• Title/Summary/Keyword: Synthetic Fuel

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A Review on the Emission Sources of Ammonia and the Factors Affecting Its Loss

  • Das, Piw;Sa, Jae-Hwan;Kim, D.S.;Kim, K.H.;Jeon, E.C.
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.E2
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    • pp.47-56
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    • 2007
  • Among all the nitrogen species present in the atmosphere, ammonia forms a considerable portion along with the nitrogen oxides. The major sources of atmospheric ammonia are animal feedlot operations including emission from excreta of domestic animals and agricultural activities, followed by emission from synthetic fertilizers, biomass burning and to some lesser extent, fossil fuel combustion. Ammonia emission factor, expressed as the weight of ammonia per unit weight, volume, or duration of the activity emitting it, is generally used in developing emission estimates for emission inventories. The factors determining ammonia loss from soil or from manures are the temperature, pH, humidity, precipitation and the velocity of wind above it.

A simulation study on synthesis gas process optimization for GTL (Gas-to-Liquid) pilot plant (GTL 합성유 제조용 파일럿 플랜트 최적 운전 변수 도출을 위한 합성가스 공정 시뮬레이션 연구)

  • Kim, Yong Heon;Bae, Ji Han;Park, Myoung Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.74.2-74.2
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    • 2011
  • A simulation study on synthesis gas process in GTL process was carried out in order to find optimum operation conditions for GTL (gas-to-liquid) pilot plant design. Optimum operating conditions for synthesis gas process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. The effect of temperature and pressure on synthesis gas process $H_2$/CO ratio were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

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Studies on the Cation Exchangers from Coals (炭質陽이온交煥體 製造에 關한 硏究)

  • Lee, Bum-Soon;Yoo, In-Sang
    • Journal of the Korean Chemical Society
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    • v.4 no.1
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    • pp.62-66
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    • 1957
  • With the intention of preparing cation exchangers from the domestic coals, and using these for softening hard water and some other purposes, seven kinds of raw coal were tested and the results are as follows. 1) The following conditions of preparation were given the good results. Reaction time 5 hours Reaction temperature $95^{\circ}$ Concentration of sulfuric acid 98% Amount of sulfuric acid 10 times to the sample (as weight) 2) The raw coals which is rich in fixed carbon and have the fuel ratio 0.8 to 1.0 were suitable, and Kampo lignite has shown the best results. 3) The cation exchangers from coals were able to exchange the cation, both hydrogen and sodium type dynamically and statically, like the synthetic ion exchange resin. The exchange capacities were as follows. Total capacity 1.60 meq/g. Breakthrough capacity 1.30 meq/g. Usable breakthrough capacity 1.20 meq/g National Central Research laboratory

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A dynamic simulation study on SCR (Stream Carbon dioxide Reforming) process for pilot plant operation (파일럿 플랜트 최적운전을 위한 SCR공정 동적 모사)

  • Kim, Yong Heon;Bae, Ji Han;Park, Myoung Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.136.2-136.2
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    • 2011
  • A dynamic simulation study on SCR process in GTL process was carried out in order to find optimum operation conditions for pilot plant operation. Optimum operating conditions for SCR synthesis gas process were determined by changing operation variables such as feed temperature and pressure. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. The effect of temperature and pressure on synthesis gas process $H_2$/CO ratio were mainly examined. Dynamic simulation results were fed back to feed operation condition for optimizing productivity, especially for appropriate condition to FT (Fischer-Tropsch) synthesis unit.

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Preparation and Characterization of PPO/PS-b-PSSA Blend for Fuel Cell (연료전지막을 위한 PPO/PS-b-PSSA 블랜드의 제조와 분석)

  • Woo, Jung-Kyu;Ahn, Sung-Guk;Cho, Chang-Gi
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.175-176
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    • 2003
  • Generally, The protone exchange membrane (PEM) contains cationic exchange groups such as SO3$\^$-/ group. The poly(styrene sulfonic acid) (PSSA) and its copolymers are widely studied because of easily synthetic method and higher conductivities. However, PSSA is not used individually because of poor physical properties such as brittleness and relatively lower Tg. So some researchers are concerned engineering plastics (EP) such as polyimides, polysulfone, polyketones, and poly(2,6-dimethyl-1,4-phenylene oxide) (MPPO) etc. (omitted)

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Development of Biopolymer-based Materials Using Ionic Liquids and Its Biotechnological Application (이온성 액체를 이용한 바이오폴리머 기반의 소재 개발 및 생명공학 분야로의 응용)

  • Lee, Sang-Hyun;Park, Tae-Joon
    • KSBB Journal
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    • v.25 no.5
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    • pp.409-420
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    • 2010
  • Biopolymer-based materials recently have garnered considerable interest as they can decrease dependency on fossil fuel. Biopolymers are naturally obtainable macromolecules including polysaccharides, polyphenols, polyesters, polyamides, and proteins, that play an important role in biomedical applications such as tissue engineering, regenerative medicine, drug-delivery systems, and biosensors, because of their inherent biocompatibility and biodegradability. However, the insolubility of unmodified biopolymers in most organic solvents has limited the applications of biopolymer-based materials and composites. Ionic liquids (ILs) are good solvents for polar organic, nonpolar organic, inorganic and polymeric compounds. Biopolymers such as cellulose, chitin/chitiosan, silk, and DNA can be fabricated from ILs into films, membranes, fibers, spheres, and molded shapes. Various biopolymer/biopolymer and biopolymer/synthetic polymer composites also can be prepared by co-dissolution of polymers into IL mixtures. Heparin/biopolymer composites are especially of interest in preparing materials with enhanced blood compatibility.

Manufacture of Top Table for Computer Desk by Wasted-Wood Materials (폐기 목질재료에 의한 컴퓨터 책상판의 제조)

  • 노정관;도정락
    • Journal of the Korea Furniture Society
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    • v.13 no.2
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    • pp.1-10
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    • 2002
  • A computer top table was manufactured with the solid wood wastes that has been landfilled, combustion or burnt as a fuel at the present time. The computer table is different in form and size to that of existing fixed rectangular. It is idea1 product not only convenient and functional to use and beautiful design but also processing Performance of edge area and overlaying properties. The main technologies to develop this computer top table are plan for moulder to mould the Product and producing, molding the most suitable material and composition, suitable adhesives selecting and synthetic technology, investigation for the moulding conditions such as temperature, time etc, adequate overlaying materials selecting and overlaying technology have to be chocked.

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The Effect of Crystal Size of SAPO-34 Synthesized Using Various Structure Directing Agents for MTO Reaction (다양한 구조 유도제로써 합성된 SAPO-34의 결정크기가 메탄올로부터 올레핀 전환반응(MTO)에 미치는 영향)

  • Song, Young-Ha;Chae, Ho-Jeong;Jeong, Kwang-Eun;Kim, Chul-Ung;Shin, Chae-Ho;Jeong, Soon-Yong
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.559-567
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    • 2008
  • SAPO-34 is a well-known catalyst for methanol to olefins (MTO) process, but is rapidly deactivated by coke formation. It is necessary to improve the catalyst lifetime of SAPO-34 for MTO process. In the present work, SAPO-34 catalysts were synthesized with a variety of structure directing agent, and the physicochemical properties of the catalysts were examined by $N_2$-isotherm, XRD, SEM, and $NH_3$-TPD. It was found that mixed structure directing agents, especially DEA and TEAOH, gave well developed SAPO-34 crystal structure and reduced the crystal size and moderated acidity of SAPO-34 under the same synthetic conditions as that of various structure directing agents. Also, we could find that SAPO-34 catalyst prepared by mixed templates of DEA and TEAOH had the superior catalytic activity and the longer lifetime in MTO reaction.

Decomposition of Liquid Wastes(Waste Oil & Solvents) under High Temperature Conditions (산업단지 발생 액상폐기물(폐유와 폐유기용제)의 고온연소 특성)

  • Kim, Min-Choul;Lee, Jae-Jeong;Suk, Min-Kwang;Lee, Gang-Woo;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.12
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    • pp.3761-3767
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    • 2009
  • This study was investigated to determine the combustion characteristics, decomposition efficiency, and the flue gas concentrations after combustion in the high temperature reactor($1,250{\sim}1,400^{\circ}C$, 1 atm) for the liquid wastes(waste oil and waste solvent) generated from the industrial complex. The concentration of nitrogen oxide(NOx) is decreased and the synthetic gas is increased when the mass ratio of $O_2$/waste is about 1.53 because the reaction condition was changed to reduction state. And BTEXs(benzene, toluene, ethylbenzene, xylene) are decomposed more than 99.99%. If the highly concentrated liquid waste (waste oil and waste solvent) is treated under the operating conditions suggested by this study, our treatment method for the liquid waste was found to be proper because of the contaminants emission concentration is very low. In addition, the synthetic gas after combustion can be used as an alternative fuel.

Determination of Transuranic Elements in Radwaste Samples from Nuclear Power Plant (원전발생 방사성폐기물 시료 중 초우란원소의 정량)

  • 조기수;김태현;전영신;지광용;김원호
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.351-357
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    • 2003
  • Transuranic elements such as Pu, Am and Cm in synthetic solution of spent nuclear fuel samples were determined by electrodeposition followed by alpha-spectrometry after separation using anion exchange and extraction chromatography in order to determine the transuranic elements in radwaste samples from nuclear power plants. Plutonium was separated by 12M HC1-0.1M HI as an eluent on anion exchange column. As a second step Am and Cm were separated in a group by DTPA-Lactic acid as the eluent on HDEHP coated column. The nuclides of $^{239}Pu$, $^{241}Am$$^{244}Cm$ separated were determined by alpha-spectrometry after electrodeposition in 0.1M $NaHSo_4$-0.53M $Na_2SO_4$buffer solution as an electrolyte. The recovery yields of $^{239}Pu$, $^{241}Am$$^{244}Cm$ were 83.8%, 85.2% and 86.3%, respectively, from the synthetic solution containing uranium and non-radioactive metal elements.

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