• Title/Summary/Keyword: Surface concentration

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방사성핵종 오염 토양 특성 분석 및 핵종제거 방법 연구

  • 김계남;원휘준;오원진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.209-212
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    • 2002
  • Main radionuclides of the soil waste stored in Korea Atomic Energy Research Institute are Co-60 and Cs-137. Moisture content of soil is 12%, pH of soil is 5.8, and content of organic matter is 2.2 %. Radioactive concentrations of the soil particle size of which is less than 0.063mm and soil in the drum surface of which is more than radiation dose rate 0.05mR/hr are higher. Meanwhile, radioactive concentration of soil in the drum surface of which is less than radiation dose rate 0.02 mR/hr are mostly lower. On using the mixing solution of ammonium sulfate and citric acid, 62% Co was removed from soil and 41% Cs was removed. Also, on using the mixing solution of ammonium nitrate and citric acid, 61% Co was removed from soil and 39% Cs was removed, and on using the mixing solution of ammonium potassium oxalate, 36% Co was removed and only 3% Cs was removed. And on using only water, removal efficiency is less than 5%.

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UV-Induced Graft Polymerization of Polypropylene-g-glycidyl methacrylate Membrane in the Vapor Phase

  • Hwang, Taek-Sung;Park, Jin-Won
    • Macromolecular Research
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    • v.11 no.6
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    • pp.495-500
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    • 2003
  • UV-induced graft polymerization of glycidyl methacrylate (GMA) to a polypropylene (PP) membrane was carried out in the vapor phase with benzophenone (BP) as a photoinitiator. Attenuated total reflection Fourier transform infrared spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM) were utilized to characterize the copolymer. The degree of grafting increased with increasing reaction time, increased UV irradiation source intensity, and increased immersion concentration of the BP solution. The optimum synthetic condition for the PP-g-GMA membrane was obtained with a reaction time of 2 hrs, a UV irradiation source intensity of 450 W, and an immersion concentration of the BP solution of 0.5 mol/L. The pure water flux decreased upon increasing the degree of grafting and increasing the amount of diethylamino functional group introduced. The analysis of AFM and SEM images shows that the graft chains and diethylamino groups of PP-g-GMA grew on the PP membrane surface, resulting in a change in surface morphology.

Hydroxyapatite Coating on Ti Plate by a Dipping Method (침적법에 의한 수산화아파타이트 코팅 금속재의 기초적 연구)

  • Lee, Jun-Hui;Kim, Seok-Yeong;Kim, Yeong-Gon;Lee, In-Seop
    • Journal of Biomedical Engineering Research
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    • v.18 no.3
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    • pp.217-222
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    • 1997
  • Hydroxyapatite(HA)-coated metal composites were made by the dipping method. The specimen substrates were Ti plates with a thickness of 2 mm. The HA coating was carried out in HA-sol for 1 min by the dipping method. The concentration of HA-sol for the coating ranged from 3.28 to 9.99 wt%. Excellent coating was observed on Ti substrate dipped once in 9.99 wt% sol. Preparation of Ti plates by sandblasting provided the better environment for coating HA on Ti surface than non-treated surface. As the concentration of sol increased, the weight change and the coating thickness increased. Above 7 wt% sol, they increased sharply.

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The Effects of the Drive-in Process Parameters on the Residual Stress Profile of the p+ Thin Film (후확산 공정 조건이 p+ 박막의 간류 응력 분포에 미치는 영향)

  • Park, T.G.;Jeong, O.C.;Yang, S.S.
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.1007-1009
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    • 1998
  • In this paper, the effects of the drive-in process parameters on the residual stress profile of the p+ silicon film has been investigated. All the residual stress profile has been estimated by the second-order polynomial. All the coefficients of the polynomial have been determined from the measurement of the deflections of cantilevers and a rotating beam by using a surface profiler meter and by means of focusing a calibrated microscope. As the drive-in temperature or the drive-in time increases, the boron concentration decreases and the magnitude of the average residual stress decreases. If the boron concentration decreases the tensile residual stress decreases except near the surface where the magnitude of compressive residual stress increases.

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Investigation of field emission mechanism of undoped polycrystalline diamond films (도핑되지 않은 다결정 다이아몬드 박막의 전계방출기구 조사)

  • 심재엽;지응준;송기문;백홍구
    • Journal of the Korean Vacuum Society
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    • v.8 no.4A
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    • pp.417-424
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    • 1999
  • In order to investigate field emission mechanism of undoped polycrystalline diamond films, diamond films with different structural properties were deposited by varying positive substrate bias and/or $CH_4$ concentration. When increasing $CH_4$ concentration and positive substrate bias voltage, nondiamond carbon content in diamond films increased. Increase of nondiamond carbon content with increasing substrate voltage is ascribed to increase of substrate and excess generation of $CH_n$ radicals. Field emission properties of undoped polycrystalline diamond films ere significantly enhanced with increasing nondiamond carbon content. For diamond films with a small amount of nondiamond carbon, electrons are emitted through diamond surface while for the films with a large amount of nondiamond carbon, electron emission occurs through diamond bulk as well as surface. From this study, depending on nondiamond carbon content two field emission mechanisms were suggested.

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Development of Novel Techniques for Determining the Oxygen Tracer Diffusion Coefficients in Oxides II - Measurements of the Depth Profiles of $^{18}O$ Concentration in the solid Samples by Raman Spectroscopy (산화물에서의 산소추적자확산계수를 결정하는 새로운 방법의 개발 II - 라만분광법에 의한 고체시료 중의 시간에 따른 $^{18}O$ 농도변화 측정 -)

  • 김병국;마하구찌히로오;박순자
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1459-1466
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    • 1994
  • A novel technique for determining the oxygen tracer diffusion coefficients in oxides was developed. After the 16O-18O solid-gas exchange reactions between 16O in the oxides and 18O in the ambient gas, Raman spectra of the cross sections of oxide samples were measured in a spatial resolution of 5 ${\mu}{\textrm}{m}$. From thus obtained Raman spectra, depth profiles of 18O concentration in the oxide samples were calculated. The oxygen tracer diffusion coefficients and the surface exchange coefficients were determined under the assumptions that samples are semi-infinite slab and that the surface exchange reactionsare not negligible. The oxygen tracer diffusion coefficient of 2.8 mol% Y2O3-containing tetragonal ZrO2 polycrystals, 8 mol% Y2O3-containing ZrO2 polycrystals, and 10 mol% Y2O3-containing cubic ZrO2 single crystals (along the a axis) are as follows.

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Optimization of Spirogyra Flocculation Using Polyaluminium Chloride (Polyaluminium Chloride를 이용한 미세조류 Spirogyra의 응집 최적화)

  • Baek, Jaewon;Choi, Jong-Il
    • KSBB Journal
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    • v.29 no.3
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    • pp.220-224
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    • 2014
  • Flocculation is known one of the effective methods for harvesting microalgae. This study was aimed to optimize the flocculation condition for decreasing the amounts of flocculant and obtaining the highest yield of algal biomass. To achieve this goal, it was optimized the flocculant concentration, reaction pH and the concentration of cell density for harvest using response surface methodology (RSM). The flocculation of microalgae, Spirogyra varians, was carried out using inorganic flocculant polyaluminium chloride. By the RSM result, the optimal flocculation condition was calculated 5 ppm of polyaluminum chloride, pH 7.5 and 0.33 of optical cell density at $OD_{640}$. The obtained recovery yield of S. varians was 97.6% at the optimal condition.

Characterization of CNT-ink and fabrication of a cold cathode using jet-printing technique.

  • Lee, Dae-Sik;Lim, Seong-Chu;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1532-1534
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    • 2008
  • Aquesous carbon nanotubes (CNTs) solutions were prepared using SDS (sodium dodecyl sulfonate) and NADDBS (sodium dodecylbenzene sulfonate). Our inks are found to have the viscosity of 1-2 cps. In addition, the surface tension of inks inversely decreased with increasing surfactant concentration and then saturated at critical micelle concentration (CMC). The low surface tension at CMC gave rise to lower contact angles on Indium layers, resulting in larger printable feature sizes. In the fabrication of cold cathode, jet-printing is feasible to modify and scale up the cathode structures. These feasibilities could contribute jet-printing method to be more adaptable for making large-area cold cathodes.

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The Effects of Chlorination on the Friction Properties of SBR (염소화 반응조건이 SBR의 표면마찰 특성에 미치는 영향)

  • Park, Cha-Cheol;Kim, Ho-Jung
    • Fashion & Textile Research Journal
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    • v.10 no.1
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    • pp.101-105
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    • 2008
  • This study was concerned with the influence of reaction conditions on the surface friction properties of Syrene-Butadiene Rubber(SBR) sheet when it was chlorinated by chemical treatment method using the sodium hypochlorite and sulfuric acid. The results of this study were as follows. SEM photographs of chlorinated SBR surface showed uneven etching caused by the chlorination. In the FTIR spectra, the intensity of C=C peak of SBR was decreased with increasing the concentration of sodium hypochlorite. Otherwise there was no trace of C=C peak in spectrum of SBR treated with 5 wt% NaOCl with pH 0.1 for 90 seconds. EDX spectra showed that relative content of chlorine of SBR was increased with increasing the amount of sodium hypochlorite, and also affected with pH condition of acid solution. Friction angle and friction coefficient of SBR were influenced with concentration of sodium hypochlorite, but were not with pH condition of acid solution.

Fatigue Strength of the Load-Carrying Cruciform Fillet Welded Joints Using the Hot-Spot Stress (Hot-Spot 응력을 이용한 하중전달형 십자형 필렛 용접재의 피로강도 평가)

  • Park, Jong-Min;Choi, Won-Sik;Kwon, Soon-Hong;Noh, Byeong-Wook
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.6 no.1
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    • pp.20-26
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    • 2007
  • In this study, fatigue strength of load-carrying cruciform fillet welded joints were evaluated using a new method proposed by Yamada, for geometric or structural stress in welded joint, that is, one-millimeter stress below the surface in the direction corresponding to the expected crack path. Validity of the method is verified by analyzing fatigue test results for load-carrying cruciform welded specimens has different size of weld toe radius, leg length and plate thickness reported in literature. Structural stress concentration factor for 1mm below the surface was calculated by finite element analysis for each specimen respectively. When compared to the basic fatigue resistance curve offered by BS7608, the one-millimeter stress method shows conservative evaluation for load-carrying cruciform fillet welded joints.

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