DOI QR코드

DOI QR Code

Study on Hygrothermal Degradation and Corrosion Protection of Epoxy Coatings Cured by Different Amine Based Curing Agents

  • Shon, Min-Young (Coating and Corrosion Research Department, Samsung Heavy Industries) ;
  • Kwon, Huck-Sang (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology)
  • Received : 2010.08.06
  • Accepted : 2010.10.20
  • Published : 2010.10.01

Abstract

Epoxy coatings cured by different amine based curing agents have been prepared. Atomic force microscopy (AFM) has been used to monitor the surface topology changes of epoxy coatings before and after hygrothermal cyclic test. The glass transition temperature ($T_g$) and coefficient of thermal expansion (CTE) of the epoxy coating were measured by Thermo-mechanical Analysis (TMA). The Electrochemical impedance spectroscopy (EIS) with hygrothermal cyclic test has been introduced to evaluate the corrosion protection of the epoxy coatings. In conclusion, thermal properties of epoxy coatings were in good agreement with the results of corrosion protection of epoxy coated carbon steel obtained result by EIS with hygrothermal cyclic test. The relationship between thermal properties, surface roughness changes and corrosion protection of epoxy coatings are discussed in this study.

Keywords

References

  1. ISO 7253, Paints and varnishes -- Determination of resistance to neutral salt spray (fog)
  2. B.S. Skerry and C.H. Simpson, Corrosion, 49, 663 (1993). https://doi.org/10.5006/1.3316098
  3. S.L. Chong, M. Jacoby, J. Boone, and H. Lum, JPCL 14. 20 ( 1997).
  4. G.P. Bierwagen, J. Li, L. Ellingson, and D.E. Tallman ., Prog. Org. Coat., 39, 67 (2000). https://doi.org/10.1016/S0300-9440(00)00106-5
  5. J. Li , C.S. Jeffcoate, G. P. Bicwagcn, D.J. Mills and D. E. Tallman., Corrosion, 54, 763 (1998). https://doi.org/10.5006/1.3284797
  6. Homma, K ., Kihira, H., and Ito. S, NACE Corrosion, 91, 9 (1991)
  7. Homma. K., Goto. N., Matsuoka. K ., and Ito, S ., ASTM STP 1137, V, Chaker Ed. ASTM (1992)
  8. Davis, Guy H ., Chester M. Dacres, Lorrie A Krebs, Mater. Perform., 39, 46 (2000).
  9. Mansfeld, F. and Tsai, C.H., Corrosion, 47, 958 (1991), https://doi.org/10.5006/1.3585209
  10. Tsai, C. H., and Mansfeld, F, Corrosion, 49, 726 (1993). https://doi.org/10.5006/1.3316106
  11. J. Li, C.S. Jeffcoate, G.P. Biewagen, D.J. Mills, D.E. Tallman, Corrosion, 54, 763 (1998), https://doi.org/10.5006/1.3284797
  12. Gordon P. Bierwagen. L. He, J. Li, L. Ellingson. D.E. Tallman, Prog. Org. Coat., 39, 67 (2000). https://doi.org/10.1016/S0300-9440(00)00106-5
  13. L. Valentinclli, J. Vogelsang, H. Ochs, and L. Fedrizzi, Prog. Org. Coat., 45, 405 (2002). https://doi.org/10.1016/S0300-9440(02)00137-6
  14. L. Fedrizzi, A. Bergo, F. Dcflorian, and L. Valentinelli, Prog, Org. Coat., 48. 271 (2003). https://doi.org/10.1016/S0300-9440(03)00109-7
  15. S. Touzain, Q. Le Thu, and G. Bonnet, Prog. Org. Coat., 52. 311 (2005). https://doi.org/10.1016/j.porgcoat.2004.09.007
  16. L. Fedrizzi, A. Bergo, and M. Fanicchia. Evaluation of accelerated aging procedures of painted galvanised steels by EIS, Elcctrochim. Acta, 51, 1864 (2006). https://doi.org/10.1016/j.electacta.2005.02.146