• Title/Summary/Keyword: Sub-Cavity

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Spectroscopy of acetylene (13C2H2) using a tunable erbium-doped fiber ring laser (파장가변 광섬유 링 레이저를 이용한 아세틸렌(13C2H2) 분광)

  • 유한영;오정미;이동한;문한섭;이원규;박갑동;서호성
    • Korean Journal of Optics and Photonics
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    • v.14 no.6
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    • pp.674-679
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    • 2003
  • We fabricated erbium-doped fiber ring laser with a new structure that can operate in C- & L-band wavelength region. The wave-length of the laser can be tuned continuously over 102 nm between 1510.4-1612.6 nm by insertion of the fiber Fabry-Perot tunable filter (FFP-TF) in the ring cavity. By use of the wavelength tunable characteristics of our fiber laser, we measured absorption spectra of more than fifty transition lines of the acetylene ($^{13}$ C$_2$H$_2$) molecule with high signal to noise ratio (SNR).

Studies on Nusselt and Sherwood number for diffusion-advective convection during physical vapor transport of Hg2Br2

  • Kim, Geug Tae;Kwon, Moo Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.3
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    • pp.127-136
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    • 2021
  • This paper is dedicated to numerical simulation for diffusion-advective convection in a square cavity during physical vapor transport of Hg2Br2. Flow characteristics of the temperature difference between the source and crystal regions, 50℃ (300℃ → 250℃), partial pressures of component argon of 20 Torr and 100 Torr are investigated and presented as velocity vectors and streamlines, isotherms and iso-mass concentrations contours. Moreover, alterations of average Nusselt and average Sherwood numbers with (a) the source and crystal regions, (b) the pressures of component argon of 20 Torr and 100 Torr are analyzed and addressed in details. Both average Nusselt and average Sherwood numbers are seen to decrease with the increasing values of the partial pressures of component argon. Also, it is found that for the two different partial pressures of component argon, average Nusselt numbers at the source region are greater than at the crystal region, and inversely, average Sherwood numbers at the crystal region are greater than the source region by a factor of 3.

Synthesis and Single-crystal Structure of Fully Dehydrated Fully Ca2+exchanged Zeolite Y (FAU), |Ca35.5|[Si121Al71O384]-FAU

  • Seo, Sung-Man;Choi, Sik-Young;Suh, Jeong-Min;Jung, Ki-Jin;Heo, Nam-Ho;Lim, Woo-Taik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.8
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    • pp.1703-1710
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    • 2009
  • The single-crystal structure of |$Ca_{35.5}$|[$Si_{121}Al_{71}O_{384}$]-FAU, $Ca_{35.5}Si_{121}Al_{71}O_{384}$ per unit cell, a = 24.9020(10) $\AA$, dehydrated at 673 K and 2 ${\times}\;10^{-6}$Torr, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd$\overline{3}$m at 294 K. The large single crystals of zeolite Y (Si/Al = 1.70) were synthesized up to diameters of ${\mu}m\;and\;Ca^{2+}$-exchanged zeolite Y were prepared by ion exchange in a batch method of 0.05 M aqueous Ca($NO_3)_2$ for 4 hrs at 294 K. The structure was refined using all intensities to the final error indices (using only the 971 reflections for which $F_o\;>\;4{\sigma}(F_o))\;R_1$ = 0.038 (based on F) and $R_2$ = 0.172 (based on $F^2$). About 35.5 $Ca^{2+}$ ions per unit cell are found at an unusually large number of crystallographically distinct positions, four. Nearly filling site I (at the centers of the double 6-rings), 14.5 octahedrally coordinated $Ca^{2+}$ ions (Ca-O = 2.4194(24) $\AA$ and O-Ca-O = 87.00(8) and 93.00($8^o$) are found per unit cell. One $Ca^{2+}$ ion per unit cell is located at site II’ in the sodalite cavity and extends 0.50 $\AA$ into the sodalite cavity from its 3-oxygen plane (Ca-O = 2.324(13) $\AA$ and O-Ca-O = 115.5(10)o). The remaining twenty $Ca^{2+}$ ions are found at two nonequivalent sites II (in the supercages) with occupancies of 10 and 10 ions, respectively. Each of these $Ca^{2+}$ ions coordinates to three framework oxygens, either at 2.283(3) or 2.333(5) $\AA$, respectively, and extends either 0.24 or 0.54 $\AA$, respectively, into the supercage from the three oxygens to which it is bound. In this crystal, site I is the most populated; sites II’ and II are only sparsely occupied.$Ca^{2+}$+ appears to fit the octahedral site I best. No cations are found at sites III or III’, which are clearly less favorable for $Ca^{2+}$ ions in dehydrated zeolite Y.

Fabrication of High-purity Rb Vapor Cell for Electric Field Sensing

  • Jae-Keun Yoo;Deok-Young Lee;Sin Hyuk Yim;Hyun-Gue Hong;Sun Do Lim;Seung Kwan Kim;Young-Pyo Hong;No-Weon Kang;In-Ho Bae
    • Current Optics and Photonics
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    • v.7 no.2
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    • pp.207-212
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    • 2023
  • In this paper, we introduce our system for manufacturing a Rb vapor cell and describe its fabrication process in a sequence of removing impurities, cold trapping, and sealing off. Saturated absorption spectroscopy was performed to verify the quality of our cell by comparing it to that of a commercial one. By using the lab-fabricated Rb vapor cell, we observed electromagnetically induced transparency in a ladder-type system corresponding to the 5S1/2-5P3/2-28D5/2 transition of the 85Rb atom. A highly excited Rydberg atomic system was prepared using two counter-propagating external cavity diode lasers with wavelengths of 780 nm and 480 nm. We also observed the Autler-Townes splitting signal while a radio-frequency source around 100 GHz incidents into the Rydberg atomic medium.

Numerical Simulation of Piezocone Dissipation Test in Dilating Soils (과압밀점토지반의 Piezocone 소산시험에 대한 수치해석기법)

  • Park, Sung-Kun;Lim, Beyong-Seock;Lee, Woo-Jin
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.153-160
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    • 2001
  • 피에조콘관입시험(PCPT)의 소산시험은 in-situ 상태의 압밀계수(c/sub v/)를 추정하는 방법으로 널리 이용되어왔다. 본 연구에서는 spherical cavity expansion theory 및 axisymmetric uncoupled linear consolidation equation(Gupta & Davidson, 1986)을 이용하여 과압밀점토에서의 초기과잉간극수압의 분포 및 과잉간극수압의 시간에 대한 소산현상을 해석하는 수치해석방법을 제안하여 현장시험결과 및 실내시험결과와 비교 분석하였다. ADIS (alternating direction implicit scheme)를 이용한 FDM 해석을 실시한 결과와 현장시험의 소산곡선은 잘 부합되는 것으로 나타났으며 압밀계수도 실내실험 또는 피에조콘관입 시험에 대한 추정방법으로 산출된 값과 비교적 일치하는 것으로 나타났다.

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The intergrity assessment of buried pipeline (매설배관의 건전성 평가)

  • Lee, Ouk-Sub;Yin, Hai-Long
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.333-338
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    • 2001
  • The object of this work is to develop an assessment system for pipeline integrity. The system consists of four module applications for internal algorithm; the effect of corrosion in pipeline, crack, stress corrosion crack (SCC) and fatigue modules and the effect of cavity. Presently, the module of the external corrosion has been developed and the internal algorithm for the effect of corrosion in pipeline and the database of the system are described in this paper. The database of the system is separated to mainly four parts; geometry of pipeline, material properties, boundary conditions and general properties. Each components of the system are designed by user-friendly concept. This system may give a guideline for maintenance and modifications for the pipeline at the industrial sight. Furthermore, a procedure to evaluate an inspection interval is also provided.

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Frequency and Length Adjustment of A PEFP Low-Beta Dumbbell

  • Changyi, Gao;An, Sun;Liping, Zhang;Yazhe, Tang;Yingmin, Li;Kim, Han-Sung;Cho, Yong-Sub
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.2
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    • pp.27-29
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    • 2008
  • Superconducting RF cavities are being considered for accelerating a proton beam at 700 MHz in the linac of the Proton Engineering Frontier Project (PEFP) and its post-project. Dumbbell fabrication is a mid-process for manufacturing an elliptical superconducting RF cavity. During the dumbbell fabrication, control of the dumbbell length and the $TM010\;{\pi}$ mode frequencies is necessary to build up a desired cavity. A new formula with a perturbation measurement method is used to measure and calculate the frequencies of the individual half-cells of a PEFP low-beta dumbbell, and to tune the frequency and length of the half-cells. In this article, the tuning method and results of the PEFP low-beta dumbbells have been presented.

Synthesis of Fully Dehydrated Partially Cs+-exchanged Zeolite Y (FAU, Si/Al = 1.56), |Cs45Na30|[Si117Al75O384]-FAU and Its Single-crystal Structure

  • Seo, Sung-Man;Kim, Ghyung-Hwa;Lee, Seok-Hee;Bae, Jun-Seok;Lim, Woo-Taik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1285-1292
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    • 2009
  • Large single crystals of zeolite, |$Na_{75}$|[$Si_{117}Al_{75}O_{384}$]-FAU (Na-Y, Si/Al = 1.56), were synthesized from gels with composition of 3.58Si$O_2$ : 2.08NaAl$O_2$ : 7.59NaOH : 455$H_2$O : 5.06TEA : 2.23TCl. One of these, a colorless single-crystal was ion exchanged by allowing aqueous 0.02 M CsOH to flow past the crystal at 293 K for 3 days, followed by dehydration at 673 K and 1 ${\times}\;10^{-6}$ Torr for 2 days. The crystal structure of fully dehydrated partially $Cs^+$-exchanged zeolite Y, |$Cs_{45}Na_{30}$|[$Si_{117}Al_{75}O_{384}$]-FAU per unit cell (a = 24.9080(10) $\AA$) was determined by single-crystal X-ray diffraction technique in the cubic space group Fd $\overline{3}$ m at 294(1) K. The structure was refined using all intensities to the final error indices (using only the 877 reflections with $F_o\;>\;4{\sigma}(F_o))\;R_1$ = 0.0966 (Based on F) and $R_2\;=\;0.2641\;(Based\;on\;F^2$). About forty-five $Cs^+$ ions per unit cell are found at six different crystallographic sites. The 2 $Cs^+$ ions occupied at site I, at the centers of double 6-ring (D6Rs, Cs-O = 2.774(10) $\AA$ and O-Cs-O = 88.9(3) and 91.1(3)$^o$). Two $Cs^+$ ions are found at site I’ in the sodalite cavity; the $Cs^+$ ions were recessed 2.05 $\AA$ into the sodalite cavity from their 3-oxygen plane (Cs-O = 3.05(3) $\AA$ and O-Cs-O = 77.4(13)$^o$). Site-II’ positions (opposite single 6-rings in the sodalite cage) are occupied by 7 $Cs^+$ ions, each of which extends 2.04 $\AA$ into the sodalite cage from its 3-oxygen plane (Cs-O = 3.067(11) $\AA$ and O-Cs-O = 80.1(3)$^o$). The 26 $Cs^+$ ions are nearly three-quarters filled at site II in the supercage, being recessed 2.34 $\AA$ into the supercage (Cs-O = 3.273(8) $\AA$ and O-Cs-O = 74.3(3)$^o$). The 4 $Cs^+$ ions are found at site III deep in the supercage (Cs-O = 3.321(19) and 3.08(3) $\AA$), and 4 $Cs^+$ ions at another site III’ (Cs-O = 2.87(4) and 3.38(4) $\AA$). About 30 $Na^+$ ions per unit cell are found at one crystallographic site; The $Na^+$ ions are located at site I’ in the sodalite cavity opposite double 6-rings (Na-O = 2.578(11) $\AA$ and O-Na-O = 97.8(4)$^o$).

Microwave Sintering of Gd-Doped CeO2 Powder (Gd-Doped CeO2 분말의 마이크로파 소결)

  • Kim, Young-Goun;Kim, Seuk-Buom
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.182-187
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    • 2007
  • 10 mol% $Gd_{2}O_{3}-CeO_{2}$ powder was sintered by microwave in a 2.45 GHz multimode cavity to develop a dense electrolyte layer for intermediate temperature solid oxide fuel cells (IT-SOFCs). Samples were sintered from $1100^{\circ}C$ upto $1500^{\circ}C$ by $50^{\circ}C$ difference and kept for 10 min and 30 min at the maximum temperature respectively. Theoretical density of the sample sintered at $1200^{\circ}C$ for 10 min was 95.4% and increased gradually upto 99% in the sample sintered at $1500^{\circ}C$ for 30 min. All of sintered samples showed very fine microstructures and the maximum average grain size of the sintered sample at $1500^{\circ}C$ for 30 min was $(0.87{\pm}0.42){\mu}m$. Ionic conductvity of the samples were measured by DC 4 probe method.

Saturated absorption spectroscopy of 13C2H2 in the 1550 nm region (1550 nm 영역에서 아세틸렌 분자의 포화흡수분광)

  • 문한섭;이원규;서호성
    • Korean Journal of Optics and Photonics
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    • v.15 no.2
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    • pp.177-182
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    • 2004
  • We have observed the saturated absorption spectrum of the P(16) line of the V$_1$+V$_3$ band of $^{13}$ C$_2$H$_2$ molecule by using the external cavity spectroscopy method. The frequency of laser has been stabilized to the saturated absorption spectrum. The relative contrast of the saturation spectrum is about 7 % with respect to the linear absorption and the linewidth is about 1.8 MHz. The frequency fluctuation of the stabilized LD is about $\pm$20 KHz during the sampling time 100 S.