• Title/Summary/Keyword: Surface concentration

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Evaluating Two Types of Rectangular Secondary Clarifier Performance at Biological Nutrient Removal Facilities (생물학적 고도처리공법에 적용된 두 형태의 장방형 이차침전지 성능 파악)

  • Lee, Byonghi
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.5
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    • pp.561-570
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    • 2013
  • There are two types of rectangular secondary clarifier at biological nutrient removal (BNR) facility to settle MLSS; conventional activated sludge secondary clarifier and Gould Type I clarifier. In this study, the performances of two types at respective biological nutrient removal facility are compared using weekly operational data. Surface Overflow Rate (SOR), Surface Loading Rate (SLR), Sludge Volume Index (SVI), secondary effluent SS concentration are studied. It has found that Gould Type I has 3.5 times less average secondary effluent SS concentration that is 2.4 mg/L than that of conventional activated sludge secondary clarifier. Both SOR and SLR have shown little effect on secondary effluent SS concentrations at Gould Type I clarifier in contrary that SOR affects the secondary effluent SS concentrations at conventional activated sludge rectangular secondary clarifier. From this study, it is recommended that Gould Type I must be considered for secondary clarifier when BNR plant is designed.

Model and Experimental Isotherms of Soluble Proteins at water sur faces (수용성 단백질의 계면상 등온곡선의 모델과 실험적 규명)

  • Cho, D.
    • Proceedings of the KAIS Fall Conference
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    • 2003.06a
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    • pp.328-330
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    • 2003
  • A surface equation of state for globular proteins at air-water interface accounting for the molecular structure, segment-segment, segment-solvent, and electrostatic interactions was proposed and compared to C-14 isotope experiments. This lattice model comprised a simplifying assumption that all adsorbed segments are in the form of trains. The number of segment adsorbed per molecule in case of bovine serum albumin linearly depended on the surface concentration whereas the lysozyme segments adsorbed at the interface were independent of surface concentration. The segment-solvent(water) interaction for both of proteins were found to be unfavorable owing to the proteins unfolding. From comparison of model computation and experimental data, BSA unfolded more than lysozyne because of the larger surface area of contact.

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TEXTURE AND RELATED PHENOMENA OF ELECTRODEPOSITS

  • Lee, D.N.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.317-330
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    • 1999
  • The texture of electrodeposits changes from the orientation that places the lowest energy crystal facets parallel to the substrate under a condition of low ion concentration adjacent to the deposit, to the orientation that places the higher energy crystal facets parallel to the substrate as the ion concentration adjacent to the deposit increases. The electrodeposits have peculiar surface morphologies and microstructures depending on their textures, which in turn may affect their mechanical properties even when they are obtained in a similar electrolysis condition. The electrodeposits undergo recrystallization, when annealed. The recrystallization texture may be different from the deposition texture. These phenomena have been discussed.

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Surface Characterization of Zinc Selenide Thin Films Obtained by RF co-sputtering

  • Lee, Seokhee;Kang, Jisoo;Park, Juyun;Kang, Yong-Cheol
    • Journal of the Korean Chemical Society
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    • v.66 no.5
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    • pp.341-348
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    • 2022
  • In this work, radio frequency magnetron sputtering was used to deposit zinc selenide thin films on p-type silicon (100) wafers and glass substrates in a high vacuum chamber. Several surface characterization instruments were implemented to study the thin films. X-ray photoelectron spectroscopy results revealed that oxidized Zn bound to Se (Zn-Se) at 1022.7 ± 0.1 eV becomes the dominant oxidized species when Se concentration exceeds 70%. Scanning electron microscopy coupled with energy dispersive spectroscopy showed that incorporating Se in Zn thin films will lead to formation of ZnSe grains on the surface. Contact angle measurements indicated that ZnSe-60 exhibited the lowest total surface free energy value of 24.94 mN/m. Lastly, ultraviolet-visible spectrophotometry and ultraviolet photoelectron spectroscopy data evinced that the energy band gap gradually increases with increasing Se concentration with ZnSe-70 having the highest work function value of 4.91 eV.

Surface Graft Copolymerization of Acrylamide onto Polyacrylonitrile (아크릴아미드의 PAN에 대한 표면 그라프트 공중합에 관한연구)

  • 최재혁;김한도
    • Textile Coloration and Finishing
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    • v.5 no.2
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    • pp.144-148
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    • 1993
  • To increase the moisture content and thereby to reduce the static charge of polyacrylonitrile (PAN), thin layer surface photografting of acylamide (AAm) onto PAN fabrics by using benzophenone as a initiator with a mixtured solvent was carried. The effects of reaction conditions such as monomer, initiator concentrations, UV irradiation time and immersion time of fabrics on grafting were investigated. The percent grafting slightly increased with increasing monomer concentration, benzophenone concentration up to limiting value and thereafter decreased or level offed. The percent grafting was significantly increased with increasing irradiation and immersion times. The moisture regain increased with increasing the percent grafting. The static charge decreased with increasing the percent grafting.

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A study on the PEO films on Mg alloys in aqueous solution (마그네슘 합금의 PEO 피막 형성 연구)

  • Nam, Yun-Gyeong;Mun, Seong-Mo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.95-95
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    • 2012
  • In this study, the effect of $PO{_4}^{3-}$ ions on formation of PEO(Plasma Electrolytic Oxidation) films was investigated in aqueous solution. A minimum concentration of $PO{_4}^{3-}$ ions was necessary for the formation of PEO film on pure Mg and arcing voltage of pure Mg decreased with increasing $PO{_4}^{3-}$ ion concentration. Immersion test to evaluate the corrosion resistance of PEO-treated pure Mg and Mg alloys were conducted in 0.5M NaCl solution.

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ELECTROLESS PLATING OF NICKEL FOR MICRO-STRUCTURE FABRICATION

  • Jin, Huh;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.331-335
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    • 1999
  • Electroless plating nickel has superior mechanical property to electroplated nickel. Furthermore nickel can be coated on nonconducting substrate. In this research, electroless plating of nickel were conducted in different bath condition to find optimum conditions of electroless nickel plating for MEMS applications. The selectivity of activation method on several substrates was investigated. The effects of nickel concentration, reducing agent concentration and inhibitor on deposition rate were investigated. The effect of pH on deposition rate and content of phosphorous in deposited nickel was also investigated.

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Electrochemical aspects of electroless nickel-boron plating (무전해 Ni 도금의 전기화학적 고찰)

  • 김영기;이원해
    • Journal of the Korean institute of surface engineering
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    • v.26 no.4
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    • pp.175-182
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    • 1993
  • Electroless plating of nickel was studied electrochemically in the presence of complexing agents. Nickel sulfate solution with dimethylamine borance(DMAB) as the reducing agent was used. Effects of temperature pH, concentration and complexing agents-citric acid, EDTA, tartaric acid-were studied.Experimental meas-urements showed that the rate of electroless nickel deposition was closely related to electrochemical parame-ters such as temdperature, pH, concentration and the properties of complexing agets.

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Optimization of Microwave Extraction Conditions for Flammulina velutipes by Response Surface Methodology (반응표면분석에 의한 팽이버섯의 microwave 추출조건 최적화)

  • Kim, Hyun-Ku;Kim, Mi-Ok;Choi, Mal-Gum;Kim, Kong-Hwan
    • Korean Journal of Food Science and Technology
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    • v.35 no.2
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    • pp.222-228
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    • 2003
  • Optimum extraction conditions for yield, browning color, electron-donating ability, nitrite-scavenging effect, total polyphenol content, and tyrosinase-inhibitory activity of Flammulina velutipes were determined using response surface methodology through central composite design. Yield of F. velutipes was affected by ethanol concentration, and browning color improved more with the increase of ethanol concentration than microwave power. Nitrite-scavenging effect was improved with increasing ethanol concentration and decreasing microwave power. Electron-donating ability and total polyphenol content were improved with increasing ethanol concentration and microwave power. Tyrosinase-inhibitory effect increased more with decrease in microwave power than with ethanol concentration. The optimal range of extraction conditions for effective component of F. velutipes were $47.21{\sim}76.05$ watt of microwave power, $10.25{\sim}43.56%$ of ethanol concentration, and 5.72 min of extraction time.

A study on the Manufacture of the CuO Powder from Copper Chloride Solution by Spray Pyrolysis Process (분무열분해법에 의한 구리염화물 용액으로부터 CuO 분말 제조에 관한 연구)

  • Yu, Jae-Geun;Park, Hui-Beom
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.58-67
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    • 2002
  • In this study copper chloride(CuCl$_2$) solution was used as raw material to produce the fine copper oxide powder which has less than 1 $\mu\textrm{m}$ average particle size and has uniform particle size distribution by spray pyrolysis process. In the present study, the effects of reaction temperature, the injection speed of solution and air, the nozzle tip size and the concentration of raw material solution on the properties of produced powder were studied. The structure of the powder became much more compact with increasing the reaction temperature regardless of copper concentration of the raw material solution. The particle size of the powder increased accordingly with increasing the reaction temperature in case of 30 g/$\ell$ copper concentration of the solution. The particle size of the powder increased accordingly, and the surface structure of the powder became more porous with increasing the copper concentration of the raw material solution. When copper concentration in raw material solution was more than 100 g/$\ell$, all produced powder was CuCl regardless of reaction temperatures. When copper concentration in solution was below 30 g/$\ell$ and reaction temperature was higher than 90$0^{\circ}C$, CuO was the main phase. The surface of the powder tended to become porous with increasing the injection speed of solution. Particle size was increased and the surface of the powder showed severely disrupted state with increasing the nozzle tip size. The particle size was decreased and the particle size distribution was more uniform with increasing the air pressure through the nozzle.