• Title/Summary/Keyword: Surface concentration

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Risk Evaluation of Monopotassium Phosphate (MKP) and Bentonite Application via the Mobility Reduction of Soil TNT and Heavy Metals (제일인산칼륨과 벤토나이트 처리를 통한 토양 내 TNT와 중금속 이동성 및 인체위해도 저감 기술)

  • Jung, Jae-Woong;Yu, Gihyeon;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.28-36
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    • 2015
  • Simultaneous mobility reduction of explosives and heavy metals in an operational range by monopotassium phosphate (MKP) and bentonite spreading technology was investigated. Potassium ion and phosphate ion in MKP act as explosives sorption enhancer and insoluble heavy metal phosphate formation, respectively, while bentonite acts as the explosives adsorbent. Then, the decrease in surface water concentration of the pollutants and resulting risk reduction for local residents of the operational range, by MKP/bentonite application was estimated. Under untreated scenario, the noncancer hazard index (HI) exceeded unity on February, July and August, mainly due to 2,4,6-trinitrotoluene (TNT); however, MKP/bentonite treatment was expected to lower the noncancer hazard index by decreasing the surface water concentration of explosives and heavy metals (especially TNT). For example, on July, estimated surface water concentration and HI of TNT were 0.01 mg/L and 1.1, respectively, meanwhile the sorption coefficient of TNT was 3.9 mg1−nkg−1Ln. However, by MKP/bentonite treatment, the TNT sorption coefficient increased to 113.8 mg1−nkg−1Ln and the surface water concentration and HI decreased to about 0.002 mg/L and 0.2, respectively. Based on the result, it can be concluded that MKP/bentonite spreading is a benign technology that can mitigate the risk posed by the pollutants migration from operational ranges.

Effects of chemical surface treatment on the shear bond Strength of denture reliners and denture base resin (화학적 표면처리에 따른 의치상 레진과 이장재 간의 전단 결합강도)

  • Choi, Esther;Kwon, Eun-Ja
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.5745-5751
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    • 2013
  • The purpose of this study was to evaluate the effect of the surface treatment of MMA and TEGDMA concentration, silane coupling agent on the shear bond strength of denture base resin and denture reliners. Denture base resin surface was treated with MMA and TEGDMA concentration, silane coupling agent. After denture reliners were injected bond strength was measured. The results of MMA and TEGDMA concentration on the shear bond strength of Vertex self curing resin showed that the value of MMA 95% and TEGDMA 5%, MMA 90% and TEGDMA 10%, MMA 80% and TEGDMA 20% groups were higher than that of other group(P<0.05). MMA and TEGDMA concentration on the shear bond strength of Kooliner resin showed that the value of MMA 95% and TEGDMA 5%, MMA 90% and TEGDMA 10% were higher than that of other group(P<0.05). Silane coupling agent on the shear bond strength of Vertex self curing resin and Kooliner showed that the value of MMA 95% and silane coupling agent 5% groups was higher than that of other group(P<0.05). Therefore, we could conclude that appropriate chemical surface treatments are supposed to affect the bond of denture base resin and denture reliners.

Characteristics of the surface ozone concentration on the occurrence of air mass thunderstorm (기단성 뇌우 발생시 지표오존농도의 변화 특성)

  • 전병일
    • Journal of Environmental Science International
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    • v.12 no.4
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    • pp.419-426
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    • 2003
  • This study was performed to research ozone concentration related to airmass thunderstorm using 12 years meteorological data(1990~2001) at Busan. The occurrence frequency of thunderstorm during 12 years was 156 days(annual mean 13days). The airmass thunderstorm frequency was 14 days, most of those occurrence at summertime(59%). In case August 4, 1996, increase of ozone concentration was simultaneous with the decrease of temperature and increase of relative humidity, In case July 23, 1997, ozone concentration of western site at Busan increased, while its of eastern site decreased as airmass thunderstorm occurred(about 1500LST). It is supposed that these ozone increases are the effect of ozone rich air that is brought down by cumulus downdrafts from height levels where the ozone mixing ratio is larger. Thunderstorms can cause downward transport of ozone from the reservoir layer in the upper troposphere into planeta교 boundary layer(PBL). This complex interaction of source and sink processes can result in large variability fer vertical and horizontal ozone distributions. Thus a variety of meteorological precesses can act to enhance vertical mixing between the earth's surface and the atmospheric in the manner described fer thunderstorm.

Stress Concentration Effects on the Nucleation of the Structural Defects in Highly Strained Heteroepitaxial Layers (高變形된 異種 에피층에서 응력 집중이 결정결함 생성에 미치는 영향)

  • Kim, Sam-Dong;Lee, Jin-Koo
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.615-621
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    • 2001
  • We carried out the kinetic model calculations in order to estimate the nucleation rates for two kinds of half-loop dislocations in highly strained hetero-epitaxial growths; $60^{\circ}$dislocations and twinning dislocations. The surface defects and the stress concentration effects were considered in this model, and the remaining elastic strain of the epilayers with increasing film thickness was taken into account by using the modified Matthews' relation. The calculations showed that the stress concentration effect at surface imperfections is very important for describing the defect generation in highly mismatched epitaxial growth. This work also showed that the stress concentration effect determined the type of dislocation nucleating dominantly at early growth stages in accordance with our XTEM (cross-section transmission electron microscopy) defect observation.

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Photoelastic Stress Analysis of the Abutment Surrounding Tissue According to Shape of the Proximal Plate of the RPI Clasp (압축하중시 RPI clasp의 3가지 다른 proximal plate 형태에 따른 지대치 주위조직의 광탄성 응력 분석)

  • Choi, Jung Soo;Kim, Busob
    • Journal of Technologic Dentistry
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    • v.34 no.4
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    • pp.473-482
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    • 2012
  • Purpose: The purpose of this study was to investigate the stress distribution of the surrounding tissues according to 3 proximal plate types of the RPI clasp. Methods: The removeable partial denture which mandibular right and left second premolars and mandibular molars were lost was attached to a three dimensional photo elastic epoxy resin model. Then 120N of vertical load was applied. After 3-dimensional photoelastic stress analysis was used to record the isochromatic fringe patterns. Results: Kratochvil type guiding plane exhibited little uniform stress distribution on load center and alveolar ridge, but higher stress concentration on buccal surface of second premolar. Krol type guiding plane exhibited the stress concentration on the front of load center and relatively higher stress concentration on buccal surface of first premolar. However, this type had no effect on canine. Researcher type guiding plane showed the stress concentration on second premolar and molar, but the little stress distribution on first premolar. Conclusion: In all types, excessive stress concentration was appeared and three types were not significant different.

Effect of PEO Process Conditions on Oxidized Surface Properties of Mg alloy, AZ31 and AZ91. II. Electrolyte (PEO 처리조건에 따른 마그네슘 합금 AZ31과 AZ91의 산화표면피막특성에 대한 연구. II. 전해질의 영향)

  • Ham, Jae-Ho;Jeon, Min-Seok;Kim, Yong-Nam;Shin, Hyun-Gyoo;Kim, Sung Youp;Kim, Bae-Yeon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.4
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    • pp.225-230
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    • 2016
  • Effect of electrolyte composition and concentration on PEO coating layer were investigated. Mg alloy, Surface of AZ31 and AZ91 were oxidized using PEO with different electrolyte system, Na-P and Na-Si. and applied voltage and concentration. We measured thickness, roughness, X-ray crystallographic analysis and breakdown voltage of the oxidized layer. When increasing concentration of electrolyte, the thickness of oxide layer also increased too. And roughness also increased as concentration of electrolyte increasing. Breakdown voltage of coated layer showed same behavior, the voltage goes high as increasing thickness of coating layer, as increasing concentration of electrolyte, and increasing applied voltage of PEO. $Mg_2SiO_4$ phase were observed as well as MgO.

A Study on the Characteristics of the High Concentration Ozone Generator for the Semiconductor Wafer Cleaning with the Ozone Dissolved De-ionized Water (반도체 웨이퍼의 오존 수(水) 세정을 위한 고농도 오존발생장치 특성 연구)

  • 손영수;함상용;문세호
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.12
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    • pp.579-585
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    • 2003
  • Recently the utilization of the ozone dissolved de-ionized water(DI-O3 water) in semiconductor wet cleaning process to replace the conventional RCA methods has been studied. In this paper, we propose the water-electrode type ozone generator which has the ozone gas characteristics of the high concentration and high purity to produce the high concentration DI-O3 water for the silicon wafer surface cleaning process. The ozone generator has the dual dielectric tube structure of silent discharge type and the water is both used to electrode and cooling water. We investigate the performance of the proposed ozone generator which has the design goal of the concentration of 7[wt%] and ozone generation quantity of 6[g/hr] at flow rate of 1[$\ell$/min). The experiment results show that the water electrode type ozone generator has the characteristics of 8.48[wt%] of concentration, 8.08[g/hr] of generation quantity and 76.2[g/kWh] of yield and it's possible to use the proposed ozone generator for the DI-O3 water cleaning process of silicon wafer surface.

The Luminescent Characteristics of C545T Doped OLED Devices (C545T가 첨가된 OLED 소자의 발광특성)

  • Ju, Sung-Hoo;Yang, Jae-Woong
    • Journal of the Korean institute of surface engineering
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    • v.40 no.2
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    • pp.77-81
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    • 2007
  • To investigate the characteristics of green light-emitting OLED device, C545T material with $Alq_3$ was doped in the OLED device of $ITO(1500)/2-TNATA(400{\AA})/NPB(80{\AA})/Alq_3:C545T(160{\AA})/Alq_3(240{\AA})/LiF(3{\AA})/Al(2400{\AA})$ structure, which was used as a activator at the respective concentration of 0.5 vol.%, 1 vol.%, 2 vol.% and 3 vol.%. It was observed from the experiments that the device efficiency firstly increased with the increase of C545T concentration and the maximum efficiency of 10.9 cd/A and 4.28 lm/W was obtained at C545T concentration of 1 vol.%, and then the device efficiency decreased as the C545T activator concentration increased above 2 vol.% contents, while the longest lifetime of over 750 hours was obtained at C545T concentration of 1 vol.%.

Effect on Al Concentration of AlGaAs Ternary Alloy (AlGaAs합금의 Al 도핑농도에 대한 효과)

  • Kang, B.S.
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.4
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    • pp.125-129
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    • 2021
  • We investigated the electronic property and atomic structure for chalcopyrite (CH) AlxGa1-xAs semiconductor by using first-principles FPLMTO method. The CH-AlxGa1-xAs exhibits a p-type semiconductor with a direct band-gap. For low Al concentration unoccupied hole-carriers are induced, but for high Al concentration it is formed a localized bonding or anti-bonding state below Fermi level. The hybridization of Al(3s)-Ga(4s, or 4p) is larger than that of Al(3s)-As(4s, or 4p). And the Al film on As-terminated surface, Al/AsGa(001), is more energetically favorable one than that on Ga-terminated (001) surface. Consequently, the band-gap of CH-AlxGa1-xAs system increases exponentially with increasing Al concentration. The change of lattice parameter is shown two different configurations with increasing Al concentration. The calculated lattice parameters for CH-AlxGa1-xAs system are compared to the experimental ones of zinc-blend GaAs and AlAs.

Optimization of Soy Sauce Production Conditions with Black Garlic Extract by Response Surface Methodology (반응표면 분석법에 의한 흑마늘 추출물이 첨가된 간장의 제조 조건 설정)

  • Shim, Hye-Jin;Kang, Min-Jung;Kim, Gyeong-Min;Lee, Chang-Kwon;Kim, Jeong-Hwan;Shin, Jung-Hye
    • Korean journal of food and cookery science
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    • v.32 no.3
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    • pp.307-315
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    • 2016
  • Purpose: The central composition design was used to optimize the mixture conditions of black garlic extract. Methods: The response surface methodology (RSM) was carried out from concentration of black garlic extract ($X_1$) and the amount of the black garlic extract ($X_2$) as independent variables, and salts ($Y_1$), reducing sugars ($Y_2$), the content of total phenolic compounds ($Y_3$) and ABTS radical scavenging activity ($Y_4$) as dependent variables. We confirmed the conditions that salinity was minimized and reducing sugar, total phenolic compounds and ABTS radical scavenging activity had maximum values through the response surface analysis. Results: All results had saddle points in originally set up conditions hence, ridge analysis was carried out for narrowing the experimental area. The minimum salt concentration was 16.03% at black garlic extract concentration of $14.84^{\circ}brix$ and contents of 9.26%. Reducing sugar content had maximum of value 7.30 g/mL at $24.58^{\circ}brix$ and contents of 8.08%. Total phenolic compounds contents and ABTS radical scavenging activity had maximum values at black garlic extract concentration of 20.33 and $25.02^{\circ}brix$. The results indicate that addition of black garlic extract contributed to increased reducing sugar, phenolic compounds contents and antioxidant activity of the soy sauce, but the salt concentration was not significantly affected. Conclusion: Based on the results of RSM, the optimum ranges of addition conditions for lowering the salt concentration and, increasing the sensory and functional ability of soy sauce were as follows: black garlic extract concentration of $15-25^{\circ}brix$ and content of 7.8-9.3%.