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Study of molecular motion by 1H NMR relaxation in ferroelectric LiH3(SeO3)2, Li2SO4·H2O, and LiN2H5SO4 single crystals

  • Park, Sung Soo
    • Journal of the Korean Magnetic Resonance Society
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    • v.20 no.1
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    • pp.1-6
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    • 2016
  • The proton NMR line widths and spin-lattice relaxation rates, $T_1^{-1}$, of ferroelectric $LiH_3(SeO_3)_2$, $Li_2SO_4{\cdot}H_2O$, and $LiN_2H_5SO_4$ single crystals were measured as a function of temperature. The line width measurements reveal rigid lattice behavior of all the crystals at low temperatures and line narrowing due to molecular motion at higher temperatures. The temperature dependences of the proton $T_1^{-1}$ for these crystals exhibit maxima, which are attributed to the effects of molecular motion by the Bloembergen - Purcell - Pound theory. The activation energies for the molecular motions of $^1H$ in these crystals were obtained. From these analysis, $^1H$ in $LiH_3(SeO_3)_2$ undergoes molecular motion more easily than $^1H$ in $LiN_2H_5SO_4$ and $Li_2SO_4{\cdot}H_2O$ crystals.

1,3-Dioxolane-Based CO2 Selective Polymer Membranes for Gas Separation (1,3-Dioxolane 기반 CO2 선택성 고분자막의 개발)

  • Iqubal Hossain;Asmaul Husna;Ho Bum Park
    • Membrane Journal
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    • v.33 no.3
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    • pp.94-109
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    • 2023
  • 1,3-Dioxolane is an exciting material that has attracted widespread interest in the chemical, paint, and pharmaceutical industries as a solvent, electrolyte, and reagent because 1,3-dioxolane is not toxic, carcinogenic, explosive, auto-flammable, and multifunctional, and due to their excellent miscibility in most organic and aqueous solvent conditions. Recently, this material has received increasing attention as a CO2-selective polymer precursor to separating CO2 from flue gas and natural gas mixtures. Poly(1,3-dioxolane) (PDXL) possesses higher ether oxygen content than polyethylene oxide (PEO), which demonstrates superior membrane CO2/N2 separation properties owing to their polar ether oxygen groups exhibiting strong affinity toward CO2. Thus, PDXL-based membranes displayed an outstanding CO2 solubility selectivity over non-polar (N2, H2, and CH4) gases. However, the polar groups of PDXL, like PEO, promote chain packing efficiency and cause polymer crystallization, thereby reducing its gas permeability, which should be improved. In this short review, we discuss the recent advancement and limitations of PDXL membranes in gas separation applications. To conclude, we provide future perspectives for inhibiting the limits of 1,3-dioxolane-based polymers in the CO2 separation process.

${\mathfrak{A}}$-GENERATORS FOR THE POLYNOMIAL ALGEBRA OF FIVE VARIABLES IN DEGREE 5(2t - 1) + 6 · 2t

  • Phuc, Dang Vo
    • Communications of the Korean Mathematical Society
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    • v.35 no.2
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    • pp.371-399
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    • 2020
  • Let Ps := 𝔽2[x1, x2, …, xs] = ⊕n⩾0(Ps)n be the polynomial algebra viewed as a graded left module over the mod 2 Steenrod algebra, ${\mathfrak{A}}$. The grading is by the degree of the homogeneous terms (Ps)n of degree n in the variables x1, x2, …, xs of grading 1. We are interested in the hit problem, set up by F. P. Peterson, of finding a minimal system of generators for ${\mathfrak{A}}$-module Ps. Equivalently, we want to find a basis for the 𝔽2-graded vector space ${\mathbb{F}}_2{\otimes}_{\mathfrak{A}}$ Ps. In this paper, we study the hit problem in the case s = 5 and the degree n = 5(2t - 1) + 6 · 2t with t an arbitrary positive integer.

ON THE FIRST GENERALIZED HILBERT COEFFICIENT AND DEPTH OF ASSOCIATED GRADED RINGS

  • Mafi, Amir;Naderi, Dler
    • Bulletin of the Korean Mathematical Society
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    • v.57 no.2
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    • pp.407-417
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    • 2020
  • Let (R, m) be a d-dimensional Cohen-Macaulay local ring with infinite residue field. Let I be an ideal of R that has analytic spread ℓ(I) = d, satisfies the Gd condition, the weak Artin-Nagata property AN-d-2 and m is not an associated prime of R/I. In this paper, we show that if j1(I) = λ(I/J) + λ[R/(Jd-1 :RI+(Jd-2 :RI+I):R m)] + 1, then I has almost minimal j-multiplicity, G(I) is Cohen-Macaulay and rJ(I) is at most 2, where J = (x1, , xd) is a general minimal reduction of I and Ji = (x1, , xi). In addition, the last theorem is in the spirit of a result of Sally who has studied the depth of associated graded rings and minimal reductions for m-primary ideals.

A GLOBAL BEHAVIOR OF THE POSITIVE SOLUTIONS OF xn+1=βxn+ xn-2 ⁄ A+Bxn + xn-2

  • Park, Jong-An
    • Communications of the Korean Mathematical Society
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    • v.23 no.1
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    • pp.61-65
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    • 2008
  • In this paper we prove that every positive solution of the third order rational difference equation $$x_{n+1}\;=\;\frac{{\beta}x_n\;+\;x_{n-2}}{A\;+\;Bx_n\;+\;x_{n-2}}$ converges to the positive equilibrium point $$\bar{x}\;=\;\frac{{\beta}\;+\;1\;-\;A}{B\;+\;1}$, where $0\;<\;{\beta}\;{\leq}\;B$, $1\;<\;A\;<\;{\beta}\;+\;1$

Electrical Characteristics of Charge Trap Flash Memory with a Composition Modulated (ZrO2)x(Al2O3)1-x Film

  • Tang, Zhenjie;Zhang, Jing;Jiang, Yunhong;Wang, Guixia;Li, Rong;Zhu, Xinhua
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.3
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    • pp.130-134
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    • 2015
  • This research proposes the use of a composition modulated (ZrO2)x(Al2O3)1-x film as a charge trapping layer for charge trap flash memory; this is possible when the Zr (Al) atomic percent is controlled to form a variable bandgap as identified by the valence band offsets and electron energy loss spectrum measurements. Compared to memory devices with uniform compositional (ZrO2)0.1(Al2O3)0.9 or a (ZrO2)0.92(Al2O3)0.08 trapping layer, the memory device using the composition modulated (ZrO2)x(Al2O3)1-x as the charge trapping layer exhibits a larger memory window (6.0 V) at the gate sweeping voltage of ±8 V, improved data retention, and significantly faster program/erase speed. Improvements of the memory characteristics are attributed to the special energy band alignments resulting from non-uniform distribution of elemental composition. These results indicate that the composition modulated (ZrO2)x(Al2O3)1-x film is a promising candidate for future nonvolatile memory device applications.

Improving Reliability of SKD61 Using Nondamaging Technology (표면균열무해화 기법에 의한 SKD61의 신뢰성 향상)

  • Lee, Gum-Hwa;Gu, Kyoung-Hee;Kim, Jae-Hoon;Yun, Seo-Hyun;Kwon, Yung-Kug;Nam, Ki-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.5
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    • pp.791-797
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    • 2022
  • Using the fatigue limit (△σunsm) and residual stress (σr) of the UNSM smooth specimen, the harmless maximum crack depth (αhml) according to the crack aspect ratio (As) was evaluated. αhml evaluated the reliability in the relationship between the minimum crack depth (αNDI1, αNDI2) detectable by nondestructive inspection(NDI) and the crack depth (α25, α50) that reduces the fatigue limit by 25% and 50%. All αhml was determined by the crack depth. The αhml of 80N UNSM with high σr and high △σunsm was found to be large. σr in the depth direction had a much effect on αhml. Since αhml50(As=0.6-0.1) and αhml25, α25 and α50(some range) can secure the safety and reliability. Since αhml50 (As=1. 0-0. 6), it cannot be made harmless by UNSM. So safety and reliability cannot be secured. αNDI1 and αNDI2 are larger than α25, α25 cannot be detected by NDI. αNDI1 and αNDI2 are smaller than α50, α25 can detected by NDI.

MULTIPLIERS OF DIRICHLET-TYPE SUBSPACES OF BLOCH SPACE

  • Li, Songxiao;Lou, Zengjian;Shen, Conghui
    • Bulletin of the Korean Mathematical Society
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    • v.57 no.2
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    • pp.429-441
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    • 2020
  • Let M(X, Y) denote the space of multipliers from X to Y, where X and Y are analytic function spaces. As we known, for Dirichlet-type spaces 𝓓αp, M(𝓓p-1p, 𝓓q-1q) = {0}, if p ≠ q, 0 < p, q < ∞. If 0 < p, q < ∞, p ≠ q, 0 < s < 1 such that p + s, q + s > 1, then M(𝓓p-2+sp, 𝓓q-2+sq) = {0}. However, X ∩ 𝓓p-1p ⊆ X ∩ 𝓓q-1q and X ∩ 𝓓p-2+sp ⊆ X ∩ 𝓓q-2+sp whenever X is a subspace of the Bloch space 𝓑 and 0 < p ≤ q < ∞. This says that the set of multipliers M(X ∩ 𝓓 p-2+sp, X∩𝓓q-2+sq) is nontrivial. In this paper, we study the multipliers M(X ∩ 𝓓p-2+sp, X ∩ 𝓓q-2+sq) for distinct classical subspaces X of the Bloch space 𝓑, where X = 𝓑, BMOA or 𝓗.

ON ℤpp[u]/k>-CYCLIC CODES AND THEIR WEIGHT ENUMERATORS

  • Bhaintwal, Maheshanand;Biswas, Soumak
    • Journal of the Korean Mathematical Society
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    • v.58 no.3
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    • pp.571-595
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    • 2021
  • In this paper we study the algebraic structure of ℤpp[u]/k>-cyclic codes, where uk = 0 and p is a prime. A ℤpp[u]/k>-linear code of length (r + s) is an Rk-submodule of ℤrp × Rsk with respect to a suitable scalar multiplication, where Rk = ℤp[u]/k>. Such a code can also be viewed as an Rk-submodule of ℤp[x]/r - 1> × Rk[x]/s - 1>. A new Gray map has been defined on ℤp[u]/k>. We have considered two cases for studying the algebraic structure of ℤpp[u]/k>-cyclic codes, and determined the generator polynomials and minimal spanning sets of these codes in both the cases. In the first case, we have considered (r, p) = 1 and (s, p) ≠ 1, and in the second case we consider (r, p) = 1 and (s, p) = 1. We have established the MacWilliams identity for complete weight enumerators of ℤpp[u]/k>-linear codes. Examples have been given to construct ℤpp[u]/k>-cyclic codes, through which we get codes over ℤp using the Gray map. Some optimal p-ary codes have been obtained in this way. An example has also been given to illustrate the use of MacWilliams identity.

Electrochemical Advanced Oxidation of Lamotrigine at Ti/DSA (Ta2O5-Ir2O5) and Stainless Steel Anodes

  • Meena, Vinod Kumar;Ghatak, Himadri Roy
    • Journal of Electrochemical Science and Technology
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    • v.13 no.2
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    • pp.292-307
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    • 2022
  • The study presents kinetics of degradation and mineralization of an anti-epileptic drug Lamotrigine (LAM) in the aqueous matrix by electrochemical advanced oxidation process (EAOP) on Ti/DSA (Ta2O5-Ir2O5) and Stainless Steel (SS) anodes using sodium sulphate as supporting electrolyte. On both the anodes, kinetic behaviour was pseudo-first-order for degradation as well as mineralization of LAM. On Ti/DSA anode, maximum LAM degradation of 75.42% was observed at an associated specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 100 ppm Na2SO4 concentration. Maximum mineralization attained was 44.83% at an associated specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 50 ppm concentration of Na2SO4 with energy consumption of 2942.71 kWh/kgTOC. Under identical conditions on SS anode, a maximum of 98.92% LAM degradation was marked after a specific charge (Q) of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 100 ppm concentration of Na2SO4. Maximum LAM mineralization on SS anode was 98.53%, marked at a specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm2 and 75 ppm concentration of Na2SO4, with energy consumption of 1312.17 kWh/kgTOC. Higher Mineralization Current Efficiency (MCE) values were attained for EAOP on SS anode for both degradation and mineralization due to occurrence of combined electro-oxidation and electro-coagulation process in comparison to EAOP on Ti/DSA anode due to occurrence of lone electro-oxidation process.