• Title/Summary/Keyword: Surface modification

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Microencapsulation of SrAl2O4 : Eu2+,Dy3+ Phosphorescent Phosphor for Enhanced Visibility of Road Lanes (차선의 시인성 향상을 위한 SrAl2O4 : Eu2+,Dy3+ 축광 마이크로 캡슐화에 관한 연구)

  • Park, Jae Il;Jeong, Soo Hwan;Cheong, In Woo
    • Journal of Adhesion and Interface
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    • v.17 no.3
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    • pp.110-116
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    • 2016
  • A decrease in the retro-reflectivity of glass-bead-covered road paint because of a rainwater film significantly reduces the visibility of drivers at night, and has been considered as a critical cause of traffic accidents. For enhanced visibility, the microencapsulation of hydrophobically modified $SrAl_2O_4:Eu^{2+}$,$Dy^{3+}$ phosphorescent phosphor was carried out via suspension polymerization of methyl methacrylate (MMA). The effects of surface modification agent and radical initiator types, loading amount of phosphorescent phosphor, and microcapsule size on the phosphor content ($W_{TGA}$) in the luminous poly(methyl methacrylate) (PMMA) microcapsules were investigated by thermogravimetric analyses (TGA). It was found that the $W_{TGA}$ value was ranged from 7 wt% to 81 wt%, which suggests suspension polymerization is suitable for the preparation of luminous microcapsules with a wide range of phosphor content. At a lower loading amount of phosphor, the $W_{TGA}$ value obviously increased as the microcapsule size decreased; however, the $W_{TGA}$ values with a higher loading amount of phosphor were less affected by the microcapsule size. The luminous microcapsules with the size range of $425{\sim}710{\mu}m$ were collected and tested as a luminous road lanes. It was found that luminance intensities of the microcapsule-coated plates remained higher than $300mcd/m^2$ for up to 100 s in darkness after 20 min of light emitting diode lamp irradiation. The results suggest that the luminous microcapsules can be a candidate for the replacement of glass beads for enhanced visibility of drivers.

Microstructure of the Antennal Sensory Organs in the Millipede Cawjeekelia pyongana (Polydesmida: Paradoxomatidae) (평안노래기 (Cawjeekelia pyongana) 안테나 감각기의 미세구조)

  • Chung, Kyung-Hwun;Moon, Myung-Jin
    • Applied Microscopy
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    • v.37 no.2
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    • pp.73-82
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    • 2007
  • The antennae of millipedes have a prominent function in detecting various types of environmental stimuli. The structural modification of the antennae is closely associated with the degree of sense recognition. Here we study functional morphology of the antennae of the millipede Cawjeekelia pyongana using field emission scanning electron microscope (FESEM). The antennae generally include eight segments, called articles. On the surface of the antennae, there are a variety of sensory receptors which include olfactory and mechanical receptors. We could identify four different types of antennal sensory organs in C. pyongana as follows: apical cone (Ac), trichoid sensilla (Ts), chaetiform sensilla (Cs) and basiconic sensilla (Bs). The most prominent of which is four APs at the 8th article. Both of the Is and the Cs are abundantly observed almost all of the antennal segments. They are long and strong bristles with longitudinal grooves acuminating toward the tip. The Bs is further divided into three subtypes: large basiconic sensilla $(Bs_1)$, small basiconic sensilla $(Bs_2)$ and spiniform basiconic sensilla $(Bs_3)$. The $Bs_1$ is located at the 5th and 6th articles, while the $Bs_2$ and $Bs_3$ can be seen at the 5th and at the 7th article, respectively.

THE EFFECT OF DIFFERENT CURING MODES ON COMPOSITE RESIN/DENTIN BOND STRENGTH IN CLASS ICAVITIES (1급 와동에서 상아질과 복합레진의 결합강도에 대한 중합방법의 효과)

  • Baek, Shin-Young;Cho, Young-Gon;Song, Byeong-Choon
    • Restorative Dentistry and Endodontics
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    • v.33 no.5
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    • pp.428-434
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    • 2008
  • The purpose of this study was to compare the microtensile bond strength in Class I cavities associated with different light curing modes of same light energy density. Occlusal enamel was removed to expose a flat dentin surface and twenty box-shaped Class I cavities were prepared in dentin. Single Bond (3M Dental product) was applied and Z 250 was inserted using bulk technique. The composite was light-cured using one of four techniques, pulse delay (PD group), soft-start (SS group), pulse cure (PC group) and standard continuous cure (CC group). The light-curing unit capable of adjusting time and intensity (VIP, Bisco Dental product) was selected and the light energy density for all curing modes was fixed at $16J/cm^2$. After storage for 24 hours, specimens were sectioned into beams with a rectangular cross-sectional area of approximately $1mm^2$ Microtensile bond strength $({\mu}TBS)$ test was per- formed using a univel·sal testing machine (EZ Test, Shimadzu Co.). The results were analyzed using oneway ANOVA and Tukey's test at significance level 0.05. The ${\mu}TBS$ of PD group and SS group was higher than that of PC group and CC group. Within the limitations of this in vitro study, modification of curing modes such as pulse delay and soft start polymerization can improve resin/dentin bond strength in Class I cavities by controlling polymerization velocity of composite resin.

Comparisons of Collection 5 and 6 Aqua MODIS07_L2 air and Dew Temperature Products with Ground-Based Observation Dataset (Collection 5와 Collection 6 Aqua MODIS07_L2 기온과 이슬점온도 산출물간의 비교 및 지상 관측 자료와의 비교)

  • Jang, Keunchang;Kang, Sinkyu;Hong, Suk Young
    • Korean Journal of Remote Sensing
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    • v.30 no.5
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    • pp.571-586
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    • 2014
  • Moderate Resolution Imaging Spectroradiometer (MODIS) provides air temperature (Tair) and dew point temperature (Tdew) profiles at a spatial resolution of 5 km. New Collection 6 (C006) MODIS07_L2 atmospheric profile product has been produced since 2012. The Collection 6 algorithm has several modifications from the previous Collection 5 (C005) algorithm. This study evaluated reliabilities of two alternative datasets of surface-level Tair and Tdew derived from C005 and C006 Aqua MODIS07_L2 (MYD07_L2) products using ground measured temperatures from 77 National Weather Stations (NWS). Saturated and actual vapor pressures were calculated using MYD07_L2 Tair and Tdew. The C006 Tair showed lower mean error (ME, -0.76 K) and root mean square error (RMSE, 3.34 K) than the C005 Tair (ME = -1.89 K, RMSE = 4.06 K). In contrasts, ME and RMSE of C006 Tdew were higher than those (ME = -0.39 K, RMSE = 5.65 K) of C005 product. Application of ambient lapse rate for Tair showed appreciable improvements of estimation accuracy for both of C005 and C006, though this modification slightly increased errors in C006 Tdew. The C006 products provided better estimation of vapor pressure datasets than the C005-derived vapor pressure. Our results indicate that, except for Tdew, C006 MYD07_L2 product showed better reliability for the region of South Korea than the C005 products.

Synthesis and Characterization of Heat Resistant Organophilic Layered Silicate Modified with Oligo(amic acid)s Having Alkyl Side Chains and Their Nanocomposites (알킬기가 도입된 올리고 아믹산 구조를 가진 고내열 친유기 층상 실리케이트의 제조 및 이를 이용한 나노복합재의 특성평가)

  • Han Ji Yun;Won Jong Chan;Lee Jae Heung;Suh Kyung-Do;Kim Yong Seok
    • Polymer(Korea)
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    • v.29 no.5
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    • pp.451-456
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    • 2005
  • In the field of designing of nano-fillers of polyimide nanocomposites, the two strategic points are the heat-resistance and compatibility with polyimide, a matrix polymer. In this study, we designed oligo(amic acid) having alkyl side chains and terminal amine groups to satisfy previous requirements and studied the modification of surface of layered silicates. Oligo(amic acid)s were prepared by the reaction of diamine monomers and PMDA and their molecular weight was controlled in about 2000g/mol. After that, acidification and ion exchange reaction led to the high-temperature organophilic layered silicate (OLS). XRD pauerns of OLS showed the more increased gallery spacing by $4{\AA}$ than that of the pristine layered silicate and the initial decomposition temperatures of OLS were in above $280^{\circ}C$. The polyimide nanocomposite films based on heat resistant OLS showed that the OLSs were well dispersed through the matrix and their CTEs showed a decrease of $26\%$ compared with pristine polyimide films.

Experiment for Reduction Effectiveness of Pollutants with the Improvement of Infiltration Ability in Vegetation Filter Strip (식생여과대내 침투능력 향상에 따른 오염물질 저감효과에 대한 실험)

  • Lee, Young-A;Choi, I-Song;Oh, Jong-Min
    • Journal of Korea Water Resources Association
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    • v.40 no.2 s.175
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    • pp.183-190
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    • 2007
  • Soil layer in vegetation filter strip is one of the very important factor for reduction of non-point pollutants by physical, chemical and biological reactions of it through infiltration process. This study was carried out to prepare more effective vegetation filter strip through modification of soil layer for river water quality improvement. Therefore, the main aims of this study are to compare and evaluate normal (straighten type) and modified (step type) vegetation filter strip, which make artificially change the soil layer to improve infiltration ability, through bench scale experiments. In the results of this study, vegetation filter strip of step type is much more highly reduction effectiveness of pollutants in surface flow compared with normal vegetation filter strip. In case of below effluent, however, it appeared that the vegetation filter strip modified soil layer showed lower reduction effectiveness of pollutants than the general vegetation filter strip. This result was judged because effluent through the vegetation filter strip of step type passed bigger size of aggregate or sand than the vegetation filter strip of straighten type. If we compare it as a definition of pollutant load to estimate total amount of reduced pollutants by vegetation filter strip, reduced pollutants load by step type showed higher than those by straighten type because below effluent amount relied on total effluent amount was higher at step type (4%) than at straighten type (2%). In conclusion, the vegetation filter strip of step type to improve infiltration effect is much more reduction effectiveness of pollutants than vegetation filter strip of straighten type.

Investigation of Convective Heat Transfer Characteristics of Aqueous SiO2 Nanofluids under Laminar Flow Conditions (층류유동 조건에서 SiO2 나노유체의 대류 열전달 특성에 대한 연구)

  • Park, Hyun-Ah;Park, Ji-Hyun;Jeong, Rag-Gyo;Kang, Seok-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.1-11
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    • 2016
  • The effect of the migration of nanoparticles near the wall of a channel on the convective heat transfer in a laminar flow of $SiO_2$ nanoparticle suspensions (nanofluids) under constant wall heat flux boundary conditions was numerically and experimentally investigated in this study. The dynamic thermal conductivity of the aqueous $SiO_2$ nanofluids was measured using T-type thermocouples attached to the outer surface of a stainless steel circular tube (with a length of 1 m and diameter of 1.75 mm). The nanofluids used in this study were synthesized by dispersing $SiO_2$ spherical nanoparticles with a diameter of 24 nm in de-ionized water (DIW). The enhancement of the thermal conductivity of the nanofluids (e.g., an increase of up to 7.9 %) was demonstrated by comparing the temperature profiles in the flow of the nanofluids with that in the flow of the basefluids (i.e., DIW). However, this trend was not demonstrated in the computational analysis, because the numerical models were based on continuum assumptions and flow features involving nanoparticles in a stable colloidal solution. Thus, to explore the non-continuum effects, such as the modification of the morphology caused by nanoparticle-wall interactions on the heat exchanging surfaces (e.g., the isolated and dispersed precipitation of the nanoparticles), additional experiments were performed using DIW right after the measurements using the nanofluids.

Evaluation of Mechanical Properties and Alkali-Silica Reaction of High Strength Mortar Using Waste Glass Sand (폐유리 잔골재를 치환한 고강도 모르타르의 역학적 특성 및 알칼리-실리카 반응 평가)

  • Eu, Ha-Min;Kim, Gyu-Yong;Choe, Gyeong-Cheol;Son, Min-Jae;Nam, Jeong-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.528-536
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    • 2020
  • In this study, high strength mortar and normal strength mortar using waste glass sand were evaluated. The main parameters studied were mechanical properties, alkali-silica reaction(ASR) and residual mechanical properties after ASR. As a result of this experiment, it was found that the increase in strength of the mortar has a limitation in improving the slip of the waste glass sand(GS), and rather, it causes a larger ASR. However, the possibility of improving the slip of GS was confirmed by the temporary increase of initial residal compressive and flexural strength of the mortar containing GS after the ASR. Therefore, to improve the slip of GS, the additional research is required, such as modification of the surface of GS and the incorporation of a binder which can increase the strength and makes matrix compact.

Evaluation of Hydraulic Conductivity of Slurry-wall-type Vertical Cutoff Wall with Consideration of Filter Cake (필터케이크(filter cake)를 고려한 슬러리월 연직차수벽의 현장투수계수 평가)

  • Nguyen, The Bao;Lee, Chul-Ho;Choi, Hang-Seok;Kim, Sang-Gyun
    • Journal of the Korean Geotechnical Society
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    • v.24 no.11
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    • pp.121-131
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    • 2008
  • In constructing a slurry trench cutoff wall, bentonite-water slurry is used to secure the stability of sidewalls during excavation before the wall is completed by backfilling. Unexpectedly, a thin but relatively impermeable layer called filter cake can be formed on the excavation surface, which significantly influences the result of slug test analysis in the cutoff wall if not considered. This study is to examine the effect of filter cake on evaluating hydraulic conductivity of the vertical cutoff wall through slug test analysis with the aid of the verified numerical program Slug_3D. The no-flux boundary conditions were adopted in Slug_3D to simulate the filter cake on the interface between the wall and the natural soil. A new set of type curves were built for applying the type curve method. New modification factors were obtained for using the modified line-fitting method. With consideration of filter cake, the type curve method and the modified line-fitting method were adopted to reanalyze the case study taken from EMCON (1995). The previous results achieved by Choi and Daniel (2006) without consideration of filter cake were compared with the present results obtained in this paper. The comparison emphasizes the necessity of considering filter cake when analyzing slug test results in vertical cutoff walls.

Effect of modifying the thickness of the plate at the level of the overlap length in the presence of bonding defects on the strength of an adhesive joint

  • Attout Boualem;Sidi Mohamed Medjdoub;Madani Kouider;Kaddouri Nadia;Elajrami Mohamed;Belhouari Mohamed;Amin Houari;Salah Amroune;R.D.S.G. Campilho
    • Advances in aircraft and spacecraft science
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    • v.11 no.1
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    • pp.83-103
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    • 2024
  • Adhesive bonding is currently widely used in many industrial fields, particularly in the aeronautics sector. Despite its advantages over mechanical joints such as riveting and welding, adhesive bonding is mostly used for secondary structures due to its low peel strength; especially if it is simultaneously exposed to temperature and humidity; and often presence of bonding defects. In fact, during joint preparation, several types of defects can be introduced into the adhesive layer such as air bubbles, cavities, or cracks, which induce stress concentrations potentially leading to premature failure. Indeed, the presence of defects in the adhesive joint has a significant effect on adhesive stresses, which emphasizes the need for a good surface treatment. The research in this field is aimed at minimizing the stresses in the adhesive joint at its free edges by geometric modifications of the ovelapping part and/or by changing the nature of the substrates. In this study, the finite element method is used to describe the mechanical behavior of bonded joints. Thus, a three-dimensional model is made to analyze the effect of defects in the adhesive joint at areas of high stress concentrations. The analysis consists of estimating the different stresses in an adhesive joint between two 2024-T3 aluminum plates. Two types of single lap joints(SLJ) were analyzed: a standard SLJ and another modified by removing 0.2 mm of material from the thickness of one plate along the overlap length, taking into account several factors such as the applied load, shape, size and position of the defect. The obtained results clearly show that the presence of a bonding defect significantly affects stresses in the adhesive joint, which become important if the joint is subjected to a higher applied load. On the other hand, the geometric modification made to the plate considerably reduces the various stresses in the adhesive joint even in the presence of a bonding defect.