioning of Printed UHF RFID Antennas", Proceedings of The Ieee, Vol. 98, No. 9, 2010. (1610-1619)   DOI
3 Bjorninen, T., Merilampi, S., Ukkonen, L., Ruuskanen, P., Sydanheimo, L., "Performance Comparison of Silver Ink and Copper Conductors for Microwave Applications", Iet Microwaves Antennas & Propagation, Vol. 4, No. 9, 2010. (1224-1231)   DOI
4 Merilampi, S., Bjorninen, T., Haukka, V., Ruuskanen, P., Ukkonen, L., Sydanheimo, L., "Analysis of Electrically Conductive Silver Ink on Stretchable Substrates under Tensile Load", Microelectronics Reliability, Vol. 50, No. 12, 2010. (2001-2011)   DOI
5 Merilampi, S. L., Bjorninen, T., Ukkonen, L., Ruuskanen, P., Sydanheimo, L., "Characterization of UHF RFID Tags Fabricated Directly on Convex Surfaces by Pad Printing", International Journal Of Advanced Manufacturing Technology, Vol. 53, No. 5-8, 2011. (577-591)   DOI
6 Lee, M. Y., Bae, K. E., Kim, S. H., Lim, S. C., Nam, S. Y., "Effect of Dispersant Contents on the Dispersity of Conductive Carbon-black and Properties of Screen-printed Source-drain Electrodes for OTFTs", Polymer, Vol. 33, No. 5, 2009. (397-406)
7 Goual, L., Sedghi, M., Wang, X., Zhu, Z., "Asphaltene Aggregation and Impact of Alkylphenols", Langmuir, Vol. 30, 2014. (5394-5403)   DOI
8 Zhang, Z., Qu, C., Zheng, T., Lai, Y., Li, J., "Effect of Triton X-100 as Dispersant on Carbon Black for $LiFePO_4$ Cathode", Int. J. Electrochem. Sci., Vol. 8, 2013. (6722-6733)
9 E1899-97, "Standard Test Method for Hydroxyl Groups Using Reaction with p-Toluenesulfonyl Isocyanate (TSI) and Potentiometric Titration with Tetrabutylammonium Hydroxide", ASTM international, West Conshohocken, PA, 2013.
10 D2896, "Standard Test Method for Base Number of Petroleum Products by Potentiometric Perchloric Acid Titration", ASTM international, West Conshohocken, PA, 2012.
11 Lee, S., Na, Y., "Effect of roll patterns on the Ink transfer in R2R printing process", International Journal of Precision Engineering and Manufacturing, Vol. 10, 2009. (123-130)   과학기술학회마을   DOI
12 Ha, Y. W., Chung J. H., Heo, P. S., "Printed Electronics, Future of the Electronics", Electronics and Telecommunication Trend, Vol. 26, No. 2, 2011. (111-125)
13 Yoon, S. H., Lee, J., Lee, S. H., Lee, B.-J., Shin, J.-K, "A Study on Processing of TFT Electrodes for Digital Sinnage Display using a Reverse Offset Printing", J. Korean Soc. Precis. Eng., Vol. 31, No. 6, 2014. (497-504)   DOI
14 Calson, A., Bowen, A. M., Huang, Y., Nuzzo, R. G., Rogers, J. A., "Transfer Printing Techniques for Materials Assembly and Micro-Nanodevice Fabrication", Advanced Materials, Vol. 24, 2012. (5284-5318)   DOI
15 Lee, S., Na, Y., "Analysis on the Ink Transfer Mechanism in R2R Application", Journal of Mechanical Science and Technology, Vol. 24, 2010. (293-296)   DOI
16 Ahmed, D. H., Sung, H. J., Kim, D.-S., "Simulation of non-Newtonian Ink Transfer between Two Separating Plates for Gravure-offset Printing", International Journal of Heat and Fluid Flow, Vol. 32, No. 1, 2010. (298-307)
17 Merilampi, S., Bjorninen, T., Ukkonen, L., Ruuskanen, P., Sydanheimo, L., "Embedded Wireless Strain Sensors based on Printed RFID Tag", Sensor Review, Vol. 31, No. 1, 2011. (32-40)   DOI
18 David, T. G., Claypole, T. C., "Printed Silver Circuits for FMCG Packaging", Circuit World, Vol. 39, No. 4, 2013. (188-194)   DOI
19 Pongpaibool, P., Jantarachote, V., Siwamogsatham, S., "An Optimization Study On Cost-Efficient Dipole And Bow-Tie Antenna Designs For Printed Uhf R fid", Microwave and Optical Technology Letters, Vol. 53, No. 11, 2011. (2676-2679)   DOI
20 Perl, A., Reinhoudt, D. N., Huskens, J., "Microcontact Printing: Limitations and Achievements", Adv. Mater., Vol. 21, 2009. (2257-2268)   DOI   ScienceOn
21 Elsayad, S., "Some Factors Affecting Ink Transfer in Gravure Printing", Pigment and Resin Technology, Vol. 31, 2002. (234-240)   DOI   ScienceOn
22 Huang, W. X., "Simulation of Liquid Transfer between Separating Walls for Modeling Micro-gravure Offset Printing", International Journal of Heat and Fluid Flow, Vol. 29, 2008. (1436-1446)   DOI   ScienceOn
23 Shulaker, M. M., Hills, G., Patil, N., Wei, H., Chen, H.-Y., Philip, H.-S., Mitra, S., "Carbon Nanotube Computer", Nature, Vol. 501, 2013. (526-530)   DOI
24 Qian, H., Greenhalgh, E. S., Shaffer, M. S. P., Bismarck, A., "Carbon Nanotube-based Hierarchical Composites: a review", J. Mater. Chem., Vol. 20, 2010. (4751-4762)   DOI   ScienceOn
25 Nizam, R., Mahdi, S., Rizvi, A., Azam, A., "Electronic Transport in Single Carbon Nanotube Structures", Int. J. Sci. Tchnology, Vol. 1, No. 4, 2011. (163-168)
26 Rwei, S.-P., Ku, F.-H., Cheng, K.-C., "Dispersion of Carbon Black in a Continuous Phase: Electrical, Rheological, and Morphological Studies", Colloid Polym Sci, Vol. 280, 2002. (1110-1115)   DOI   ScienceOn
27 Hashmi, S. M., Quintiliano, L. A, Firoozabadi, A., "Polymeric Dispersants Delay Sedimentation in Colloidal Asphaltene Suspensions", Langmuir, Vol. 26, No. 11, 2010. (8021-8029)   DOI
28 Jeong, K.-C., Eom, S.-H., Kim, Y.-K., Cho, M. S., "Dispersion Characteristics of Carbon Black Particles in a High Viscous Simulated Solution", Appl. Chem. Eng., Vol. 24, No. 2, 2013. (165-170)
29 Zhang, M., Li, L., Xu, J., Sun, D., "Effect of Polyisobutylenesuccinimide on Low-temperature Rheology and Dispersibility of Clay Particles in Mineral Oil", Colloids and Surfaces A: Physicochem. Eng. Aspects, Vol. 431, 2013. (133-141)   DOI
30 Dubois-Clochard, M.-Cl., Durand, J.-P., Delfort, B., Gatean, P., Barre, L., Blanchard, I., Chevalier, Y., Gallo, R., "Adsorption of Polyisobutenylsuccinimide Derivatives at a Solid-Hydrocarbon Interface", Langmuir, Vol. 17, 2001. (5901-5910)   DOI
31 Kumari, S., Nigam, D., Nigam, I., "Synthesis and Characterization of Alkali Modified Styrene-maleic Anhydride Copolymer (SMA) for Dispersion of Carbon Black", Int J Plast Technol, Vol. 15, No. 2, 2011. (113-132)
32 Jianhui, Zhu, Jiali, Cai, Wenchun, Xie, Pin-Hsuan Chen, Massimo, Gazzano, Mariastella Scandola and Richard A. Gross, "Poly(butylene 2,5-furan dicarboxylate) a Biobased Alternative to PBT: Synthesis, Physical Properties, and Crystal Structure", Macromolecules, Vol. 46, 2013. (796804)
33 Pomchaitaward, C., Manas-Zloczowera, I., Feke, D. L., "Investigation of the Dispersion of Carbon Black Agglomerates of Various Sizes in Simple-shear Lows", Chemical Engineering Science, Vol. 58, 2003. (1859-1865)   DOI
34 Kim, S. H., "Design and Application Technologies of Nano-Paste", Journal of KWJS, Vol. 26, No. 2, 2008. (122-126)
35 Ding, Y., Chen, S., Xu, H., Wang, Z., Zhang, X., "Reversible Dispersion of Single-Walled Carbon Nanotubes Based on a $CO_2$-Responsive Dispersant", Langmuir, Vol. 26, No. 22, 2010. (16667-16671)   DOI
36 D664, "Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration", ASTM international, West Conshohocken, PA, 2012.
37 D3359, "Standard Test Methods for Measuring Adhesion by Tape Test", ASTM international, West Conshohocken, PA, 2013.