• Title/Summary/Keyword: Surface protection materials

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Study on Hygrothermal Degradation and Corrosion Protection of Epoxy Coatings Cured by Different Amine Based Curing Agents

  • Shon, Min-Young;Kwon, Huck-Sang
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.201-208
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    • 2010
  • Epoxy coatings cured by different amine based curing agents have been prepared. Atomic force microscopy (AFM) has been used to monitor the surface topology changes of epoxy coatings before and after hygrothermal cyclic test. The glass transition temperature ($T_g$) and coefficient of thermal expansion (CTE) of the epoxy coating were measured by Thermo-mechanical Analysis (TMA). The Electrochemical impedance spectroscopy (EIS) with hygrothermal cyclic test has been introduced to evaluate the corrosion protection of the epoxy coatings. In conclusion, thermal properties of epoxy coatings were in good agreement with the results of corrosion protection of epoxy coated carbon steel obtained result by EIS with hygrothermal cyclic test. The relationship between thermal properties, surface roughness changes and corrosion protection of epoxy coatings are discussed in this study.

Development of Inorganic Fire Protection Materials for High Strength Concrete (구조체 보호를 위한 고내화성 마감재 적용에 관한 실험적 연구)

  • Jung, Suk-Jo;Song, Hun;Kwon, Choon-Woo;Kim, Young-Yup;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.885-888
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    • 2006
  • Nowaday, High strength concrete(HSC) has been mainly used in high rise building. HSC have superior property as well as improvement in durability compared with ordinary strength concrete. In spite of durability of HSC, explosive spalling in concrete front surface near the source of fire occurs serious problem in structural safety. Thus, this study is concerned with experimentally investigation fire resistance of the inorganic fire protection materials at high temperatures up to $800^{\circ}C$. From the test result, developed inorganic binder becomes general that with rising temperature the compressive strength of the material increases in tendency. Therefore, the results indicate that it is possible to fireproof panels, fire protection of materials, etc.

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A Study on the Application of Anti-Corrosion Techniques on the Surface of Oxygen Free Copper (무산소동의 표면부식 방지기술 적용에 관한 연구)

  • Joo, Hyung-Goun;Lee, Dae-Young;Zhang, Da Quan;Lee, Kang-Yong;Al-Hanash, Essam Khamis Ibrahim
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.425-429
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    • 2009
  • The protection for copper tarnish was developed by surface treatment method and volatile corrosion inhibiting (VCI) technology. The performance of surface treatment and VCI material is also examined in simulated test environment. Benzotriazole (BTAH) solution that contained molybdate showed best performance than others. Usage of VCI materials with surface treatment was more effective. The protection film foamed on the surface of copper was investigated by auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). Molybdate does not participate in the formation of the protective film but promotes the passivation effect. This facilitates the stabilization of the cuprous oxide film, and strengthens the adsorption of BTAH.

PLASMA POLYMERIZED THIN FILMS GROWN BY PECVD METHOD AND COMPARISON OF THEIR ELECTROCHEMICAL PROPERTIES

  • I.S. Bae;S.H. Cho;Park, Z. T.;Kim, J.G.;B. Y. Hong;J.H. Boo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2003.10a
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    • pp.119-119
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    • 2003
  • Plasma polymerized organic thin films were deposited on Si(100) glass and Copper substrates at 25 ∼ 100 $^{\circ}C$ using cyclohexane and ethylcyclohexane precursors by PECVD method. In order to compare physical and electrochemical properties of the as-grown thin films, the effects of the RF plasma power in the range of 20∼50 W and deposition temperature on both corrosion protection efficiency and physical properties were studied. We found that the corrosion protection efficiency (P$\_$k/), which is one of the important factors for corrosion protection in the interlayer dielectrics of microelectronic devices application, was increased with increasing RF power. The highest P$\_$k/ value of plasma polymerized ethylcyclohexane film (92.1% at 50 W) was higher than that of the plasma polymerized cyclohexane film (85.26% at 50 W), indicating inhibition of oxygen reduction. Impedance analyzer was utilized for the determination of I-V curve for leakage current density and C-V for dielectric constants. To obtain C-V curve, we used a MIM structure of metal(Al)-insulator(plasma polymerized thin film)-metal(Pt) structure. Al as the electrode was evaporated on the ethylcyclohexane films that grew on Pt coated silicon substrates, and the dielectric constants of the as-grown films were then calculated from C-V data measured at 1㎒. From the electrical property measurements such as I-V ana C-V characteristics, the minimum dielectric constant and the best leakage current of ethylcyclohexane thin films were obtained to be about 3.11 and 5 ${\times}$ 10$\^$-12/ A/$\textrm{cm}^2$ and cyclohexane thin films were obtained to be about 2.3 and 8 ${\times}$ 10$\^$-12/ A/$\textrm{cm}^2$.

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Application of Electro-deposition Method for Crack Closing and Surface Improvement of Reinforced Concrete (철근콘크리트의 균열폐색 및 표면개선을 위한 전착의 응용)

  • 문한영;류재석
    • Journal of the Korea Concrete Institute
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    • v.11 no.6
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    • pp.79-88
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    • 1999
  • In this paper, the electro-deposition method for the rehabilitation of cracked concrete, based on the electro-chemical technique, is presented. The main purpose of this paper is to apply this technique to reinforced concrete members on land. After cracking with a specified load(crack width 0.5mm), 10$\times$10$\times$20cm concrete specimens with embedded steel bars were immersed in several solutions, then a constant current density between the embedded steel in concrete and an electrode in the solution was applied for 4~20 weeks. The results indicate that electro-deposits formed in this process are able to close concrete cracks and to coat the concrete surface and that formation of these electro-deposits is confirmed to have an effect of protection against detrimental materials. Therefore, it is demonstrated that the electro-deposition method can be usefully applied for the rehabilitation technique of concrete.

METALLIC COATING PROTECTION ON DIELECTROMAGNETS PREPARED FROM MIXTURE OF HARD MAGNETIC POWDERS

  • Slusarek, Barbara;Wasenczuk, Andrzej
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.687-689
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    • 1995
  • Our team works on mixture of hard magnetic materials. As hard magnetic material we used mixture of powders: melt-spun ribbon Nd-Fe-B, ferrite and Alnico. Their different mixtures are basic material for dielectromagnets under our investigation. Main disadvantage of dielectromagnets with Nd-Fe-B alloy powder as a component is a low corrosion resistance. Protection against corrosion is covering dielectromagnets with metallic or organic coating film. The coating film protects dielectromagnets from free particles on the surface and low resistance for mechanical stresses too. The surface of dielectromagnets prepared from mixture of powders if formed by metallic particles - powder of Nd-Fe-B and Alnico, particles of oxide - powder of ferrite and particles of resin - bonding materials. Team work on technology of laying the metallic coating on dielectromagnets prepared from mixture of mentioned powders. Papers show the results of initial investigation on metallic coating technology. It shows influence of type and used technology of the metallic coating film on magnetic properties of dielectromagnets.

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Fire test procedures for flammability of bulkhead, ceiling and deck finish materials (선박의 격벽, 천정, 내장재 및 표면바닥재의 화재안정성 평가방법)

  • Kim, S.Y.;Kim, D.S.;Ahn, B.H.;Kwark, J.H.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.04a
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    • pp.117-119
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    • 2008
  • It is very important to protect life, property at sea from any fire. Recommendation on improved fire test procedures for surface flammability of bulkhead, ceiling and deck finish materials specifies a procedure for measuring fire characterizing their flammability and thus their suitability for use in marine construction. In this paper, we investigated the positive expected by fire test procedures for flammability of bulkhead, ceiling and deck finish materials. Also, unusual materials were analyzed. Finally, we suggest methods to solve several problems related to unusual materials.

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An Experimental Study on the Characters of Bullet Proof for Al and Ti Alloy (Al합금과 Ti합금의 방탄특성에 관한 실험적 연구)

  • Sohn Se Won
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.4
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    • pp.113-120
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    • 2005
  • In order to investigate the characteristics of penatration and the effect of surface treatment in A15052-H34, Al5082-Hl31 and titanium alloy laminates which were treated by anodizing and PVD(Physical Vapor Desposition) method, ballistic tests were conducted. Thickness of surface membrane in A15052-H34, Al5082-Hl31, were $25{\mu}m$ and that of titanium $0.9{\mu}m$ respectively. Surface hardness test was conducted using micro Vicker's hardness tester. Resistance to penetration is determined by the protection ballistic limit(V50), a statistical velocity with $50\%$ probability for complete penetration. Fracture behaviors and ballistic tolerance, described by penetration modes, are observed from the results of V50 test and Projectile Through Plate(PTP) test at velocities greater than protection ballistic limit, respectively. Present experimental results derived from this research help to optimize laminate impact behavior by varing the laminate thickness and surface treated materials.

Bond Capacity of Near-Surface-Mounted FRP in Concrete Corresponding to Fire-Protection Method (콘크리트에 표면매립보강된 FRP의 내화단열방법에 따른 부착성능)

  • Lim, Jong-wook;Kim, Tae-hwan;Seo, Soo-yeon
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.1
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    • pp.3-10
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    • 2019
  • The purpose of this paper is to find the fire-protection method for keeping on the bond capacity of Near-Surface-Mounted (NSM) FRP under high temperature. Experiments have been carried out to evaluate the bond capacity of NSM FRP by using CFRP-plates and to confirm the heat transfer to the concrete block when the refractory insulation is attached to the surface of NSM FRP. Bond test of NSM FRP under room temperature was conducted to obtain the maximum bond strength. And then a heating tests were carried out with keeping the bond stress of 30% of the maximum bond strength. As a result, the bond capacity of NSM FRP was disappeared when the temperature at epoxy reached to its glass transition temperature (GTT). In order to secure the bond capacity of the NSM FRP, it is necessary to protect the front as well as side by using insulation materials.