• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.22-28
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• 2019

To maximize the oxygen evolution reaction (OER) in the electrolysis of water, nano-grade $IrO_2$ powder with a low specific surface was prepared as a catalyst for a solid polymer electrolyte (SPE) system, and a membrane electrode assembly (MEA) was prepared with a catalyst loading as low as $2mg\;cm^{-2}$ or less. The $IrO_2$ catalyst was composed of heterogeneous particles with particle sizes ranging from 20 to 70 nm, having a specific surface area of $3.8m^2g^{-1}$. The anode catalyst layer of about $5{\mu}m$ thickness was coated on the membrane (Nafion 117) for the MEA by the decal method. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) confirmed strong adhesion at the interface between the membrane and the catalyst electrode. Although the loading of the $IrO_2$ catalyst was as low as $1.1-1.7mg\;cm^{-2}$, the SPE cell delivered a voltage of 1.88-1.93 V at a current density of $1A\;cm^{-2}$ and operating temperature of $80^{\circ}C$. That is, it was observed that the over-potential of the cell for the oxygen evolution reaction (OER) decreased with increasing $IrO_2$ catalyst loading. The electrochemical stability of the MEA was investigated in the electrolysis of water at a current density of $1A\;cm^{-2}$ for a short time. A voltage of ~2.0 V was maintained without any remarkable deterioration of the MEA characteristics.

• 한국재료학회지
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• 제29권10호
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• pp.631-638
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• 2019

As automation systems become more common, there is growing interest in functional labeling systems using organic and inorganic hybrid materials. Especially, the demand for thermally and chemically stable labeling paper that can be used in a high temperature environment above $300^{\circ}C$ and a strong acid and base atmosphere is increasing. In this study, a composite coating solution for the development of labeling paper with excellent thermal and chemical stability is prepared by mixing a silica inorganic binder and titanium dioxide. The silica inorganic binder is synthesized using a sol-gel process and mixed with titanium dioxide to improve whiteness at high-temperature. Adhesion between the polyimide substrate and the coating layer is secured and the surface properties of the coating layer, including the thermal and chemical stability, are investigated in detail. The effects of the coating solution dispersion on the surface properties of the coating layer are also analyzed. Finally, it is confirmed that the developed functional labeling paper showed excellent printability.

• 한국표면공학회지
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• 제34권5호
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• pp.414-420
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• 2001

A 30-kV plasma immersion ion implantation setup (P $I^3$) has been equipped with a self-developed 6'-magnetron to perform hard coatings with enhanced adhesion by P $I^3$D(P $I^3$ assisted deposition) process. Using ICP source with immersed Ti antenna and reactive magnetron sputtering of Ti target in $N_2$/Ar ambient gas mixture, the TiN films were prepared on Si substrates at different pulse bias and ion-to-atom arrival ratio ( $J_{i}$ $J_{Me}$ ). Prior to TiN film formation the nitrogen implantation was performed followed by deposition of Ti buffer layer under A $r^{+}$ irradiation. Films grown at $J_{i}$ $J_{Me}$ =0.003 and $V_{pulse}$=-20kV showed columnar grain morphology and (200) preferred orientation while those prepared at $J_{i}$ $J_{Me}$ =0.08 and $V_{pulse}$=-5 kV had dense and eqiaxed structure with (111) and (220) main peaks. X-ray diffraction patterns revealed some amount of $Ti_{x}$ $N_{y}$ in the films. The maximum microhardness of $H_{v}$ =35 GN/ $M^2$ was at the pulse bias of -5 kV. The P $I^3$D technique was applied to enhance wear properties of commercial tools of HSS (SKH51) and WC-Co alloy (P30). The specimens were 25-kV PII nitrogen implanted to the dose 4.10$^{17}$ c $m^{-2}$ and then coated with 4-$\mu\textrm{m}$ TiN film on $Ti_{x}$ $N_{y}$ buffer layer. Wear resistance was compared by measuring weight loss under sliding test (6-mm $Al_2$ $O_3$ counter ball, 500-gf applied load). After 30000 cycles at 500 rpm the untreated P30 specimen lost 3.10$^{-4}$ g, and HSS specimens lost 9.10$^{-4}$ g after 40000 cycles while quite zero losses were demonstrated by TiN coated specimens.s.

• 한국건축시공학회지
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• 제24권1호
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• pp.77-86
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• 2024

본 연구에서는 폴리우레아 도막방수재의 시공 시차별 분석과 열화면에 대한 유지관리 시공 타입별 분석을 통해 시공 이음부위의 적정 시공 방안을 제시하고자 전체 16가지 조건을 대상으로 시공 이음부위에 대한 평가를 진행하였다. 결과 분석을 통해 시공시차가 길어지면 길어질수록 이음부를 통한 누수발생률은 증가하는 것으로 분석되었고, 프라이머 시공을 통해 누수 예방이 가능한 것으로 확인되었다. 또한 장시간 옥외 노출된 폴리우레아는 표면이 열화되어 약해진 상태이기 때문에 해당 부위를 연마할 경우 표면손상이 확대되어 계면 형성에 영향을 미치는 것으로 분석되어, 유지관리 시공 시에는 프라이머를 도포하고 시공하는 것이 바람직하겠으며, 동일한 우레아 계열의 재료를 시공하는 것이 방수 안정성을 확보할 수 있을 것으로 판단된다.

• 한국건축시공학회지
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• 제24권1호
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• pp.35-42
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• 2024

본 연구에서는 도로 보수재로서 메틸 메타크릴레이트(MMA)의 활용 적합성을 평가하였다. A type과 B type의 2가지 MMA를 콘크리트에 적용하여 건조시간, 인장 접착 강도, 내알칼리 시험을 진행하였다. 항온항습(R), 수중(W), 수중+염화이온(N)의 3가지 조건으로 양생하여 모체의 표면 상태를 설정하였다. 시험 결과, B type MMA가 A type 보다 빠른 건조시간과 우수한 내알칼리성을 나타냈다. 인장 접착 강도는 A type이 더 높게 나타났지만, 콘크리트 모체와 함께 탈락되었다. 본 연구 범위에서는 B type이 도로 보수재로 사용하기 적합하다고 판단된다. 그러나 내구성을 고려하여 아스팔트 모체에서의 추가 실험을 진행할 필요가 있다.

• Journal of Korean Vacuum Science & Technology
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• 제6권2호
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• pp.105-107
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• 2002

a-C:H films were coated on windows of mobile telephone by RF plasma chemical vapor deposition equipment made in our company. Thickness of the coatings is about 0.7 micrometers and they have high hardness, low friction coefficient, good adhesion, high optical transparency and chemical inertness. Knoop hardness of the diamond-like carbon films on glass substrate is 2328 kg/mm$^2$. The adherence between films and substrate is good and shows to be 69 N by scratching test. The optical performance is improved obviously owing to coat the film on it. The index of the coated windows is 2.5, transmission of visible light is larger than 90%, and transmission of ultraviolet light decreases by 30% and the ultraviolet light can be obstructed obviously. The coated glass also has self-clean effect and decontamination ability. The films have hydrophobic character and the soakage angle of water drop is larger than 90 degrees. The windows have fog-proof ability owing to eliminate the capillary phenomena in the inner surface. The physics and chemical properties of the coated windows are steady. Study indicates that the performance of a-C:H coated mobile phone windows are improved notably on wear-resistance, corrosion-proof and optical properties and it is excellent mobile windows protective coatings.

• Corrosion Science and Technology
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• 제8권5호
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• pp.197-202
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• 2009

The high toxicity of wax, oil, varnish and volatile corrosion inhibitor(VCI) corrosion inhibitors lead to an increasing interest in using non-toxic alternatives such as anti-corrosive film. This study aims to investigate the possibility to use acryl based anti-corrosive film as a substitution of toxic corrosion inhibitors. Acryl emulsions were polymerized by several acryl monomers(acrylonitrile(AN), n-butyl acrylate(nBA), methylmethacrylate(MMA) and glycycyl methacrylate(GMA)), non-toxic corrosion inhibitor, crosslinking agents(diethylene glycol dimethacrylate(DEGDA)) and various additives in order to apply substrate of anti-corrosive film. Acryl emulsion for anti-corrosive film(AeACF) as a substrate of corrosion inhibitor film has excellent removal characteristic at above $25^{\circ}C$. The crosslinked by DEGDA in a range of above 4 wt% content anti-corrosive film can easily remove from the metal surface by using hands because it kept a balance of cohesion and adhesion strength. Anti - corrosive performance of AeACF is better than anti-corrosive oil by corrosion rate test, which was measured $54.3mg/dm^2$ day(MDD) and $142.9mg/dm^2$ day, respectively. Anti-corrosive film consisting of acryl monomers and inorganic anti-corrosive ingredients did not emit any toxic pollutants by gas chromatography. Thus it is estimated that acryl based anti-corrosion film can substitute toxic corrosion inhibitors.

• 한국의류학회지
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• 제29권5호
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• pp.671-679
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• 2005

Chitosan is the affinitive finishing agent and gives susceptible effect in textile finishing. In order to examine the modification of polyester fabric treated with chitosan, we observed the characteristic of polyester fabric surface and measured its physical properties. For the purpose of confirming the adhesion of cationic material, we made a comparative study on anionic acid dye. The fabric was treated with crosslinking agent after chitosan finishing. Glutardialdehyde as crosslinking agent was used to improve the fixation rate of chitosan on the polyester fabric. And the US value was increased according to increasing of chitosan concentration. As the concentration of crosslinking agent was increased, whiteness index of the fabric chitosan treated was increased. Moisture regain of the fabric treated with $1\%$ chitosan was doubled and that treated with $2\%$ chitosan was tripled comparing with original fabric. Tensile strength of the chitosan treated fabric had been an increase of $10\%$ compared with alkali treated fabric and crease resistance decreased regardless of chitosan concentration.

• 대한기계학회논문집B
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• 제38권6호
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• pp.513-523
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• 2014

유체이송 기술은 최근 마이크로 유체시스템 개발에서 핵심문제로 인식되고 있다. 본 연구에서는 최근 저자가 제안한 외부동력을 사용하지 않고 액적을 이송시킬 수 있는 새로운 개념인 친수성/소수성 수평 표면에서의 액적이송을 자체개발 코드(PowerCFD)를 사용하여 수치해석하였다. 수치해석에 사용된 코드는 보존적인 압력기반 유한체적방법에 기초한 비정렬 셀 중심 방법 및 VOF 방법에 체적포착법인 CICSAM을 채용하고 있다. 액적 내 및 주위의 속도벡터, 압력분포 및 전체운동에너지와 같은 수치해석 결과를 제시하고 이 결과들을 통해 액적이송 메커니즘을 규명하였다.

• 대한전자공학회논문지SD
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• 제40권2호
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• pp.81-86
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• 2003

반도체형 압력센서를 이용하여 물이나 화학약품 매질의 압력을 측정하기 위해서는 센서를 보호하기 위한 패키징이 필요하다. 스테인레스 봉입형 압력센서는 SUS316으로 패키지 되어있으며 SUS316은 표면이 다량의 크롬과 니켈을 함유하고 있어 내부식성이 강하고 또한 인성 및 응접성이 양호하여 센서를 분리하는 박막으로 널리 사용된다. 그렇지만 SUS316은 강산과 강알칼리 용매에서는 급격히 부식된다. 따라서 내부식성이 우수한 파리렌 막을 SUS316의 표면에 2000A의 Cu막을 증착한 다음에 5㎛ 두께로 처리함으로써 내화학성이 우수한 압력센서를 제작할 수 있었다, 파리렌 막을 코팅하기 전에 봉입형 압력센서의 정확도는 ±0.5%FSO이었고, 코팅 후의 센서도 동일한 특성을 보여주었다.