Journal of Radiation Industry (방사선산업학회지)

Korean Society of Radiation Industry (한국방사선산업학회)
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Surface Modification of F-MgO by High Energy Electron-beam

높은 에너지의 전자빔을 이용한 F-MgO의 표면 개질

  • Kim, Kwang-Dae (Department of Chemistry, Sungkyunkwan University) ;
  • Tai, Wei Sheng (Department of Chemistry, Sungkyunkwan University) ;
  • Luo, Yuan (Department of Chemistry, Sungkyunkwan University) ;
  • Seo, Hyun Ook (Department of Chemistry, Sungkyunkwan University) ;
  • Lee, Byung Cheol (Quantum Optics Research Division, Korea Atomic Energy Research Institute) ;
  • Yang, Ki Ho (Quantum Optics Research Division, Korea Atomic Energy Research Institute) ;
  • Park, Ok Kyung (Quantum Optics Research Division, Korea Atomic Energy Research Institute) ;
  • Kim, Young Dok (Department of Chemistry, Sungkyunkwan University)
  • 김광대 (성균관대학교 화학과) ;
  • ;
  • ;
  • 서현욱 (성균관대학교 화학과) ;
  • 이병철 (한국원자력연구원 양자광학연구부) ;
  • 양기호 (한국원자력연구원 양자광학연구부) ;
  • 박옥경 (한국원자력연구원 양자광학연구부) ;
  • 김영독 (성균관대학교 화학과)
  • Received : 2009.01.13
  • Accepted : 2009.01.28
  • Published : 2009.03.31

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Abstract

The variation of MgO surfaces, in which fluorine was contained (F-MgO), by high energy electron-beam (EB) was studied using X-ray photoelectron spectroscopy (XPS). Fluorine on the MgO surface was eliminated by EB treatment with the consequence that the electronic structures of Mg, O and C were varied. Moreover, as a result of oxidation of carbon species on the surface by high dose EB treatment (90 kGy), the concentration of carbonate and carboxyl species on the surface was increased. In this experiment, it was confirmed that the structure of oxidized metal surface can be adjusted by varying conditions of EB treatment (energy and dose). This result implies that EB can be applied for developing new catalysts.

Keywords

Acknowledgement

Supported by : 한국과학재단