• Title/Summary/Keyword: Surface Fibers

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Effects of Electrochemical Oxidation of Carbon Fibers on Mechanical Interfacial Properties of Carbon Fibers-reinforced Polarized-Polypropylene Matrix Composites (전기화학적 산화처리가 탄소섬유/극성화된 폴리프로필렌 복합재의 기계적 계면 특성에 미치는 영향)

  • Kim, Hyun-Il;Choi, Woong-Ki;Oh, Sang-Yub;An, Kay-Hyeok;Kim, Byung-Joo
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.476-482
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    • 2013
  • In this work, the effects of electrochemical oxidation of carbon fiber surfaces on mechanical interfacial properties of carbon fibers-reinforced polarized-polypropylene matrix composites were studied with various current densities during the treatments. Surface properties of the fibers before and after treatments were observed by SEM, AFM, XPS, and contact angle measurements. Mechanical interfacial properties of the composites were measured in terms of critical stress intensity factor ($K_{IC}$). From the results it was found that $O_{1s}$ peaks of the fiber surfaces were strengthened after electrochemical oxidation which led to the enhancement of surface free energy of the fiber, resulting in good mechanical performance of the composites. It can be concluded that electrochemical oxidation of the carbon fiber surfaces can control the interfacial adhesion between the carbon fibers and polarized-polypropylene in this composites system.

Fiber Surface Engineering to Improve Papermaking Raw Material Quality

  • Wang Eugene I-Chen;Perng Yuan Shing
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.271-278
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    • 2006
  • We used polymers of alternating cationic and anionic nature to build up shells on fiber surfaces, strengthen the worn-out fibers and improve paper properties made from such fibers. OCC and ONP pulps were either dipped or salted out in the cationic polyallylamine, polyacrylamide and starch solutions. After centrifugal drying, these were followed by treatments in anionic polyacrylic acid, poly-acrylamide, and starch solutions, respectively. The shell-enhanced fibers were formed into handsheets and their physical properties evaluated. The results show that building multiple shells on worn-out fiber surfaces can strengthen the fibers and paper. The simpler and more practical impregnation-centrifuging treatment provided the desired effects, whereas salting out the polymers produced somewhat superior fibers. The latter process, were impractical, however. The first pair of polymeric shells imparted marked strength improvement, whereas later layers had diminishing efficacies. Overall, the methods can improve fiber quality, attaining paper strength requirements without resorting to expensive measures. Alternate cationic polymer and filler powders were also deposited on fiber surface based on the micriparticle system in an anticipation of stiffness gains. Platy minerals, such as montmorillonite, bentonite, sericite, clay and talc were added following cationic PAM. After dewatering of polymer-pigment shelled fiber of one to 3 pairs of layers, handsheets either calendered or uncalendered were evaluated. The results indicate that regardless of calendaring, stiffness of the handsheets did not improve appreciably while certain other strength properties showed gains. We also attempted the novel starch gel filler addition method wherein tapioca starch and filers (PCC, sericite or clay) were mixed at high solids content of 50% and cooked until gelatinized. The filled handsheets were dried under various conditions and then tested for their properties. Improvements in strengths of modified filled paper were observed.

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Various Metal Oxide Additions Based on TiO2 and Adsorption Characteristics of Hollow Fiber Adsorbent on Arsenic (TiO2 기반의 다양한 금속산화물 첨가와 중공사형 흡착제의 비소 흡착 특성)

  • Eom, Hanki;Jang, Younghee;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.345-351
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    • 2019
  • In this study, the hollow fibers from $TiO_2$ and various metal oxides additives were fabricated and characterized in order to remove the arsenic substance from a contaminated water. Experimental results showed the best arsenic adsorption performance from pristine $TiO_2$ hollow fibers. When metal oxides were added, the metal oxides reduced the acid sites on the surface of $TiO_2$ and the arsenic adsorption performance decreased. However, the long term arsenic adsorption performance was enhanced and showed better performance than that of using pristine $TiO_2$ hollow fibers when $Al_2O_3$ was added during the hollow fiber fabrication. In addition, the arsenic adsorption performance showed a high dependency on the specific surface area of hollow fibers. It was confirmed that the abundancy of Lewis and Bronsted acid sites provided was favorable for the arsenic adsorption. It was also demonstrated that commercially available $TiO_2$ powders can be an attractive candidate material for manufacturing hollow fibers for a small scale water treatment plant.

Growth of superconducting $MgB_2$ fibers for wire applications

  • Kim J. H.;Yoon H. R.;Jo W.
    • Progress in Superconductivity and Cryogenics
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    • v.7 no.4
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    • pp.1-3
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    • 2005
  • Superconducting $MgB_2$ fibers are in-situ grown by a diffusion method. The fibers are prepared by exposing B filaments to Mg vapor inside a folded Ta foil over a wide range of temperature and growth time. The materials are sealed inside a quartz tube by gas welding. The as - grown fibers are characterized by scanning electron microscopy and energy dispersive x - ray analysis. The fibers have a diameter of about $110{\mu}m$. Surface morphology of the fibers looks dependent on growth temperature and mixing ratio of Mg and B. Radial distribution of Mg ions into B is observed and analyzed over the cross - sectional area. Transport properties of the $MgB_2$ fibers are examined by a physical property measurement system. The $MgB_2$ fibers grown at $900^{\circ}C$ for 2 hours show a superconducting transition at 39.8K with ${\Delta}T_c<$ 2.0 K. Resistance at room temperature $MgB_2$ is 3.745 $\Omega$ and residual resistivity ratio (RRR) is estimated as 4.723.

Preparation and thermal properties of polyethylene-based carbonized fibers

  • Kim, Kwan-Woo;Lee, Hye-Min;Kim, Byoung Suhk;Hwang, Seon-Hwan;Kwac, Lee-Ku;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • v.16 no.1
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    • pp.62-66
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    • 2015
  • In this study, carbonized fibers were prepared by using acidically cross-linked LDPE fibers. The surface morphologies of the carbonized fibers were observed by SEM. The effects of cross-linking process temperatures were studied using thermal analyses such as DSC and TGA. The melting and heating enthalpy of the fibers decreased as the cross-linking temperature increased. The cross-linked fibers had a carbonization yield of over 50%. From SEM results the highest yield of carbonized LDPE-based fibers was obtained by cross-linking at a sulfate temperature ($170^{\circ}C$). As a result, carbonation yield of the carbonized fibers was found to depend on the functions of the cross-linking ratio of the LDPE precursors.

The Fabrication of Zirconia Fibers from Sol-Gel Process (졸-겔법에 의한 지르코니아 섬유의 제조)

  • 황규홍;윤태경;고기준;김의훈
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.544-550
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    • 1992
  • Zirconia gel fibers could be made by drawing from polyester sol containing zirconyl oxychloride during the reaction between ethylen glycol and citric acid. In this case, the critical mole ratio of zirconyl oxychloride to citric acid was about 4 and by adding CaCl2 and calcining the gel fiber in the air, cubic stabilized zirconia fibers having much micropores at surface could be obtained.

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Antibacterial Activity of Activated Carbon Fibers Containing Silver Metal

  • Park, Soo-Jin;Kim, Byung-Joo;Ryu, Seung-Kon
    • Carbon letters
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    • v.4 no.3
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    • pp.140-145
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    • 2003
  • Antibacterial behaviors of PAN-based activated carbon fibers (ACFs) containing silver metal were investigated. The effects of surface and pore structures of the ACFs were studied by $N_2$/77 K adsorption and D-R plot as a function of silver loading content. The antibacterial activities were investigated by a dilution test against Staphylococcus aureus (S. aureus; gram positive) and Klebsiella pnemoniae (K. pnumoniae; gram negative). As experimental results, the ACFs showed some decreases in specific surface areas, micropore volumes, and total pore volume with an increase of silver content. However, the antibacterial activities of the ACFs were strongly increased against S. aureus as well as K. pnumoniae, which could be attributed to the presence of antibacterial metal in the ACFs system.

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Fabrication and Characterization of Polystyrene/Gold Nanoparticle Composite Nanofibers

  • Kim, Jung-Kil;Ahn, Hee-Joon
    • Macromolecular Research
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    • v.16 no.2
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    • pp.163-168
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    • 2008
  • Polystyrene/gold nanoparticle (PS/AuNP) composite fibers were fabricated using an electrospinning technique. Transmission electron microscopy (TEM) showed that the diameters of the naphthalenethiol-capped gold nanoparticles (prior to incorporation into the PS fibers) ranged from 2 to 5 nm. UV-vis spectroscopy revealed the surface plasmon peaks of the gold nanoparticles centered at approximately 512 nm, indicating that nano-sized Au particles are well-dispersed in solution. This was consistent with the TEM observations. The electrospun nanofibers of PS/AuNP composites were approximately 60-3,000 nm in diameter. The surface morphology of the PS/AuNP composite and the dispersability of the Au nanoparticles inside of PS after electrospinning process were investigated by SEM and TEM. The thermal behavior of the pure PS and PS/AuNP nanocomposites and fibers were examined by DSC.

ON A FIBER SPACE WITH CONNECTED FIBERS

  • Shin, Dong-Kwan
    • Bulletin of the Korean Mathematical Society
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    • v.35 no.4
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    • pp.625-627
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    • 1998
  • Let f: S$\rightarrow$ C be a fiber space with connected fibers. We may have an information about a surface S from the fiber space structure. The result we have is ${\chi}({\mathcal O}_C){\chi}({\mathcal O}_F){\leq}{\chi}({\mathcal O}_S)$.

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THE SCANNING ELECTRON MICROSCOPIC STUDY OF HEALTHY AND PATHOLOGIC STRUCTURE OF ROOT SURFACE (정상 및 염증상태의 치근표면구조의 주사전자현미경적 연구)

  • Kim, Mi-Yeung;Kim, Chong-Kwan
    • The Journal of the Korean dental association
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    • v.19 no.7 s.146
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    • pp.625-634
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    • 1981
  • A Scanning Electron Microscopic Study of the root surface changes was carried out in advanced periodontal disease. The results obtained were summerized as follow; 1. The root surface of cementoenamel junction of healthy root showed smooth surface, while the root surface of diseased state showed covering of deposits which regareded as a course of calcification. 2. At the mid-portion of the root, the regular cemental projection were observed on the healthy root surface and on the root surface of diseased state, cemental projection showed relatively irregular pattern. 3. On the root surface which consist of wall of periodontal pocket, there were various deposits which could be considered as subgingival calculus, bacterial plaque and epithelial attachment remnant. 4. The bottom area of the pathologic pocket, tearing altered collagen fibers were seen on the root surface. 5. At the apical portion of root surface, calcified fibers ran parallel to the root surface in healthy tooth and the fiber bundles of periodontal ligament were seen in the diseased state.

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