• 제목/요약/키워드: Surface chemistry

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Unipolar pulse를 이용하여 형성된 Al6061 합금 표면의 MAO 코팅의 표면 구조에 대한 연구 (Surface Morphological Properties of Micro-arc Oxidation Coating on Al6061 Alloys using Unipolar Pulse)

  • 김남열;박승호;박기용;최진섭
    • 한국표면공학회지
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    • 제50권5호
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    • pp.421-426
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    • 2017
  • Herein, we investigated surface morphological characteristics of anodic films on Al6061 alloy prepared by unipolar pulsed Micro-arc oxidation (MAO) in a mixed solution of $Na_2SiO_3$ + KOH. The number and size of pores as well as craters on anodic alumina surface were studied as a function of different voltages, duty cycles and applied anodic current densities. The morphological characteristics of all samples were investigated by scanning electron microscopy, conforming that the most uniform surface morphology of MAO films on Al1050 alloy was obtained at high applied current density with low duty cycle.

Characterization of Antibacterial Activity and Synergistic Effect of Cationic Antibacterial Peptide-resin Conjugates

  • Kim, Jeong-Min;Jang, Su-Jung;Yang, Mi-Hwa;Cho, Hyeong-Jin;Lee, Keun-Hyeung
    • Bulletin of the Korean Chemical Society
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    • 제32권11호
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    • pp.3928-3932
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    • 2011
  • We synthesized peptide-resin conjugates (1 and 2) by immobilizing ${\beta}$-sheet antibacterial peptide and ${\alpha}$ helical antibacterial peptide on PEG-PS resin, respectively. Conjugate 1 showed considerable antibacterial activity in various conditions, whereas conjugate 2 did not exhibit antibacterial activity. The growths of various bacteria were inhibited by conjugate 1 even at lower concentrations than MIC. Conjugate 1 killed bacteria at MIC and had a potent synergistic effect with current antibacterial agents such as vancomycin and tetracycline, respectively. Overall results indicate that polymer surface modification using antibacterial ${\beta}$ sheet peptide is a powerful way to prevent microbial contamination on polymer surfaces.

UV-감응형 에폭시 마스크를 사용한 균일한 분포의 터널형 알루미늄 에치 피트 형성 연구 (Formation of Aluminum Etch Tunnel Pits with Uniform Distribution Using UV-curable Epoxy Mask)

  • 박창현;유현석;이준수;김경민;김영민;최진섭;탁용석
    • 공업화학
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    • 제24권5호
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    • pp.562-565
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    • 2013
  • 고순도의 알루미늄 호일은 전기화학적 에칭을 통해 표면적을 증가시킨 후 전해 커패시터의 양극으로 사용된다. 그러나 산화 피막의 결함 및 에치 피트의 불규칙 생성에 의해 성장된 에치 피트의 분포는 불균일하며 이러한 불균일 형태는 알루미늄 넓은 표면적 분포에도 불구하고 여러 형태의 적용을 어렵게 만든다. 본 연구에서는 알루미늄의 선택적 에칭을 위해 포토리소그래피 방법으로 제작된 패턴 마스크를 사용하여 알루미늄 표면에 균일성을 갖는 보호층을 형성시켰다. 균일한 패턴을 갖는 알루미늄을 용액의 온도 및 전류밀도 등의 조건을 변경하여 실험하였고, 알루미늄 표면에 다양한 크기($2{\sim}5{\mu}m$)의 균일성을 갖는 에치 피트의 형성을 확인할 수 있었다.

Polymer surfaces studied by sum-frequency vibrational spectroscopy

  • Kim, D.;J. Sung;H. M. Cheong;C. N. Whang;Y. Ouchi;T. limori;N. Matsuie;K. Seki
    • 한국진공학회지
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    • 제12권S1호
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    • pp.70-73
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    • 2003
  • Sum-frequency vibrational spectroscopy has recently been used to investigate the surface of the various polymers and was able to find the chemical compositions and structures specific to the surface. Here we report our studies on two specific polymer samples to demonstrate its capability. Polyimide thin films were made by spin coating on fused quartz and $CaF_2$ substrates. The sum-frequency signal originating mainly from the air/polymer interface showed markedly different spectra, indicating the structural change of the polymer surface depending on the underlying substrate. Various polyethylene surfaces were also investigated by sum-frequency vibrational spectroscopy. The surface of polyethylene samples in the CH-region showed different sum-frequency spectra, presumably due to the trace amount of additives having much higher concentration at the air/polymer interface. These examples demonstrate the surface and interface of the polymer could have different structure and chemical composition from those of a bulk, which can be studied effectively by surface nonlinear optical spectroscopy.

A Cell-based Method to Monitor the Interaction between Hepatitis B Virus Capsid and Surface Proteins

  • Kim, Yun-Kyoung;Oh, Soo-Jin;Jin, Bong-Suk;Park, Chan-Hoo;Jeon, Hye Sung;Boo, Doo-Wan;Yu, Yeon-Gyu
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.577-581
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    • 2009
  • Interactions between the surface and capsid proteins of the hepatitis B virus (HBV) are critical for the assembly of virus particles. In this study, we developed a cell-based method to visualize the interactions between the capsid and surface proteins of HBV. Capsid-GFP, a capsid protein fused to a green fluorescence protein (GFP), forms nucleocapsid-like structures in the cytoplasm of mammalian cells. It relocates to the plasma membranes in cells expressing PH-PreS, a fusion protein consisting of the PreS region of the HBV surface protein and the PH domain of PLC-$\gamma$. Membrane localization of the capsid-GFP in these cells is prevented by an inhibitory peptide that blocks the interaction between the capsid and surface proteins. This dynamic localization of capsid-GFP is applicable for screening compounds that may potentially inhibit or prevent the assembly process of HBV particles.

Cell Adhesion and Growth on Nanostructured Surface

  • Yoon, Seo Young;Park, Yi-Seul;Choi, Sung-Eun;Jung, Da Hee;Lee, Jin Seok
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.93-93
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    • 2013
  • To make the rationale design of interface between cell and artificial surface, many studies have been controlled influencing cue which can typically be divided into two central categories: chemical cues based on modification surface chemical properties containing attractive/repulsive molecules, and physical cues that may include applied tension/stress, electrical polarization, magnetic field, and topography. Recently, researches have been focused on physical cue, especially topography. The surface topography may influence cellular responses for example, cell adhesion, cell morphology and gene expression. However, there were few systematic studies about these nanotopographical effects on neuronal developments in a feature size-dependent manner. Herein, we report a nanoscale-resolved study of nanotopographical effects on cellular adhesion and growth. In this study, we use substrates with packed glass beads by rubbing method for generating highly periodic nanotopographies with various sizes. We found that acceleration of neuritogenesis appeared only on the beads larger than 200 nm in diameter, and observed that filopodial thickness was comparable with this scale. This study is expected to be essential to elucidate the nanotopographical effect on cellular adhesion and growth.

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높은 에너지의 전자빔을 이용한 F-MgO의 표면 개질 (Surface Modification of F-MgO by High Energy Electron-beam)

  • 김광대;;;서현욱;이병철;양기호;박옥경;김영독
    • 방사선산업학회지
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    • 제3권1호
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    • pp.1-5
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    • 2009
  • The variation of MgO surfaces, in which fluorine was contained (F-MgO), by high energy electron-beam (EB) was studied using X-ray photoelectron spectroscopy (XPS). Fluorine on the MgO surface was eliminated by EB treatment with the consequence that the electronic structures of Mg, O and C were varied. Moreover, as a result of oxidation of carbon species on the surface by high dose EB treatment (90 kGy), the concentration of carbonate and carboxyl species on the surface was increased. In this experiment, it was confirmed that the structure of oxidized metal surface can be adjusted by varying conditions of EB treatment (energy and dose). This result implies that EB can be applied for developing new catalysts.

The Band Edge Liminescence of SUrface Modified CdSe Nanocrystallites and Their Applications

  • Lee, Jin-Kyu;Kuno, Masaru K.;Bawendi, Moungi G.
    • Journal of Photoscience
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    • 제5권4호
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    • pp.175-179
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    • 1998
  • In this paper, a brief overview of nanocrystallites of metal and semi-conductor materials will be presented, and then the novel synthetic method of high quality CdSe nanocrystallites developed by Bawendi group at MIT will be introduced . It will be shown that results of optical properties of surface modified nanocrystallites give the evidence that the luminescence of CdSe nanocrystallites is not originated from surface related trap states, but from intrinsic spin forbidden core states. Some of the interesting applications of CdSe nano-crystallites will also be discussed at the end.

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