• Journal of Electrochemical Science and Technology
• /
• v.13 no.2
• /
• pp.199-207
• /
• 2022

Lithium-sulfur batteries (LSBs) have emerged as a promising alternative to lithium-ion batteries (LIBs) owing to their high energy density and economic viability. In addition, all-solid-state LSBs, which use solid-state electrolytes, have been proposed to overcome the polysulfide shuttle effect while improving safety. However, the high interfacial resistance and poor ionic conductivity exhibited by the electrode and solid-state electrolytes, respectively, are significant challenges in the development of these LSBs. Herein, we apply a poly (ethylene oxide) (PEO)-based composite solid-state electrolyte with oxide Li₇La₃Zr₂O₁₂ (LLZO) solid-state electrolyte in an all-solid-state LSB to overcome these challenges. We use an electrochemical method to evaluate the degradation of the all-solid-state LSB in accordance with the carbon content and loading weight within the cathode. The all-solid-state LSB, with sulfur-carbon content in a ratio of 3:3, exhibited a high initial discharge capacity (1386 mAh g^-1), poor C-rate performance, and capacity retention of less than 50%. The all-solid-state LSB with a high loading weight exhibited a poor overall electrochemical performance. The factors influencing the electrochemical performance degradation were revealed through systematic analysis.

• 전기의세계
• /
• v.29 no.8
• /
• pp.532-537
• /
• 1980

Effect of Argon and Sulfur hexafloride in the transformer oil are experimented under non-uniform A.C. electric field. The result has shown that the corona frequency and corona charge quantity in liquid dielectrics were varied with gas condition in the oil and affected by the additives. SF$_{6}$ that has the effects of pressure and electrical negative characteristic is the most effective. The corona is considered to be the breakdown of bubble produced by gas contained in the oil or by dissociated ion of the oil molecules.s.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.14 no.2
• /
• pp.78-84
• /
• 2000

마이크로파 방전 무전극 황전등은 마그네트론에서 발생된 마이크로파로 이원자 황을 여기하여 방출되는 빛을 조명에 사용하는 차세대 조명기구이다. 이원자 황에서 방출된 빛은 자외선과 적외선이 매우 적고 가시광선 영역에서 연속적인 분광 분포를 가지며 발광 효율은 100[1m/W] 이상으로 매우 높다 본 논문에서는 전력연구원에서 국내 최초로 개발한 마이크로파 여기형 무전극 방전등을 소개한다. 방전구의 회전, 방전전력과 압력의 조정, 및 Na 등의 첨가를 통해 전등의 상관색온도를 가변(2,500 - 10,000 K 범위)하였다. 아울러 연색성 평가수를 90 이상으로 개선 할 수 있음을 보였다.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.57 no.4
• /
• pp.635-640
• /
• 2008

New gas mixtures are now finding applications such as interrupting media for high-voltage circuit breakers. These mixtures consist of a high content of carbon tetrafluoride($CF_4$) added to sulfur hexafluoride($SF_6$). Nowdays $SF_6$ has been established for the use in gas insulated substations due to its high insulation withstand level and good arc quenching capability. At this paper Breakdown characteristics were investigated for $SF_6/CF_4$ mixtures when AC voltage and standard lightning impulse voltage(LI) was applied in a needle-plane electrodes. And partial discharge(PD) experiments were carried out in the test chamber which was made in needle-plane electrode. And ${\Phi}$-Q-N distribution of partial discharge signals was analyzed. The total pressure of the $SF_6/CF_4$ mixtures was varied within the range of 0.1-0.5 Mpa in the test chamber. The breakdown voltage in needle-plane electrode displayed N shape characteristics for increasing the content of $SF_6$ at positive impulse voltage and the PD inception voltage was increased slightly when pressure of $SF_6/CF_4$ Mixtures was increased. Maximum PD inception voltage is showed in 80% SF6/20%$CF_4$.

• Journal of the Korean Geographical Society
• /
• v.44 no.4
• /
• pp.429-446
• /
• 2009

To understand the sulfur flux and cycle in the forest catchment, the hydrological processes and chemical variation of soil solution, groundwater and stream water were analyzed at the Matsuzawa catchment located in the Kiryu Experimental Basin, Shiga Prefecture, central Japan. Unsaturated soil layer at the upper slope of catchment was the source area of ${SO_4}^{2-}$, and deep soil layer and groundwater were the sink zone of ${SO_4}^{2-}$. The vertical distribution of ${SO_4}^{2-}$ concentrations in groundwater affected seasonal variation of ${SO_4}^{2-}$ concentrations in stream water, as groundwater level changed. It is reasonable to assume that each hydrological processes in the forest catchment play an important roles in the retention and discharge of ${SO_4}^{2-}$.

• Korean Journal of Crystallography
• /
• v.14 no.2
• /
• pp.110-114
• /
• 2003

LiAl/sub 0.24/Mn/sub 1.76/O/sub 4-y/S/sub y/ (y=0, 0.02) were synthesized by the sol-gel method. Both structures were refined by Rietveld method, its structure refined as a cubic spinel, space group Fd-3m, a=8.17937(30) Å and 8.18331(19) Å respectively. Though it has been made a charge/discharge experiment above 20 times, there was no change of 3 V/4 V capacity degradation. It was considered that the volume change of MnO/sub 6/ octahedron induced by sulfur substitution plays a key role in keeping the 3 V/4 V capacity. The refined composition of the compound could be confirmed with the ICP analysis.

• Journal of Electrochemical Science and Technology
• /
• v.5 no.2
• /
• pp.49-52
• /
• 2014

Graphene nanosheets (GNS), nitrogen-doped graphene nanosheets (N-GNS), and sulfur-doped graphene nanosheets (S-GNS) were successfully synthesized, and their catalytic effects on the oxygen reduction reaction (ORR) in $Li-O_2$ batteries were compared. The S-GNS electrode exhibited the highest ORR catalytic activity, resulting in enhanced discharge capacity and power capability. We attributed the enhanced ORR catalytic activity to the increased defect sites on graphene.

• Journal of Environmental Health Sciences
• /
• v.26 no.4
• /
• pp.38-44
• /
• 2000

Compared to other waste, waste tire has much discharge quantity and calorie. When we use waste heat from waste tire, it can be definitely better substitute energy than coal and anthracite in high oil price age. To use as a basic data for providing low cost and highly effective heating system, following conclusion was founded. Annual waste tire production was 19,596 million in 1999, Recycling ratio was almost 55% and more than 8.78 million was stored. Waste tire has lower than 1.5% sulfur contain ratio which is resource of an pollution, So it is a waste fuel which can be combustion based on current exhaust standard value without any extra SOx exclusion materials. Waste tire has 9,256Kcal/kg calorific value and it is higher than waste rubber, waste rubber, waste energy as same as B-C oil. When primary and second air quantity was 1.6, 8.0 Nm$^3$/min, dry gas production time was 270min and total combustion time was 360 min. In the SOx, NOx, HC of air pollution material density were lower than exhaust standard value at the back of cyclone and dusty than exhaust standard value without dust collector.

• Proceedings of the KIEE Conference
• /
• 2003.07c
• /
• pp.1623-1625
• /
• 2003

마이크로과 방전 무전극 황전등은 마그네트온에서 발생된 마이크로파로 2-원자 황을 여기하여 방출되는 빛을 조명에 사용하는 차세대 조명기구이다. 1990년대 초반에 미국의 Fusion Lighting Inc에 의해 최초로 소개된 무전극 황전등은 방전구 회전에 의한 방전을 하였다. 기존의 방전기술은 선형편파를 이용, 필드가 중앙에 모이므로 램프를 회전시켜 방전을 유지하였다. 그에 따라 시스템 구성이 복잡해지고 램프회전 속도에 따라 방전에 영향을 주었다. 본 논문에서는 원편파를 이용하여 램프 회전에 따른 문제점을 해결하고, 원편파에 의해 발생된 회전 플라즈마 방전현상을 실험적으로 보인다. 또한 원편파 방전에 의판 분광분포 및 휘도 분석등 방전 현상을 관찰했다. 아울러 연색성이 80이상, 색온도 4900k ${\sim}$ 6827k 범위를 보였다.

• The Journal of Korea Robotics Society
• /
• v.17 no.1
• /
• pp.93-101
• /
• 2022

Bioheavy oil, which is expanding its range of use as an alternative fuel to reduce environmental pollutant emissions, has a lot of difficulty in combustion due to its low emission of pollutants such as nitrogen oxide (NOx) and sulfur oxide (SOx), while its low dissipation and high oxygen content in fuel. many studies have been conducted on change in characteristics by mixing rate combustion characteristics and combustion reactions, but there have been no specific and effective studies on the composition of control system, optimization of control, development of logic for mixing and burning, minimizing environmental pollutantants discharge. In this study, we intend to consider systemmatic and empirical considerations on the composition, logic development, solve the problem of manual switching of bioler master due to excessive oxygen content and tuning of the control system for optimal combustion of bioheavy oil.