• Title/Summary/Keyword: Swelling Agent

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Changes of Flame Retardant and Physical Properties of Cotton Knitted Fabrics after Flame Resistant Treatment (면편성물의 방염처리에 의한 방염성과 물성변화)

  • Jee, Ju-Won;Song, Kyung-Geun
    • Fashion & Textile Research Journal
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    • v.5 no.3
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    • pp.273-282
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    • 2003
  • Effect of fixation methods and relaxation treatment on the flame retardant(FR) and physical properties of MDPP/HMM treated cotton weft-knitted fabrics were studied. Combination of four different fixation methods - relaxation, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of cotton weft-knitted fabric with MDPP/HMM. As the results, 1. Swelling agent and wet fixation method helps FR agent penetrate the fiber efficiently. Interlock showed relatively higher values of LOI than single jersey. 2. Interlock showed relatively higher values of bending rigidity(B), shear rigidity(G) and coefficient of friction(MIU) than those of single jersey before and after flame resistant treatment. 3. An increase in internal volume of cotton fiber by relaxation treatment increased the bending rigidity(B), shear rigidity(G) and compressional energy(WC). 4. The cotton weft-knitted fabric treated wet fixation, which crossliked FR agent efficiently, showed higher bending rigidity, shear rigidity(G) and lower compressional energy(WC). Retention of swelling ability of cotton weft-knitted fabrics treated with MDPP/HMM, which increased the internal volume of cotton weft-knitted fabric, showed lower bending rigidity.

Preparation and Swelling Property of Superporous Hydrogels using Glycol Chitosan (글리콜키토산을 이용한 초다공성 하이드로젤의 제조 및 팽윤거동)

  • Kuang, Jia;Li, Zheng-Zheng;Yun, Chwi-Im;Yuk, Kun-Young;Huh, Kang-Moo
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.263-268
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    • 2009
  • Superporous Hydrogels (SPHs) have been extensively investigated for various biomedical applications due to their fast swelling and superabsorbent properties. In this study, glycol chitosan that is one of most abundant natural polymers was used as a cross-linking agent instead of bisacrylamide (BIS), which is a broadly used crosslinking agent for preparation of SPHs. Glycol chitosan was modified to have reactive vinyl groups by chemical conjugation with glycidyl methacrylate (GMA). The vinyl group-containing glycol chitosan (GC-GMA) was characterized by FT-IR and $^1H$-NMR measurements. SPHs have been prepared in various synthetic conditions to establish the optimum synthetic process for making superporous structure, where the inner pores are interconnected to each other to form a open channel structure. Various SPHs with different GC-GMA contents have been successfully prepared and have been observed to show faster swelling properties than other conventional SPHs. From the study on the swelling behavior of SPHs, the GC-GMA content is considered to be an important factor for controlling their swelling properties.

Influence of the Type of Curing Agent on Swelling Behavior of Natural Rubber Foam (가교제의 종류가 천연고무 발포체의 팽윤거동에 미치는 효과)

  • Lee, Hwan-Kwang;Chung, Tea-Kyung;Kim, Sung-Chan;Kim, Hyun-Gi;Choi, Kyung-Man;Kim, Young-Min;Han, Dong-Hun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1775-1781
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    • 2008
  • The effects of the type of curing agent on the swelling of the natural rubber(NR) sponge applicable to the self-sealing layer of a helicopter fuel tank were investigated. The curing systems employed were peroxide and mixed ones of sulfur and peroxide. The NR compounds were prepared in a kneader and a roll-mill. The compounds were partially cured in a press at high pressure and subsequently cured fully with expansion in another press at atmospheric pressure. The apparent density of the NR sponge was measured and the cell structure was observed with scanning electron microscopy. The swelling experiments were performed at room temperature using toluene, iso-octane, and an aircraft fuel as a solvent. More rapid volume swelling of the NR sponge cured by peroxide was achieved than cured by sulfur and peroxide with similar amount of curing agent added in rubber compounds. The apparent density and cell structure of the sponge were extremely sensitive to the amount of peroxide, which influences again the swelling behavior of the NR sponge. It is important to control properly two reactions of decomposition of foaming agent and crosslinking of NR in the mold to obtain rapid swelling of the NR sponge on contact of the fuel.

Drug Interactions of Ibuprofen and Prednisolone in Antiinflammatory and Antipyretic Effects (항염 및 해열효과에 미치는 Ibuprofen과 Prednisolone의 약 상호 작용)

  • 강영자;조윤성
    • YAKHAK HOEJI
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    • v.25 no.3
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    • pp.109-114
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    • 1981
  • The authors investigated drug interaction of ibuprofen and prednisolone in antiinflammatory and antipyretic activities. We have found significant differences of the antiinflammatory and antipyretic activities between single and concurrent administration of ibuprofen and prednisolone, using Sprague-Dawley Strain rats, carrageenin as a phlogistic agent and brewer's yeast as a fever inducing agent. 1) Ibuprofen(20mg/kg) was administered to the rats orally and resulted in significant reduction of (31.70 %) the swelling of rat paw induced by carrageenin, 2) prednisolone (9mg/kg) showed significant reduction of (45.76%) the swelling, 3) concurrent administration of ibuprofen (20mg/kg) and prednisolone (9mg/kg) also reduced (57.40%) the swelling. In ibuprofen (125mg/kg) administration, the inhibition rate of edema was 39.32% and in prednisolone (1mg/kg) administration, the rate was 39.04%. In concurrent administration of ibuprofen (125mg/kg) and prednisolone (1mg/kg), the inhibition rate of edema was 63.09%. Concurrent administration of ibuprofen and prednisolone showed more anti-inflammatory effects than single administration of ibuprofen and prednisolone respectively. Prednisolone itself did not show antipyretic effect, but concurrent administration of ibuprofen and prednisolone showed more antipyretic effects than ibuprofen single administratron.

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Synthesis and Swelling Kinetics of a Cross-Linked pH-Sensitive Ternary Copolymer Gel System (pH-민감성 삼성분계 공중합체 젤의 합성 및 팽윤 속도론)

  • Zafar, Zafar Iqbal;Malana, M.A.;Pervez, H.;Shad, M.A.;Momma, K.
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.219-229
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    • 2008
  • A pH sensitive ternary copolymer gel was synthesized in the presence of ethylene glycol dimethacrylate (EGDMA) as a crosslinking agent through radical polymerization of vinyl acetate (VA), acrylic acid (AA) and methyl acrylate(MA) with a weight ratio of 1 : 1.3 : 1. A number of experiments were carried out to determine the swelling behavior of the gel under a variety of pH conditions of the swelling medium. As the pH of the swelling medium was changed from 1.0 to 8.0 at $37^{\circ}C$, the gel showed a shift in the pH-dependent swelling behavior from Fickian (n=0.3447) to non-Fickian (n=0.9125). The resulting swelling parameters were analyzed using graphical and statistical methods. The results showed that the swelling of the gel was controlled by the pH of the medium, i.e. $n=n_o{\exp}(S_{C}pH)$, where n is the diffusion exponent, $n_o(=28.9645{\times}10^{-2})$ is the pre-exponential factor and $S_C$(=0.1417) is pH sensitivity coefficient. The swelling behavior of the gel was also examined in aliphatic alcohols. The results showed that the rate of swelling increased with increasing number of carbon atoms in the alcoholic molecular chain.

Drying Shrinkage and Pore Structure of Self-Healing Epoxy-Modified Mortars Using Expansive Admixtures (팽창성 혼화재를 병용한 에폭시수지 혼입 자기치유 모르타르의 건조수축 및 세공구조)

  • Ham, Seong-Min;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.166-167
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    • 2015
  • The purpose of this study is to examine the effect on drying shrinkage of self-healing epoxy-modified mortars(EPMMs) using expansive admixtures. The EPMMs are prepared with polymer-binder ratios of 0 and 10%, and tested for drying shrinkage and pore structure analysis. As a result, regardless of the expansion and swelling agent content, the drying shrinkage of the EPMMs is remarkably decreased than that of unmodified mortars. Also, the pore size distribution of the EPMMs is moved to smaller size in comparison with unmodified mortars. In this study, the EPMM with expansive agent 7.5% and swelling agent 2.5% is recommended as a optimal mix proportion for reduction of drying shrinkage.

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Swelling of Commercial Matrix Tablets Based on Carboxymethyl Cellulose Sodium and Alginic Acid (시판중인 메트릭스 정제의 팽윤력 비교 연구)

  • Kim, Ki Taek;Kim, Ji Su;Park, Ju-Hwan;Lee, Jae-Young;Jo, Yeong Woo;Yang, Jae-Gwon;Jang, Jun Hee;Choi, Eun-Sun;Kim, Dae-Duk
    • YAKHAK HOEJI
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    • v.60 no.2
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    • pp.73-77
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    • 2016
  • Alginic acid and carboxymethyl cellulose sodium are dietary fibers from plants. They have a swelling property and delay the gastric emptying time, thereby resulting in feeling satiated after oral administration, which may eventually contribute to loss of body weight. The goal of this study was to compare swelling property of three commercial matrix tablets based on alginic acid and carboxymethyl cellulose sodium. When the swelling was determined by the Korean Ministry of Food and Drug Safety (MFDS) guideline, the tablet prepared by direct compression method with highly viscous swelling agent showed the highest swelling in acidic conditions. Water uptake of these tablets was rapid and completed within 30 min. Moreover, when the pH was changed from 2.5 to 6.8 buffer, the water uptake was not significantly changed in all tablets.

Swelling Behavior of Low Toxic Absorbent Based on Biopolymer (생물고분자로 이루어진 저독성 흡수제의 팽윤거동)

  • Jung, Jin Hee;Kim, Jin;Lee, Ki-Young
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.478-485
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    • 2013
  • In this study, hydrogels with fast swelling and high absorbent properties were prepared using biopolymers approved as a food additive and their swelling properties were characterized. To improve the swelling properties of conventional hydrogels, we formed gas bubbles using a foaming agent in the process of preparing hydrogels and characterized in terms of equilibrium swelling ratio, swelling kinetics and cytotoxicity. In particular, alginate hydrogels observed by a digital microscope have an open-pore channels structure with the sizes of hundreds micrometers. Also, the cell viability of all hydrogels were found to be much higher than that of poly(acrylic acid).

Albumin-Crosslinked PVP Hydrogel as a Gastric Retention Platform (위내체류를 목적으로 한 알부민 가교 PVP 하이드로겔의 팽윤특성)

  • Shim, Chang-Koo;Yeo, So-Hyeon
    • Journal of Pharmaceutical Investigation
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    • v.23 no.3
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    • pp.145-153
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    • 1993
  • Retaining a drug in the stomach by some means is sometimes necessary to extend the G1 absorption time of the drug more than 6-8 hrs. Hydrogel has often been examined for its feasibility as a dosage form, so called platform, that could be retained in the stomach due to its excellent swelling properties in the gastric fluid. In this study, polyvinylpyrrolidone (PVP) hydrogel crosslinked by albumin or acrylated albumin was synthesized in a tablet form and evaluated for its possibility as the platform. The synthesis of the hydrogel was performed by $^{60}Co\;{\gamma}-ray$ irradiation of N-vinyl-2-pyrrolidone (monomer) in the presence of a crosslinking agent: aqueous solution of albumin or acrylated albumin. Synthetic conditions such as radiation dose, dose rate and concentration of crosslinking agent were varied in order to optimize the swelling and mechanical properties of the hydrogels. Degree of swelling of albumin-crosslinked PVP (Al-PVP) was highly dependent on radiation dose, dose rate and albumin concentration: it was decreased as they increased. On the other hand, that of acrylated albumin-crosslinked PVP (Acryl-PVP) was almost independent on them except dose rate: it was decreased as the radiation dose rate increased. The compressive strength of the two hydrogels was decreased as the dose rate increased. Digestion of both PVP in artificial gastric fluid containing pepsin was delayed by the ${\gamma}-ray$ irradiation. In conclusion, Al-PVP and Acry-PVP with diverse swelling and mechanical properties could be obtained by controlling synthetic conditions, mainly the irradiation dose rate.

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Dyeing and Printing on Aramid Materials (아라미드 소재의 침염 및 날염)

  • Hong, Jin-Pyo;Kim, Mi-Kyung;Yoon, Seok-Han;Choi, Woo-Hyuk
    • Textile Coloration and Finishing
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    • v.23 no.4
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    • pp.298-303
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    • 2011
  • Aramid fibers have been widely used as the reinforcement for composites due to their high modulus and strength. Nowadays the safety measures is required to improve the personal protection. The dyeing of aramid fibers is considered to be very difficult and their dyeing mechanism is not well illucidated. Therefore, this study is to establish the dyeing & printing technology for aramid fibers. The effects of swelling agent and neutral salt in the dye bath on the obtained colors were studied. Also dyeing method of aramid fibers depending on dyeing temperature and dye concentration were established. Color fastness of the dyed aramid fabric with cationic dyes were acceptable excluding light fastness.