• Title/Summary/Keyword: Surface Profiling

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Surface Analysis of Modified Polymer Samples by X-Ray Photoelectron Spectroscopy and Rutherford Backscattering Spectroscopy (X-선 광전자 분광법 및 라더포드 후방산란법에 의한 개질된 고분자 시료의 표면분석)

  • Park, Sung-Woo;Kim, Dong-Hwan;Kim, Young-Man;Park, Byung-Sun;Han, Wan-Soo;Suh, Bae-Suk
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.301-313
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    • 1994
  • X-Ray Photoelectron Spectroscopy(XPS) and Rutherford Backscattering Spectroscopy(RBS) are used for the analysis of additives, examination of chemical structure and determination of identity with qualitative and quantitative analysis of surface elements, binding energy level and depth profiling in the surface. We analyzed surface of polyethylene, acrylonitrile butadien rubber, polypropylene, glass, fiber and paper treated with $XeF_2$ or C-F plasma by XPS and RBS. It was found that fluoro element was penetrated to sample surface and the distribution of surface elements are different than untreated samples.

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Biological Effects of Different Thin Layer Hydroxyapatite Coatings on Anodized Titanium

  • Sohn, Sung-Hwa;Jun, Hye-Kyoung;Kim, Chang-Su;Kim, Ki-Nam;Ryu, Yeon-Mi;Lee, Seung-Ho;Kim, Yu-Ri;Seo, Sang-Hui;Kim, Hye-Won;Shin, Sang-Wan;Ryu, Jae-Jun;Kim, Meyoung-Kon
    • Molecular & Cellular Toxicology
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    • v.1 no.4
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    • pp.237-247
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    • 2005
  • Several features of the implant surface, such as roughness, topography, and composition play a relevant role in implant integration with bone. This study was conducted in order to determine the effects of various thin layer hydroxyapatite (HA) coatings on anodized Ti surfaces on the biological responses of a human osteoblast-like cell line (MG63). MG63 cells were cultured on A (100 nm HA coating on anodized surface), B (500-700 nm HA coating on anodized surface), C ($1{\mu}m$ HA coating on anodized surface), and control (non HA coating on anodized surface) Ti. The morphology of these cells was assessed by SEM. The cDNAs prepared from the total RNAs of the MG63 were hybridized into a human cDNA microarray (1,152 elements). The appearances of the surfaces observed by SEM were different on each of the four dental substrate types. MG63 cells cultured on A, C and control exhibited cell-matrix interactions. It was B surface showing cell-cell interaction. In the expression of several genes were up-, and down-regulated on the different surfaces. The attachment and expression of key osteogenic regulatory genes were enhanced by the surface morphology of the dental materials used.

Comparison of Shear-wave Velocity Sections from Inverting SH-wave Traveltimes of First Arrivals and Surface Wave Dispersion Curves (SH파 초동주시 역산과 표면파 분산곡선 역산으로부터 구한 횡파속도 단면 비교)

  • Lee, Chang-Min;Kim, Ki-Young
    • Journal of the Korean Geophysical Society
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    • v.8 no.2
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    • pp.67-74
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    • 2005
  • Two-dimensional S-wave velocity sections from SH-wave refraction tomography and surface wave dispersions were obtained by inverting traveltimes of first arrivals and surface wave dispersions, respectively. For the purpose of comparison, a P-wave velocity tomogram was also obtained from a P-wave refraction profiling. P and Rayleigh waves generated by vertical blows on a plate with a sledgehammer were received by 100- and 4.5-Hz geophones, respectively. SH-waves generated by horizontal blows on both sides of a 50 kg timber were received by 8 Hz horizontal geophones. The shear-wave signals were enhanced subtracting data of left-side blows from ones of the right-side blows. Shear-wave velocities from tomography inversion of first-arrival times were compared with ones from inverting dispersion curves of Rayleigh waves. Although the two velocity sections look similar to each other in general, the one from the surface waves tends to have lower velocities. First arrival picking of SH waves is troublesome since P and PS-converted waves arrive earlier than SH waves. Application of the surface wave method, on the other hand, is limited where lateral variation of subsurface tructures is not mild.

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Surface Analysis of Fluorine-Plasma Etched Y-Si-Al-O-N Oxynitride Glasses

  • Lee, Jung-Ki;Hwang, Seong-Jin;Lee, Sung-Min;Kim, Hyung-Sun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.38.1-38.1
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    • 2009
  • Plasma etching is an essential process for electronic device industries and the particulate contamination during plasma etching has been interested as a big issue for the yield of productivity. The oxynitride glasses have a merit to prevent particulate contamination due to their amorphous structure and plasma etching resistance. The YSiAlON oxynitride glasses with increasing nitrogen content were manufactured. Each oxynitride glasses were fluorine-plasma etched and their plasma etching rate and surface roughness were compared with reference materials such as sapphire, alumina and quartz. The reinforcement mechanism of plasma etching resistance of the YSiAlON glasses studied by depth profiling at plasma etched surface using electron spectroscopy for chemical analysis. The plasma etching rate decreased with nitrogen content and there was no selective etching at the plasma etched surface of the oxynitride glasses. The concentration of silicon was very low due to the generation of SiF4 very volatile byproduct and the concentration of aluminum and yttrium was relatively constant. The elimination of silicon atoms during plasma etching was reduced with increasing nitrogen content because the content of the nitrogen was constant. And besides, the concentration of oxygen was very low on the plasma etched surface. From the study, the plasma etching resistance of the glasses may be improved by the generation of nitrogen related structural groups and those are proved by chemical composition analysis at plasma etched surface of the YSiAlON oxynitride glasses.

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Application of multimodal surfaces using amorphous silicon (a-Si) thin film for secondary ion mass spectrometry (SIMS) and laser desorption/ionization mass spectrometry (LDI-MS)

  • Kim, Shin Hye;Lee, Tae Geol;Yoon, Sohee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.384.1-384.1
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    • 2016
  • We reported that amorphous silicon (a-Si) thin film provide sample plate exhibiting a multimodality to measure biomolecules by secondary ion mass spectrometry (SIMS) and laser desorption/ionization mass spectrometry (LDI-MS). Kim et al.1 reported that a-Si thin film were suitable to detect small molecules such as drugs and peptides by SIMS and LDI-MS. Recently, bacterial identification has been required in many fields such as food analysis, veterinary science, ecology, agriculture, and so on.2 Mass spectrometry is emerging for identifying and profiling microbiology samples from its advantageous characters of label-free and shot-time analysis. Five species of bacteria - S. aureus, G. glutamicum, B. kurstaki, B. sphaericus, and B. licheniformis - were sampled for MS analysis without lipid extraction in sample preparation steps. The samples were loaded onto the a-Si thin film with a thickness of 100 nm which did not only considered laser-beam penetration but also surface homogeneity. Mass spectra were recorded in both positive and negative ionization modes for more analytical information. High reproducibility and sensitivity of mass spectra were demonstrated in a mass range up to mass-to-charge ratio(m/z) 1200 by applying the a-Si thin film in mentioned above MS. Principle component analysis (PCA) - a popular statistical analysis widely used in data processing was employed to differentiate between five bacterial species. The PCA results verified that each bacterial species were readily distinguished and differentiated effectively from our MS approach. It shows a new opportunity to rapid bacterial profiling and identification in clinical microbiology. More details will be discussed in the presentation.

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The design and characteristic of the TiNx optical film for ARAS coating (ARAS용 TiNx 광학박막의 설계제작과 특성연구)

  • Park, Moon-Chan;Jung, Boo-Young;Hwangbo, Chang-Kwon
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.31-35
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    • 2001
  • The anti-reflective anti-static(ARAS) optical film Was designed using conducting layer $TiN_x$ by Essential Macleod program. From this results, [air ${TiN_x{\mid}SiO_2{\mid}$ glass] two layer shows wide-band AR coating in the wavelength range of 450~700 nm. The $TiN_x$ thin films were prepared on the glass substrate by RF(radio-freqency) magnetron sputtering apparatus from a Ti target in agaseous mixture of argon and nitrogen with the thickness of 7~10 nm. For the films obtained, the chemical binding energy of the films was investigated by x-ray photoelectron spectroscopy(XPS) in order to analyze the chemical nature and composition of the films. In addition, we investigated the relationship between the surface resistance and the chemical nature the sheet resistance and XPS depth profiling the chemical binding of the films.

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A Study on the Development and the Verification of a Sonar Sensor System of a Socket Roughness Measurement Device for A Lagre-diamter Drilled Shaft (대구경 현장타설말뚝의 소켓 벽면 거칠기 측정장치(SRPS)에 사용되는 소나센서부의 개발 및 검증에 관한 연구)

  • Jeon, Byeong-Han;Choi, Yong-Kyu
    • Journal of the Korean Geotechnical Society
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    • v.28 no.12
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    • pp.87-98
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    • 2012
  • A sonar sensor system of a new socket roughness profiling system (SRPS) which can measure the socket roughness of the large-diameter drilled shafts under the in-situ condition was developed and verified. In model tests, the salinity, temperature, and high-turbidity have been changed for simulating the in-situ borehole water conditions. From the test results, it was found that the sonar sensor can measure the distance within an accuracy of 1mm. Because of the wave form characteristics of sonar sensor, the relative error exists in case of the inclined and curved surface, however, the shape of specimen was confirmed relatively exactly using the developed sonar sensor. Moreover, the salinity, temperature, and high-turbidity did not affect the measured data of socket roughness.

A Mechanism to profile Pavement Blocks and detect Cracks using 2D Line Laser on Vehicles (이동체에서 2D 선레이저를 이용한 보도블럭 프로파일링 및 균열 검출 기법)

  • Choi, Seungho;Kim, Seoyeon;Jung, Young-Hoon;Kim, Taesik;Min, Hong;Jung, Jinman
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.21 no.5
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    • pp.135-140
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    • 2021
  • In this paper, we propose an on-line mechanism that simultaneously detects cracks and profiling pavement blocks to detect the displacement of ground surface adjacent to the excavation in the urban area. The proposed method utilizes a 2D laser to profile the information about pavement blocks including the depth and distance among them. In particular, it is designed to enable the detection of cracks and portholes at runtime. For the experiment, real data was collected through Gocator, and trainng was carried out using Faster R-CNN. The performance evaluation shows that our detection precision and recall are more than 90% and the pavement blocks are profiled at the same time. Our proposed mechanism can be used for monitoring management to quantitatively detect the level of excavation risk before a large-scale ground collapse occurs.

The Validation of Landsat TM Band Ratio Algorithm using In-water Optical Measurement (수중 광학측정을 이용한 Landsat TM 밴드비율 알고리듬 검증)

  • Jeong, Jong-Chul
    • Journal of the Korean Association of Geographic Information Studies
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    • v.4 no.1
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    • pp.18-26
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    • 2001
  • Landsat TM band ratio algorithms were made by in-water optical measurement data of each sampling points for water quality monitoring of coastal area using Landsat TM satellite data. The algorithm was derived from in-water optical reflectance data which was measuring by the PRR(profiling reflectance radiometer). And, in-water optical reflectance data were applied to Landsat TM bands. Relationship between in-water optical reflectance and pigments proposed by the ratio of TM band 1 and band 2 showed to as follows; $Y=3.8352{\times}(R(band\;1)/R(band\;2))^{-2.1978}$ ($R^2$=0.7069) and, relationship of the ratio of TM band 1 and band 3 as follows; $Y=23.288{\times}(R(band\;1)/R(band\;3))^{-1.5243}$ ($R^2$=0.8062). Calculated the upwelling radiance of water surface and radiance of TM showed the ratio of atmospheric effect. In the coastal area Rayleigh and Mie scattering of atmosphere is to make over 80% of normalized radiance of Landsat TM. In order to apply in-water algorithm obtained by PRR, we had to calculate the atmospheric effects at sampling site. And, the quantitative analysis of in-water components using Landsat TM data need the calibration of in-water algorithm and effective method of atmospheric correction.

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Analysis of the Na Gettering in PSG/SiO2/Al-1%Si Multilevel Thin Films using XPS and SIMS (XPS와 SIMS를 이용한 PSG/SiO2/Al-1%Si 적층 박막내의 Na 게터링 분석)

  • Kim, Jin Young
    • Journal of the Korean institute of surface engineering
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    • v.49 no.5
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    • pp.467-471
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    • 2016
  • In order to investigate the Na gettering, PSG/$SiO_2$/Al-1%Si multilevel thin films were fabricated. DC magnetron sputter techniques and APCVD (atmosphere pressure chemical vapor deposition) were utilized for the deposition of Al-1%Si thin films and PSG/$SiO_2$ passivations, respectively. Heat treatment was carried out at $300^{\circ}C$ for 5 h in air. SIMS (secondary ion mass spectrometry) depth profiling and XPS (X-ray Photoelectron Spectroscopy) analysis were used to determine the distribution and binding energies of Na, Al, Si, O, P and other elements throughout the PSG/$SiO_2$/Al-1%Si multilevel thin films. Na peaks were mainly observed at the the PSG/$SiO_2$ interface and at the $SiO_2$/Al-1%Si interfaces. Na impurity gettering in PSG/$SiO_2$/Al-1%Si multilevel thin films is considered to be caused by a segregation type of gettering. The chemical state of Si and O elements in PSG passivation appears to be $SiO_2$.