• Journal of Electrochemical Science and Technology
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• 제12권2호
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• pp.230-236
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• 2021

Ionic conduction mechanism of Mg-Al layered double hydroxides (LDHs) intercalated with CO₃^2- (Mg-Al CO₃^2- LDH) was studied. The electromotive force for the water vapor concentration cell using Mg-Al CO₃^2- LDH as electrolyte showed water vapor partial pressure dependence and obeyed the Nernst equation, indicating that the hydroxide ion transport number of Mg-Al CO₃^2- LDH is almost unity. The ionic conductivity of Mg(OH)₂, MgCO₃ and Al₂(CO₃)₃ was also examined. Only Al₂(CO₃)₃ showed high hydroxide ion conductivity of the order of 10^-4 S cm^-1 under 80% relative humidity, suggesting that Al₂(CO₃)₃ is an ion conducting material and related to the generation of carrier by interaction with water. To discuss the ionic conduction mechanism, Mg-Al CO₃^2- LDH having deuterium water as interlayer water (Mg-Al CO₃^2- LDH(D₂O)) was prepared. After the adsorbed water molecules on the surface of Mg-Al CO₃^2- LDH(D₂O) were removed by drying, DC polarization test for dried Mg-Al CO₃^2- LDH(D₂O) was examined. The absorbance attributed to O-D-stretching band for Mg-Al CO₃^2- LDH(D₂O) powder at around the positively charged electrode is larger than that before polarization, indicating that the interlayer in Mg-Al CO₃^2- LDH is a hydroxide ion conduction channel.

• 대한조선학회논문집
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• 제55권6호
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• pp.490-496
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• 2018

The consistency of the initially designed waves in the domain is essential for accurate calculation of the added resistance in waves through CFD. In particular, unwanted reflected waves at domain boundaries can cause incorrect numerical solutions due to the superposition with initially designed waves. Euler Overlay Method(EOM) is one of the methods for reducing wave reflections by adding an additional source term to momentum and phase conservation equations, respectively. In this study, we apply the Euler Overlay Method(EOM) to the open-source CFD library, OpenFOAM(R), to simulate the accurate free-surface waves in the domain and the parametric study is performed for efficient implementation of Euler Overlay Method(EOM). Considering that the damping efficiency depends on the selection of the overlay parameter in the added source terms, the size of overlay zone and the wave steepness, the influences of these factors are tested through the wave elevation measured at constant time intervals in the 2D numerical wave tank. Through this process, guidelines for selection of optimal overlay parameter and overlay zone size that can be applied according to the scaling law are finally presented.

• 한국재료학회지
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• 제28권12호
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• pp.725-731
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• 2018

We investigate the reduction of $SnO_2$ and the generation of syngas($H_2$, CO) using methane($CH_4$) and hydrogen($H_2$) or a mixed gas of methane and hydrogen as a reducing gas. When methane is used as a reducing gas, carbon is formed by the decomposition of methane on the reduced Sn surface, and the amount of generated carbon increases as the amount and time of the supply of methane increases. However, when hydrogen is used as a reducing gas, carbon is not generated. High purity Sn of 99.8 % and a high recovery rate of Sn of 93 % are obtained under all conditions. The effects of reducing gas species and the gas mixing ratio on the purity and recovery of Sn are not significantly different, but hydrogen is somewhat more effective in increasing the purity and recovery rate of Sn than methane. When 1 mole of methane and 1 mole of hydrogen are mixed, a product gas with an $H_2/CO$ value of 2, which is known to be most useful as syngas, is obtained.

• 한국지리정보학회지
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• 제21권4호
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• pp.218-237
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• 2018

전 세계적으로 홍수와 가뭄 발생 빈도는 가파르게 증가하고 있고, 태풍 및 가뭄 발생 빈도도 꾸준히 증가하고 있어 광범위한 관측과 정확한 예측, 즉각적 대처 능력 확보를 위한 수자원 관리 기술 확보가 필요하였다. 이를 위해, 본 연구에서는 독립적이고 주도적인 관측인프라 및 분석 기반 확보를 통해 수재해 관리 기반을 획기적으로 혁신하고, 기후변화에 대비한 물안보 및 재해로부터 안전성을 확보하기 위하여 저궤도 수재해 감시 중형급(500kg이하) 위성 개발 방안을 제시하고자 하였다. 수자원 수재해 위성은 주야 및 악천후에도 지표면의 변화탐지 및 수문인자 관측이 가능할 뿐만 아니라, 독자적인 기술 확보기 가능한 C밴드 영상레이더 탑재체 및 시스템을 선정하여 세부적인 개발 방안을 제시하였다. 이를 통해 국가가 추진하는 차세대중형위성 2단계 사업 계획에 반영하여 광역 물 관련 재해 감시 체계 구축을 위한 기반 확보가 가능하게 되었다.

• 수산해양기술연구
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• 제55권2호
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• pp.129-137
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• 2019

This study was conducted to investigate the effects of underwater noise caused by pile driving during marine construction on fish. In this study, the three gray rockfish were released about 1 km away from the construction site of wind power generation on July 18, 2018 and traced using two acoustic telemetry techniques. The behavior of the fish was analyzed by calculating the moving distance, swimming speed and direction of the gray rockfish. In the results of the acoustic tracking using the ship, the rockfish moved about 2.11 km for about two hours at a speed of $0.28{\pm}0.14m/s$ (0.94 TL/s). The bottom depth of the trajectory of the rockfish was $1.0{\pm}0.6m$ on average. There was a significant directionality in swimming direction of the gray rockfish, and there was no significant correlation between the swimming direction and tidal current direction. Moving distance during 5 minutes (5MD) during pile driving and finishing operations between rock surface and bedrock were 0.94-0.96 times (76.0-77.0 m) and 1.81-2.73 times (146.0-219.5 m), respectively, compared with no pile driving. This study is expected to be used as a basic data of fish behavior research on underwater noise.

• 실내환경 및 냄새 학회지
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• 제16권2호
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• pp.187-198
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• 2017

It is very important to treat infected livestock carcasses safely and quickly. In this study, the degradation characteristics and odor generation characteristics of carcasses were investigated during the treatment of swine carcasses using the anaerobic burial composting method. While the carcasses were decomposed, the temperature remained high, at $40{\sim}55^{\circ}C$ on average, and most of the carcasses were decomposed rapidly. The major odor-contributing substances in the buried composting method are sulfuric odor substances such as $H_2S$, $CH_3SH$, dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), and the odor contribution of these substances is 93~99%. Among them, $CH_3SH$, which accounts for about 56~89% of odor contribution, was the most representative indicator substance. Despite the anaerobic digestion process, the methane concentration in the digestion process was as low as 0.5~0.8% at the burial point of the carcass. The odor and methane produced during the decomposition of the carcasses decreased considerably during the discharge to the surface layer through the buried layer consisting of compost. These results suggest that anaerobic high temperature burial composting is one of the most useful methods to treat carcasses of infected livestock.

• Structural Engineering and Mechanics
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• 제70권6호
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• pp.703-710
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• 2019

While fiber-reinforced plastic (FRP) materials have been largely used in the retrofitting of concrete buildings, its application has been limited because of some problems such as de-bonding of FRP layers from the concrete surface. This paper is the part of a wide experimental and analytical investigation about flexural retrofitting of reinforced concrete (RC) columns using FRP and mechanical fasteners (MF). A new generation of MF is proposed, which is applicable for retrofitting of RC columns. Furthermore, generally, to evaluate a retrofitted structure the nonlinear static and dynamic analyses are the most accurate methods to estimate the performance of a structure. In the nonlinear analysis of a structure, accurate modeling of structural elements is necessary for estimation the reasonable results. So for nonlinear analysis of a structure, modeling parameters for beams, columns, and beam-column joints are essential. According to the concentrated hinge method, which is one of the most popular nonlinear modeling methods, structural members shall be modeled using concentrated or distributed plastic hinge models using modeling parameters. The nonlinear models of members should be capable of representing the inelastic response of the component. On the other hand, in performance based design to make a decision about a structure or design a new one, numerical acceptance should be determined. Modeling parameters and numerical acceptance criteria are different for buildings of different types and for different performance levels. In this paper, a new method was proposed for FRP retrofitted columns to avoid FRP debonding. For this purpose, mechanical fasteners were used to achieve the composite behavior of FRP and concrete columns. The experimental results showed that the use of the new method proposed in this paper increased the flexural strength and lateral load capacity of the columns significantly, and a good composition of FRP and RC column was achieved. Moreover, the modeling parameters and acceptance criteria were presented, which were derived from the experimental study in order to use in nonlinear analysis and performance-based design approach.

• 대한금속재료학회지
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• 제56권12호
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• pp.910-914
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• 2018

Since catalyst technology is one of the promising technologies to improve the working performance of next generation energy and electronic devices, many efforts have been made to develop various catalysts with high efficiency at a low cost. However, there are remaining challenges to be resolved in order to use the suggested catalytic materials, such as platinum (Pt), gold (Au), and palladium (Pd), due to their poor cost-effectiveness for device applications. In this study, to overcome these challenges, we suggest a useful method to increase the surface area of a noble metal catalyst material, resulting in a reduction of the total amount of catalyst usage. By employing block copolymer (BCP) self-assembly and nano-transfer printing (n-TP) processes, we successfully fabricated sub-20 nm Pt line and cross-bar patterns. Furthermore, we obtained a highly ordered Pt cross-bar pattern on a Ni thin film and a Pt-embedded Ni thin film, which can be used as hetero hybrid alloy catalyst structure. For a detailed analysis of the hybrid catalytic material, we used scanning electron microscope (SEM), transmission electron microscope (TEM) and energy-dispersive X-ray spectroscopy (EDS), which revealed a well-defined nanoporous Pt nanostructure on the Ni thin film. Based on these results, we expect that the successful hybridization of various catalytic nanostructures can be extended to other material systems and devices in the near future.

• Korean Chemical Engineering Research
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• 제59권1호
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• pp.35-41
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• 2021

차세대 리튬이차전지용 음극활물질로 각광을 받고 있는 실리콘은 높은 이론용량을 가지고 있어 상용화를 하기 위해 많은 연구가 진행되었다. 하지만 실리콘은 충방전시 부피팽창이 심하고, 전기전도도가 낮은 단점을 가지고 있다. 이러한 문제를 해결하기 위해서 실리콘 표면에 SiO2를 형성시키고, 탄소를 코팅함으로써 실리콘의 부반응을 억제시키고 전기전도도를 향상시켰다. 추가적으로 CNF와 CNT를 복합적으로 첨가하여 부피팽창에 대한 완충효과를 부여하고 전기전도도를 향상시켰다. 제조된 샘플은 XRD, SEM, EDS로 물리적 특성 분석을 실시하였으며, 전기화학적 특성은 전기전도도, EIS, CV 그리고 사이클 테스트를 통해 분석하였다. (Si/SiO2/C)+CNT&CNF 복합체의 경우 다른 샘플들에 비하여 높은 전기전도도 및 낮은 전하전달저항을 보여주었으며, 사이클테스트 결과 첫 번째 사이클에서 1528 mAh/g 그리고 50번째 사이클에서 1055 mAh/g의 용량을 가졌으며 83%의 용량 유지율을 보여주었다.

• 상하수도학회지
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• 제35권3호
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• pp.197-204
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• 2021

In MBR, extracellular polymeric substance (EPS) is known as an important factor of fouling; soluble EPS (sEPS) affects internal contamination of membrane, and bound EPS (bEPS) affects the formation of the cake layer. The production of EPS changes according to the composition of influent, which affects fouling characteristics. Therefore, in this study, the effects of the F/M ratio on the sEPS concentration, bEPS content, and fouling were evaluated. The effects of F/M ratio on the amount and composition of EPS were confirmed by setting conditions that were very low or higher than the general F/M ratio of MBR, and the fouling occurrence characteristics were evaluated by filtration resistance distribution. As a result, it was found that the sEPS increased significantly with the increase of the F/M ratio. When the substrate was depleted, bEPS content decreased because bEPS was hydrolyzed into BAP and seemed to be used as a substrate. In contrast, when the substrate is sufficient, UAP (utilization-associated products) was rapidly generated in proportion with the consumption of the substrate. UAP has a relatively higher Protein/Carbohydrate ratio (P/C ratio) than BAP, and this means, it has a higher adhesive force to the membrane surface. As a result, UAP seems like causing fouling rather than BAP (biomass-associated products). Therefore, R_f (Resistance of internal contamination) increased rapidly with the increase of UAP, and R_c (Resistance of cake layer) increased with the accumulation of bEPS in proportion, and as a result, the fouling interval was shortened. According to this study, a high F/M ratio leads to an increment in UAP generation and accumulation of bEPS, and by these UAP and bEPS, membrane fouling is promoted.