Browse > Article

Fabrication and Characterization of Polystyrene/Gold Nanoparticle Composite Nanofibers  

Kim, Jung-Kil (Department of Fiber and Polymer Engineering, Hanyang University)
Ahn, Hee-Joon (Department of Fiber and Polymer Engineering, Hanyang University)
Publication Information
Macromolecular Research / v.16, no.2, 2008 , pp. 163-168 More about this Journal
Abstract
Polystyrene/gold nanoparticle (PS/AuNP) composite fibers were fabricated using an electrospinning technique. Transmission electron microscopy (TEM) showed that the diameters of the naphthalenethiol-capped gold nanoparticles (prior to incorporation into the PS fibers) ranged from 2 to 5 nm. UV-vis spectroscopy revealed the surface plasmon peaks of the gold nanoparticles centered at approximately 512 nm, indicating that nano-sized Au particles are well-dispersed in solution. This was consistent with the TEM observations. The electrospun nanofibers of PS/AuNP composites were approximately 60-3,000 nm in diameter. The surface morphology of the PS/AuNP composite and the dispersability of the Au nanoparticles inside of PS after electrospinning process were investigated by SEM and TEM. The thermal behavior of the pure PS and PS/AuNP nanocomposites and fibers were examined by DSC.
Keywords
electrospinning; gold nanoparticle; nanofibers; polystyrene/gold nanocomposite;
Citations & Related Records
Times Cited By KSCI : 7  (Citation Analysis)
Times Cited By Web Of Science : 20  (Related Records In Web of Science)
Times Cited By SCOPUS : 16
연도 인용수 순위
1 O. A. Aktsipetrov, Coll. Surf. A, 202, 165 (2002)
2 J. L. MenZndez, B. Besc-s, G. Armelles, R. Serna, J. Gonzalo, R. Doole, A. K. Petford-Long, and M. I. Alonso, Phys. Rev. B, 65, 205413 (2002)
3 V. Pardo-Yissar, R. Gabai, A. N. Shipway, T. Bourenko, and I. Willner, Adv. Mater., 13, 1320, (2001)
4 A. K. Boal and V. M. Rotello, J. Am. Chem. Soc., 124, 5019 (2002)
5 G. Schmid, B. Morun, and J. -O. Malm, Angew. Chem. Int. Ed. Engl., 28, 778 (1989)
6 S. V. Manorama, K. M. Reddy, C. V. G. Reddy, S. Narayanan, P. R. Paja, and P. R. Chatterji, J. Phys. Chem. Solids, 63, 135 (2002)
7 Y. Zhou, H. Itoh, T. Uemura, K. Naka, and Y. Chujo, Langmuir, 18, 5287 (2002)
8 L. Quaroni and G. Chumanov, J. Am. Chem. Soc., 121, 10642 (1999)
9 C. Johans, J. Clohessy, S. Fantini, K. Kontturi, and V. J. Cunnane, Electrochem. Commun., 4, 227 (2002)
10 W. K. Son, J. H. Youk, T. S. Lee, and W. H. Park, Macromol. Rapid Commun., 25, 1632 (2004)
11 W. K. Son, J. H. Youk, T. S. Lee, and W. H. Park, Polymer, 45, 2959 (2004)
12 C. Park, M. Rhue, J. Lim, and C. Kim, Macromol. Res., 15, 39 (2007)   과학기술학회마을   DOI
13 D. I. Cha, K. W. Kim, G. H. Chu, H. Y. Kim, K. H. Lee, and N. Bhattarai, Macromol. Res., 14, 331 (2006)   과학기술학회마을   DOI
14 Z. Lin, B. Gilbert, Q. Liu, G. Ren, and F. Huang, J. Am. Chem. Soc., 128, 6126 (2006)   DOI   ScienceOn
15 K. Park, H. J. Jung, J. J. Kim, K.-D. Ahn, D. K. Han, and Y. M. Ju, Macromol. Res., 14, 552 (2006)   과학기술학회마을   DOI
16 J. Bai, Y. Li, S. Yang, J. Du, S. Wang, J. Zheng, Y. Wang, Q. Yang, X. Chen, and X. Jing, Solid State Commun., 141, 292 (2007)
17 S.-D. Oh, B.-S. Byun, S. Lee, S. H. Choi, M. I. Kim, and H. J. Park, Macromol. Res., 15, 285 (2007)   과학기술학회마을   DOI
18 L. Nicolais and G. Carotenuto, Metal-polymer nanocomposites, Wiley, New Jersey, 2005.
19 G. I. Frolov, Tech. Phys., 46, 1537 (2001)   DOI   ScienceOn
20 A. K. Boal and V. M. Rotello, J. Am. Chem. Soc., 122, 734 (2000)
21 K. J. Klabunde, J. Habdas, and G. Crdenas-Trivi-o, Chem. Mater., 1, 481 (1989)
22 P. Mulvaney, Langmuir, 12, 788 (1996)
23 A. B. Kharitonov, A. N. Shipway, and I. Willner, Anal. Chem., 71, 5441, (1999)
24 K. H. A. Lau, W. Knoll, and D. H. Kim, Macromol. Res., 15, 211 (2007)   과학기술학회마을   DOI
25 A. B. Kharitonov, A. N. Shipway, E. Katz, and I. Willner, Rev. Anal. Chem., 18, 255, (1999)
26 M. Brust, M. Walker, D. Bethell, D. J. Schiffrin, and R. Whyman, J. Chem. Soc., Chem. Commun., 801 (1994)
27 Y. Wang, Y. Li, G. Sun, G. Zhang, H. Liu, J. Du, S. Yang, J. Bai, and Q. Yang, J. Appl. Polym. Sci., 105, 3618 (2007)
28 U. Heiz and U. Landman, Nanocatalysis, Springer, Berlin, 2007
29 Y. H. Jung, H. Y. Kim, D. R. Lee, S. Y. Park, and M. S. Khil, Macromol. Res., 13, 385 (2005)
30 S.-D. Oh, B.-S. Byun, S. Lee, and S. H. Choi, Macromol. Res., 14, 194 (2006)   과학기술학회마을   DOI
31 G.-M. Kim, A. Wutzler, H.-J. Radusch, G. H. Michler, P. Simon, R. A. Sperling, and W. J. Parak, Chem. Mater., 17, 4949 (2005)
32 Z.-M. Auang, Y.-Z. Zhang, M. Kotaki, and S. Ramakrishna, Composites Sci. Tech., 63, 2223 (2003)
33 G. Shemer and G. Markovich, J. Phys. Chem. B, 106, 9195 (2002)   DOI   ScienceOn
34 M. S. El-Shall and W. Slack, Macromolecules, 28, 8456 (1995)
35 T. K. Sarma, D. Chowdhury, A. Paul, and A. Chattopadhyay, Chem. Commun., 1048 (2002)
36 Q. L. Feng, J. Wu, G. Q. Chen, F. Z. Cui, T. N. Kim, and J. O. Kim, J. Biomed. Mater. Res., 52, 662 (2000)
37 L. Balan and D. Burget, Eur. Polym. J., 42, 3180 (2006)
38 H. Park, K. Y. Lee, S. J. Lee, K. E. Park, and W. H. Park, Macromol. Res., 15, 238 (2007)   과학기술학회마을   DOI