• Title/Summary/Keyword: Subcritical water

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Thermo-chemical Conversion of Poplar Wood (Populus alba × glandulosa) to Monomeric Sugars by Supercritical Water Treatment (초임계수에 의한 현사시나무의 당화 특성)

  • Choi, Joon-Weon;Lim, Hyun-Jin;Han, Kyu-Sung;Choi, Don-Ha
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.6
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    • pp.44-50
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    • 2006
  • To characterize thermo-chemical feature of su gar conversion of woody biomass poplar wood (Populus alba${\times}$glandulosa ) by sub- and supercritical water was treated for 60s under subcritical (23 MPa, 325 and $350^{\circ}C$) and supercritical (23 MPa, 380, 400, and $425^{\circ}C$) conditions, respectively. Among degradation products undegraded poplar wood solids existed in aqueous products. As the treatment temperature increased, the degradation of poplar wood was enhanced and reached up to 83.1% at $425^{\circ}C$. The monomeric sugars derived from fibers of poplar wood by sub- and supercritical treatment were analyzed by high performance anionic exchange chromatography (HPAEC). Under the subcritical temperature ranges, xylan, main hemicellulose component in poplar wood, was preferentially degraded to xylose, while cellulose degradation started at the transition zone between sub and supercritical conditions and was remarkably accelerated at the supercritical condition. The highest yield of monomeric sugars amounts to ca. 7.3% based on air dried wood weight (MC 10%) at $425^{\circ}C$.

Comparison on the Extraction Efficiency and Antioxidant Activity of Flavonoid from Citrus Peel by Different Extraction Methods (추출방법에 따른 감귤 과피 유래 Flavonoid의 추출효율 및 항산화 효과에 대한 비교)

  • Cheigh, Chan-Ick;Jung, Won-Guen;Chung, Eun-Young;Ko, Min-Jung;Cho, Sang-Woo;Lee, Jae-Hwan;Chang, Pahn-Shick;Park, Young-Seo;Paik, Hyun-Dong;Kim, Kee-Tae;Chung, Myong-Soo
    • Food Engineering Progress
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    • v.14 no.2
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    • pp.166-172
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    • 2010
  • The extraction of polyphenol and flavonoid from citrus peel was performed by the ethanol, sugar, hot water (80$^{\circ}C$), and subcritical water extraction methods. The maximum yields of total polyphenolic compounds (27.25${\pm}$1.33 mg QE/g DCP, QE and DCP indicate quercetin equivalent and dried citrus peel, respectively) and flavonoids (7.31${\pm}$0.41 mg QE/g DCP) were obtained by subcritical water extraction (SWE) with operating conditions of 190$^{\circ}C$, 1300 psi, and 10 min. The yields by SWE were over 7.2-, and 8.5-fold higher than those of total polyphenols (3.79${\pm}$0.73 mg QE/g DCP) and flavonoids (0.86${\pm}$0.27 mg QE/g DCP) obtained using the ethanol extraction, which showed the highest extraction efficiency among tested conventional methods, respectively. Antioxidant activities of extracts obtained by different methods showed no significant differences. However, the relative antioxidant yield per 1 g dried citrus peel by SWE (190$^{\circ}C$, 10 min) was over 9.5-fold higher than that by the ethanol extraction.

Effect of Subcritical Water for the Enhanced Extraction Efficiency of Polyphenols and Flavonoids from Black Rice Bran (흑미강으로부터 유용 폴리페놀 및 플라보노이드의 추출효율 증진을 위한 아임계수의 효과)

  • Cheigh, Chan-Ick;Chung, Eun-Young;Ko, Min-Jung;Cho, Sang-Woo;Chang, Pahn-Shick;Park, Young-Seo;Lee, Kyoung-Ah;Paik, Hyun-Dong;Kim, Kee-Tae;Hong, Seok-In;Chung, Myong-Soo
    • Food Engineering Progress
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    • v.14 no.4
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    • pp.335-341
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    • 2010
  • The extraction of polyphenol and flavonoid from black rice bran was performed by diverse extraction methods using the sugar solution, ethanol, hot water ($80^{\circ}C$), and by subcritical water extraction (SWE) method. By SWE under operating conditions of $190^{\circ}C$, 1,300 psi, and 10 min, the maximum yields of total polyphenolic compounds (35.06${\pm}$1.28 mg quercetin equivalent (QE)/g dried material and flavonoids (7.08${\pm}$0.31 mg QE/g dried material) could be obtained. These results were over 11.77- and 12.21-fold higher than those of the ethanol extraction, which showed the highest extraction efficiency among tested conventional methods in total polyphenols (2.98${\pm}$0.74 mg QE/g dried material) and flavonoids (0.58${\pm}$0.21 mg QE/g dried material), respectively. Though the highest antioxidant activity (87.14${\pm}$1.14%) was observed at the dried extract obtained from ethanol method, the relative antioxidant activity per 1 g dried black rice bran by SWE ($190^{\circ}C$, 10 min) was over 11.53-fold higher than that by the ethanol extraction.

Modelling and Verification of Once-Through Subcritical Heat Recovery Steam Generator (관류형 아임계압 배열회수보일러의 열성능 모델링과 검증)

  • Lee, Chae-Soo;Choi, Young-Jun;Kim, Hyun-Gee;Yang, Ok-Chul;Chong, Chae-Hon
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1692-1697
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    • 2004
  • The once-through heat recovery steam generator is ideally matched to very high temperature and pressure, well into the supercritical range. Moreover this type of boiler is structurally simpler than drum type boiler. In drum type boiler, each tube play a well-defined role: water preheating, vaporization, superheating. Empirical equations are available to predict the average heat transfer coefficient for each regime. For once-through heat recovery steam generator, this is no more the case and mathematical models have to be adapted to account for the disappearance of drum type economizer, boiler, superheater. General equations have to be used for each tube of boiler, and actual heat transfer condition in each tube has to be identified.

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Stress Corrosion Crack Growth Evaluation in Primary Loop of Nuclear Power Plant (원전 주배관의 응력부식 가상결함 성장에 대한 잔류응력 영향 평가)

  • Yang, J.S.;Park, C.Y.;Yoon, K.S.;Kang, S.Y.;Oho, J.K.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.274-277
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    • 2004
  • The most important mode of subcritical crack growth is primary water stress corrosion crack, which was the reported mechanism from the root cause analysis of the crack in the bimetallic welds. Stress corrosion crack growth evaluations was carried out for several flaw shapes of both axial and circumferential flaws, using the steady-state stresses including residual stresses. This evaluation considered the possibility of additional flaws in the primary loops of nuclear power plant, even though no such flaws have been identified by Ultrasonic Test. Consequently, Results show that the predicted flaw sizes will determine acceptability for continued service and maintenance.

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Measurement of safety rods reactivity worth by advanced source jerk method in HWZPR

  • Nasrazadani, Z.;Ahmadi, A.;Khorsandi, J.
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.963-967
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    • 2019
  • Accurate measurement of the reactivity worth of safety rods is very important for the safe reactor operation, in normal and emergency conditions. In this paper, the reactivity worth of safety rods in Heavy Water Zero Power Reactor (HWZPR) in the new lattice pitch is measured by advanced source jerk method. The average of the results related to two different detectors is equal to 29.88 mk. In order to verify the result, this parameter was compared to the previously measured value by subcritical to critical approach. Different experiment results are finally compared with corresponding calculated result. Difference between the average experimental and calculated results is equal to 2.2%.

Volatile Fatty Acid Production from Saccharina japonica Extracts by Anaerobic Fermentation: Evaluation of Various Environmental Parameters for VFAs Productivity (혐기성 발효에 의한 다시마 추출물로부터 휘발성 유기산 제조: 휘발성 유기산 생산성에 대한 환경적 영향인자 평가)

  • Choi, Jae Hyung;Song, Min Kyung;Chun, Byung Soo;Lee, Chul Woo;Woo, Hee Chul
    • Clean Technology
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    • v.19 no.2
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    • pp.148-155
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    • 2013
  • Volatile fatty acids (VFAs) production from marine brown algae, Saccharina japonica, was investigated in anaerobic dark fermentation. In order to evaluate the VFAs productivity, various experimental parameters (i.e., physicochemical pre-treatment, microorganism inoculation ratio, substrate concentration, and pH) were evaluated. According to the physicochemical pre-treatment methods, the maximum concentrations of VFAs were obtained in the order of sulfuric acid, subcritical water and subcritical water with lipid-extraction. Also, we investigated the operating parameters such as microorganism inoculation ratio (MV/M = 10 to 30), the substrate concentration (18.0 to 72.0 g/L) and pH (6.0 to 7.0) in sulfuric acid pre-treatment method. When the substrate concentrations were 18.0, 36.0, 54.0 and 72.0 g/L at $35^{\circ}C$, microorganism inoculation ratio 15, pH 7.0 for 372 hours, the maximum concentrations of VFAs were respectively 9.8, 13.9, 18.6 and 22.3 g/L. The change in VFAs concentrations was detected that acetic- and propionic acids increased according to increasing pH, while the butyric acid increased with decreasing pH. The VFAs obtained from concentration and separation process may be used as basic chemistry materials and bio-fuel, and they will expect to produce alternative energy of fossil fuel.

Dynamic Simulation of the Water-steam System in Once-through Boilers - Sub-critical Power Boiler Case - (관류보일러 물-증기 계통의 동적 시뮬레이션 - 아임계 동력보일러 사례 -)

  • Kim, Seongil;Choi, Sangmin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.5
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    • pp.353-363
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    • 2017
  • The dynamics of a water-steam system in a once-through boiler was simulated based on the physics-based modeling approach, representing the system in response to large load change or scale disturbance simulations. The modeling considered the mass, energy conservation, and momentum equation in the water pipe and the focus was limited to the sub-critical pressure region. An evaporator tube modeling was validated against the reference data. A simplified boiler system consisting of economizer, evaporator, and superheater was constructed to match a 500 MW power boiler. The dynamic response of the system following a disturbance was discussed along with the quantitative response characteristics. The dynamic response of the boiler system was further evaluated by checking the case of an off-design point operation of the feedwater-to-fuel supply ratio. The results re-emphasized the significance of controlling the feedwater-to-fuel supply ratio and additional design requirements of the water-steam separator and spray attemperator.

Weighted Averaged Flux Method for Computation of Shallow Water Equations (WAF 기법을 이용한 천수방정식 해석)

  • Kim, Woo-Gu;Jung, Kwan-Sue;Kim, Jae-Han
    • Journal of Korea Water Resources Association
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    • v.36 no.5
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    • pp.777-785
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    • 2003
  • A numerical model for the solution of two-dimensional free surface flow is developed on unstructured grid. By using fractional step method, the two-dimensional shallow water equations (SWE) are treated as two one-dimensional problems. Thus, it is possible to simulate computational hydraulic problems with higher computational efficiency. The one-dimensional problems are solved using upwind TVD version of second-order Weighted Averaged Flux (WAF) scheme with HLLC approximate Riemann solver. The numerical oscillations which are common with second-order numerical scheme are controlled by exploiting WAF flux limiter, Some idealized test problems are solved using this model and very accurate and stable solutions are obtained. It can be concluded as an efficient implement for the computation of SWE including dam break problems that concerning discontinuities, subcritical and supercritical flows and complex domain.

Depth Averaged Numerical Model for Sediment Transport by Transcritical Flows (급변류에 의한 하상변동 예측을 위한 수심적분 수치모형)

  • Kim, Boram;Kim, Dae-Hong
    • Journal of Korea Water Resources Association
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    • v.47 no.11
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    • pp.1061-1066
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    • 2014
  • A stable second-order finite volume method was proposed to predict sediment transport under rapidly varied flow conditions such as transcritical flow. For the use under unsteady flow conditions, a sediment transport model was coupled with shallow water equations. HLLC approximate Riemann solver based on a monotone upstream-centered schemes for conservation laws (MUSCL) reconstruction was used for the computation of the flux terms. From the comparisons of dam break flow experiments on erodible beds in one- and two-dimensional channels, good agreements were obtained when proper parameters were provided. Lastly, dam surface erosion problem by overtopped water was simulated. Overall, the numerical solutions showed reasonable results, which demonstrated that the proposed numerical scheme could provide stable and physical results in the cases of subcritical and supercritical flow conditions.