• Title/Summary/Keyword: Surface exfoliation

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Properties, Preparation, and Energy Storage Applications of Two-dimensional Molybdenum Disulfide (2차원 이황화몰리브덴의 성질, 제조 및 에너지 저장 소자 응용)

  • Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.133-140
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    • 2019
  • Two-dimensional (2D) ultrathin molybdenum dichalcogenides $MoS_2$ has gained a great deal of attention in energy conversion and storage applications because of its unique morphology and property. The 2D $MoS_2$ nanosheets provide a high specific surface area, 2D charge channel, sub-nanometer thickness, and high conductivity, which lead to high electrochemical performances for energy storage devices. In this paper, an overview of properties and synthetic methods of $MoS_2$ nanosheets for applications of supercapacitors and rechargeable batteries is introduced. Different phases triangle prismatic 2H and metallic octahedral 1T structured $MoS_2$ were characterized using various analytical techniques. Preparation methods were focused on top-down and bottom-up approaches, including mechanical exfoliation, chemical intercalation and exfoliation, liquid phase exfoliation by the direct sonication, electrochemical intercalation exfoliation, microwave-assisted exfoliation, mechanical ball-milling, and hydrothermal synthesis. In addition, recent applications of supercapacitors and rechargeable batteries using $MoS_2$ electrode materials are discussed.

A Study on Surface Treatment and Configuration Design of Cellular Phone (핸드폰의 형상디자인과 표면처리에 대한 연구)

  • Lee, Jung-Hyun;Park, Jae-Won
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.3
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    • pp.7-13
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    • 2011
  • In Korea, the car mobile phone service had started in 1961 and with this Korea Mobile Telecommunications Services was established in 1984. Its service was mainly focused on the mobile phone service for the car which led the popularity of the full-scale mobile phone service. There are many kinds of materials, colors and patterns which are the elements of surface coating techniques. In light of that, we are focused on the UV coating that is ranked as an important part of the techniques in this study. In the first, the use of various materials for the cellular phone and surface processing techniques for the cellular phone were searched. On the basis of the results, the experiments of actual consumer experience with the exfoliation of the surface were done and through that we proposed the best way of processing the surface for the cellular phone and the materials. The result of the Wear Test showed that thick coating was detached more slowly and each company differed in their results with UV paints despite the same thickness of UV coating. The seal (UV) exfoliation of cellular phone is deeply related with the film thickness and the film formation when the users use the cellular phones and the exfoliation of the cellular phone surface will be decreased if the manufacturers meet the best conditions for the cellular phone.

Preparation and Characterization of Muscovite Mica/UV Coating Materials for Steel

  • Cheong, In-Woo;Kim, Hyeon-Seok;Hwang, Dong-Seop;Yoo, Hye-Jin;Kim, Jin-Tae;Lee, Jae-Ryung
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.265-269
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    • 2010
  • This paper describes the exfoliation and surface modification of muscovite mica for UV coating formulation. For the exfoliation of the mica, hydrothermal process was used in the presence of lithium nitrate ($LiNO_3$). After the cation exchange with $Li^+$ ions, the surface of the mica was modified with several amphiphilic substances to increase compatibility and storage stability in UV coating formulation. Such a hydrophobic surface modification affected colloidal stability as well as dispersibility of the exfoliated mica in UV coating solution. Anticorrosive property of mica/UV coated steel plates was tested by salt spray test (SST) and compared with sodium montmorillonite ($Na^+$-MMT)/UV coated steel plates.

Influence of the Soluble Salt on the Exfoliation of the Stone Monument (수용성염이 석조문화재 표면 박리현상에 미치는 영향)

  • Do, Jin-Young;Lim, Kwon-Woong
    • Journal of Conservation Science
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    • v.22
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    • pp.121-134
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    • 2008
  • The mechanism of stone exfoliation and its cause in relation to chemical weathering by soluble salt were studied. Chemical, mineralogical and physical analysis was performed in exfoliation samples from stone monuments. The representative salt is gypsum in the exfoliation samples. In order to understand the salt reaction, stone samples(tuff and granite) were treated with two type of the salt, gypsum and sodium sulfate, which have different solubility. The capillary water uptakes are slight increased in impregnated with Na2SO4 and weathering simulation of two rock types. It means that the rock is deteriorated in the near of the surface by $Na_2SO_4$. $CaSO_4{\cdot}2H_2O$ bring out the thicker exfoliation than $Na_2SO_4$ because it is penetrated into the deeper zone and amount of accumulated salt is more abundant in the inner part than in the near of the surface. The exfoliation was formed in the tuff by salt treatment and 30cycle of weathering simulation, but there are not significant symptoms of exfoliation in the granite by same condition. This result was caused by the different capillary water uptakes and porosity of the rocks. In the tuff, salt solutions are penetrated into the inner part due to its high capillary water uptakes and porosity but the granite, which has low value relatively, can be formed thinner exfoliation.

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Precise Drilling characteristics of glass fiber epoxy composite material (유리섬유 에폭시 복합재료의 정밀드릴가공 특성)

  • 김홍배
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.7 no.4
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    • pp.117-122
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    • 1998
  • Glass fiber epoxy composite material is widely used in the structures of aircrafts, robots and other machines because of their high specific strength, high specific stiffness and high damping. In order for the composite materials to be used in the aircraft structures or machine elements, accurate surfaces for bearing mounting or joint must be provided, which require precise machining. In this paper, the machinability of the glass fiber epoxy composite material was experimentally investigated. The results can be summarized as follows : 1. The entrance of hole is very good manufacturing existing, but exit come to occur sever surface exfoliation. 2. The cutting force in drilling of the glass fiber epoxy composite material is decreased as the drilling speed increased. 3. If the glass fiber epoxy composite material is drilling by the standard twist drill, then the hole recommand cutting condition is spindle speed 400∼600rpm, feed 40∼50mm/min.

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A Study on Precise Drilling Characteristics of Carbon Fiber Epoxy Composite Materials (탄소섬유 에폭시 복합재료의 정밀드릴가공 특성에 관한 연구)

  • 김홍배
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.10
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    • pp.203-208
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    • 1998
  • Carbon fiber epoxy composite materials are widely used in the structures of aircrafts, robots and other machines because of their high specific strength, high specific stiffness and high damping. In order for the composite materials to be used in the aircraft structures or machine elements, accurate surfaces for bearing mounting or joints must be provided, which require precise machining. In this paper, the machinability characterisitcs of the drilling operation of the carbon fiber epoxy composite materials was experimentally investigated. The experimental results are as follows 1.The entrance of hole is very good manufacturing existing, but exit come to occur sever surface exfoliation. 2. The cutting force in drilling of the carbon fiber epoxy composite materials is decreased as the drilling speed increased. 3.The hole of the carbon fiber epoxy composite materials is not good manufacturing by use of the standard twist, therefore, the new drill designed in order to accurate hole.

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Petrological Characteristics and Deterioration phenomena of the rocks consisting the Naju-Dongmunoi-Seogdanggan(Stone Stele) (나주동문외석당간 구성암석의 암석학적 특징과 훼손양상)

  • Lee, Sang-Hun
    • Journal of Conservation Science
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    • v.19
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    • pp.57-66
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    • 2006
  • The rock consisting the Naju-Dongmunoi-Seogdanggan (Stone Stele)(Treasure number 49) is biotite granite of medium to coarse grains which might be taken from nearby area. The rock is mainly composed of quartz, plagioclase, alkali feldspar and biotite. Due to strong weathering grail peel-off and surface exfoliation are well developed. The rock surface is changed into pale brown or pale black colors according to weathering, organism and weathering product of iron band. Major deterioration phenomena are grain peel-off, surface exfoliation, cracks and damage which may be originally classified into weathering, effect of weathering product of iron band, organisms, structural unstabilities and impact.

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The Study for the Air Bubble Deterioration of Combined High Flowing Self-Compacting Concrete (병용계 고유동 자기충전콘크리트의 기포저감을 위한 연구)

  • Choi, Yun-Wang;Kim, Kyung-Hwan;Ruy, Deug-Hyun;Jeong, Jae-Gwon;Kang, Hyun-Jin;Lee, Jae-Nam
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.449-452
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    • 2008
  • This study is to manufacture HSCC (High flowing Self-Compacting Concrete) be able to construction without vibration & hardening, and it is stable according to the change of the surface number of aggregate and to examine the factor of reduction occurred before after hardening through the indoor experiment. It is essential to use of the thickener to increase the viscosity in the combined HSCC. In this result, it make more bubbles than HSCC of pulverulent body. The result of study has shown, through the surface air bubble by not passed air bubbles within concrete after hardening, It has bad effect in not only appearance of structures but strength & duration. It is the experiment for air bubble of concrete according to the types of aggregate (fine aggregate), mixing time of concrete, exfoliation, material of model form and so that reduce the air bubble of combined HSCC. Experiments have shown, the effect of exfoliation was bigger than the effect of form for the performance of surface finishing of combined HSCC after hardening according to the exfoliation or material of model form and the opaque guris has good condition of finishing.

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The Relationship Between the Quality of Surface Layer of Concrete Floor and the Defect of Self-Leveling Material - Evaluation Method about Surface Layer Quality of Concrete Floor Groundwork Corresponding to Defect in Self-leveling Material (Part II) - (콘크리트 표층부 품질이 SL재의 하자에 미치는 영향 - SL재의 하자 발생에 영향을 미치는 콘크리트 표층부의 품질 평가방법(II) -)

  • Kim, Doo-Ho;Choi, Soo-Kyung
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.4
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    • pp.125-132
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    • 2007
  • The use of Self-Leveling material is increasing recently. This paper assesses the quality of surface layer of concrete floor when Self-Leveling material is defective. The paper shows how to predict the defect of SL material before construction begins. The relationship between the quality of surface layer of concrete floor and the defect of SL material was determined and the quality of surface layer of concrete floor was then estimated. The relations between the quality of surface layer and the defect of SL material were determine considering surface strength, moisture, and consistency of surface layer. Absorbing amount was used as the indicator of consistency and the absorbing amount of test material was measured. Then the relations between the test material and surface strength were determined. Generally concrete floor with greater consistency has greater surface strength, however in this study, we hound that high impact concrete floor could have lower surface strength as the consistency gets bigger. The relations between the level of defect occurred in SL material and the quality of surface layer were examined and we clarified that the surface layer with lower consistency gets higher possibility to occur exfoliation in early stage, one or two weeks after constructing SL material. When the consistency is sufficient, the occurring situation of defect depends upon the moisture of surface layer. Little amount of moisture gets higher possibility not to occur the defect. As the amount increases, fissure generates and early exfoliation may occur. In addition, the level of fissure is highly related with the surface strength.

A Study on Blasting for Paint Exfoliation on Plastic Coated Faces Using the Environment-Friendly Abrasive Materials of Starch Series (친환경 전분계 연마재를 이용한 플라스틱 도장면의 페인트 박리를 위한 블라스팅 가공에 관한 연구)

  • Li, Li-Hai;Kim, Yeon-Sul;Lee, Hi-Koan;Yang, Gyun-Eui;Mun, Sang-Don
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.7
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    • pp.79-86
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    • 2010
  • The environment-friendly abrasive materials of starch series has a wide range of application value such as deburring of plastic injection products, paint exfoliation and surface treatment of painted products and polishing, etc. In this study, an experiment of paint exfoliation was performed by using the environment-friendly abrasive materials made of cheap starch, and its performance was reviewed. By adjusting the grit size of abrasive materials, nozzle pressure, nozzle feed and number of nozzle repetition, paint could be exfoliated effectively. In this experiment, it was found that the most suitable condition was grit size 0.75~1.0 mm, nozzle pressure 0.4 MPa, nozzle feed 5 mm/min and number of processing repetition 2 times.