• 공업화학
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• 제30권2호
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• pp.133-140
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• 2019

Two-dimensional (2D) ultrathin molybdenum dichalcogenides $MoS_2$ has gained a great deal of attention in energy conversion and storage applications because of its unique morphology and property. The 2D $MoS_2$ nanosheets provide a high specific surface area, 2D charge channel, sub-nanometer thickness, and high conductivity, which lead to high electrochemical performances for energy storage devices. In this paper, an overview of properties and synthetic methods of $MoS_2$ nanosheets for applications of supercapacitors and rechargeable batteries is introduced. Different phases triangle prismatic 2H and metallic octahedral 1T structured $MoS_2$ were characterized using various analytical techniques. Preparation methods were focused on top-down and bottom-up approaches, including mechanical exfoliation, chemical intercalation and exfoliation, liquid phase exfoliation by the direct sonication, electrochemical intercalation exfoliation, microwave-assisted exfoliation, mechanical ball-milling, and hydrothermal synthesis. In addition, recent applications of supercapacitors and rechargeable batteries using $MoS_2$ electrode materials are discussed.

• 반도체디스플레이기술학회지
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• 제10권3호
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• pp.7-13
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• 2011

In Korea, the car mobile phone service had started in 1961 and with this Korea Mobile Telecommunications Services was established in 1984. Its service was mainly focused on the mobile phone service for the car which led the popularity of the full-scale mobile phone service. There are many kinds of materials, colors and patterns which are the elements of surface coating techniques. In light of that, we are focused on the UV coating that is ranked as an important part of the techniques in this study. In the first, the use of various materials for the cellular phone and surface processing techniques for the cellular phone were searched. On the basis of the results, the experiments of actual consumer experience with the exfoliation of the surface were done and through that we proposed the best way of processing the surface for the cellular phone and the materials. The result of the Wear Test showed that thick coating was detached more slowly and each company differed in their results with UV paints despite the same thickness of UV coating. The seal (UV) exfoliation of cellular phone is deeply related with the film thickness and the film formation when the users use the cellular phones and the exfoliation of the cellular phone surface will be decreased if the manufacturers meet the best conditions for the cellular phone.

• Corrosion Science and Technology
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• 제9권6호
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• pp.265-269
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• 2010

This paper describes the exfoliation and surface modification of muscovite mica for UV coating formulation. For the exfoliation of the mica, hydrothermal process was used in the presence of lithium nitrate ($LiNO_3$). After the cation exchange with $Li^+$ ions, the surface of the mica was modified with several amphiphilic substances to increase compatibility and storage stability in UV coating formulation. Such a hydrophobic surface modification affected colloidal stability as well as dispersibility of the exfoliated mica in UV coating solution. Anticorrosive property of mica/UV coated steel plates was tested by salt spray test (SST) and compared with sodium montmorillonite ($Na^+$-MMT)/UV coated steel plates.

• 보존과학회지
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• 제22권
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• pp.121-134
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• 2008

석조문화재에서 나타나는 박리현상의 발생메커니즘과 염수용액에 의한 화학적 풍화와 관련된 그 원인을 연구하였다. 박리편에 대하여 화학적, 광물학적, 물리적 분석을 수행하여 함유하고 있는 대표적인 염이 석고임을 밝혔다. 염의 작용을 이해하기 위하여 석고와 더불어 용해도가 상이한 황산나트륨을 공극율이 다른 응회암과 화강암에 처리하였다. $Na_2SO_4$ 처리와 인공풍화를 거친 암석시료들의 모세관물흡수율은 약간 증가하였는데 이는 이 염에 의해 암석의 표면가까이에만 변화가 있었음을 의미한다. Na2SO4는 암석의 표면공극내에서 결정화가 일어나 수화압과 결정압을 발생하여 얇은 박리를 형성하는 것으로 보인다. $CaSO_4{\cdot}2H_2O$는 상대적으로 암석의 내부로 깊이까지 들어가서 집적되므로 집적되는 양이 $Na_2SO_4$ 보다 더 많고, 표면에 집적되는 양보다 내부에 집적되는 양이 많아 물흡수량이 증가하는 결과를 보이는 것이며, 이러한 성질로 인하여 암석에 두꺼운 박리가 야기될 것으로 판단된다. 암석종에 따른 변화에서는 응회암의 경우, 큰 공극율과 높은 모세관물흡수율로 인하여 암석 내부의 깊이까지 들어가서 염이 집적하게 되므로 화강암에 비해 염집적율이 더 크고, 이에 따른 물흡수율이 커서 화강암에 비해 두꺼운 박리현상이 나타날 것으로 보인다. 이에 비해 공극율과 모세관물흡수율이 낮은 화강암에서는 표면부위에서 집중적으로 염의 집적이 일어나서 얇은 박리가 발생하는 것으로 판단된다.

• 한국생산제조학회지
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• 제7권4호
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• pp.117-122
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• 1998

Glass fiber epoxy composite material is widely used in the structures of aircrafts, robots and other machines because of their high specific strength, high specific stiffness and high damping. In order for the composite materials to be used in the aircraft structures or machine elements, accurate surfaces for bearing mounting or joint must be provided, which require precise machining. In this paper, the machinability of the glass fiber epoxy composite material was experimentally investigated. The results can be summarized as follows : 1. The entrance of hole is very good manufacturing existing, but exit come to occur sever surface exfoliation. 2. The cutting force in drilling of the glass fiber epoxy composite material is decreased as the drilling speed increased. 3. If the glass fiber epoxy composite material is drilling by the standard twist drill, then the hole recommand cutting condition is spindle speed 400∼600rpm, feed 40∼50mm/min.

• 한국정밀공학회지
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• 제15권10호
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• pp.203-208
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• 1998

Carbon fiber epoxy composite materials are widely used in the structures of aircrafts, robots and other machines because of their high specific strength, high specific stiffness and high damping. In order for the composite materials to be used in the aircraft structures or machine elements, accurate surfaces for bearing mounting or joints must be provided, which require precise machining. In this paper, the machinability characterisitcs of the drilling operation of the carbon fiber epoxy composite materials was experimentally investigated. The experimental results are as follows 1.The entrance of hole is very good manufacturing existing, but exit come to occur sever surface exfoliation. 2. The cutting force in drilling of the carbon fiber epoxy composite materials is decreased as the drilling speed increased. 3.The hole of the carbon fiber epoxy composite materials is not good manufacturing by use of the standard twist, therefore, the new drill designed in order to accurate hole.

• 보존과학회지
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• 제19권
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• pp.57-66
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• 2006

나주동문외석당간(보물 제49호)은 심한 풍화에 의해 많이 훼손되어 있다. 이 연구의 목적은 풍화양상을 분석하여 그 요인을 파악하여 보존대책 수립의 기본 자료를 구축하는데 있다. 이 석당간을 이루고 있는 암석은 중립 내지 조립질의 흑운모화강암이며, 이 암석은 주위에 비교적 넓게 분포하고 있는 중생대의 흑운모화강암체로부터 채취한 것으로 판단된다. 이 암석을 이루고 있는 주 구성광물은 석영, 사장석, 알칼리 장석 및 흑운모 등이다. 이 암석의 표면은 심한 풍화에 의해 전체적으로 입자박락과 표면박리가 잘 발달되어 있다. 또한 풍화, 오염물 그리고 철띠의 산화물 등의 영향에 의해 붉게 또는 검게 변색되어 있는 곳이 많다. 암석 표면은 전체적으로 유기물에 의해 피복되어 있다. 띠로 사용된 철의 부식물은 부분적으로 산화철 또는 수산화철로 재침전되어 표면을 피복하기도 한다. 훼손양상으로 중요한 것들은 입자박락, 표면박리, 균열, 흑화현상 및 부재들의 모서리 부분의 파손 등을 들 수 있다. 이들은 주로 풍화, 철 부식물의 영향, 유기물의 피복, 구조적 불안정 및 충격 등의 요인에 의한 것으로 판단된다. 전체적으로 볼 때 구조적으로 약간 불안정하며 풍화에 의한 균열이 계속 진행되고 있는 것으로 판단되어 이에 대한 대책이 필요하다고 생각된다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.449-452
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• 2008

본 연구는 골재의 표면수 변동에 따른 콘크리트의 품질변동이 안정하며 현장에서 무진동 무다짐 시공이 가능한 병용계 고유동 자기충전콘크리트 (High flowing Self-Compacting Concrete ; 이하 HSCC라 약함)를 제조하였으며, 실내실험을 통하여 경화 전 후 콘크리트에서 발생하는 기포의 저감 요인을 검토하고자 한다. 병용계 HSCC는 굳지 않은 콘크리트의 점성을 증가하기 위하여 증점제의 사용은 필연적이며 이러한 결과 분체계 HSCC보다 많은 수의 기포를 발생시킨다. 또한 경화 후 콘크리트 내에 갇흰공기의 발생으로 만들어진 표면의 기포는 구조물의 미관뿐만 아니라 강도 및 내구성에도 나쁜 영향을 미치는 연구결과가 보고 되고 있다. 본 논문에서는 병용계 HSCC의 기포발생을 저감하기 위하여 골재(잔골재) 종류, 콘크리트 비빔시간, 박리제 종류 및 모형 거푸집 재질에 따른 콘크리트의 기포발생에 대한 실험을 실시하였다. 실험 결과 박리제 및 모형 거푸집 재질에 따른 경화 후 병용계 HSCC의 표면마감성능은 거푸집의 영향 보다 박리재의 영향이 크게 작용하였으며 불투명 구리스가 가장 좋은 마감상태를 유지하였다.

• 한국건축시공학회지
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• 제7권4호
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• pp.125-132
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• 2007

The use of Self-Leveling material is increasing recently. This paper assesses the quality of surface layer of concrete floor when Self-Leveling material is defective. The paper shows how to predict the defect of SL material before construction begins. The relationship between the quality of surface layer of concrete floor and the defect of SL material was determined and the quality of surface layer of concrete floor was then estimated. The relations between the quality of surface layer and the defect of SL material were determine considering surface strength, moisture, and consistency of surface layer. Absorbing amount was used as the indicator of consistency and the absorbing amount of test material was measured. Then the relations between the test material and surface strength were determined. Generally concrete floor with greater consistency has greater surface strength, however in this study, we hound that high impact concrete floor could have lower surface strength as the consistency gets bigger. The relations between the level of defect occurred in SL material and the quality of surface layer were examined and we clarified that the surface layer with lower consistency gets higher possibility to occur exfoliation in early stage, one or two weeks after constructing SL material. When the consistency is sufficient, the occurring situation of defect depends upon the moisture of surface layer. Little amount of moisture gets higher possibility not to occur the defect. As the amount increases, fissure generates and early exfoliation may occur. In addition, the level of fissure is highly related with the surface strength.

• 한국정밀공학회지
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• 제27권7호
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• pp.79-86
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• 2010

The environment-friendly abrasive materials of starch series has a wide range of application value such as deburring of plastic injection products, paint exfoliation and surface treatment of painted products and polishing, etc. In this study, an experiment of paint exfoliation was performed by using the environment-friendly abrasive materials made of cheap starch, and its performance was reviewed. By adjusting the grit size of abrasive materials, nozzle pressure, nozzle feed and number of nozzle repetition, paint could be exfoliated effectively. In this experiment, it was found that the most suitable condition was grit size 0.75~1.0 mm, nozzle pressure 0.4 MPa, nozzle feed 5 mm/min and number of processing repetition 2 times.