• 제목/요약/키워드: Sub- resonance

검색결과 517건 처리시간 0.023초

Structural Characteristics of 3- and 4-Coordinate Borons from 11B MAS NMR and Single-Crystal NMR in the Nonlinear Optical Material BiB3O6

  • Kim, Woo Young;Lim, Ae Ran
    • 한국자기공명학회논문지
    • /
    • 제17권1호
    • /
    • pp.24-29
    • /
    • 2013
  • The structural characteristics of 4-coordinate $BO_4$ [B(1)] and 3-coordinate $BO_3$ [B(2)] groups in $BiB_3O_6$ were studied by $^{11}B$ magic angle spinning (MAS) and single-crystal nuclear magnetic resonance (NMR) spectroscopy. The spin-lattice relaxation time in the laboratory frame, $T_1$, for $^{11}B$ decreased slowly with increasing temperature, whereas the spin-lattice relaxation times in the rotating frame, $T_{1{\rho}}$, for B(1) and B(2), which differed from $T_1$, were nearly constant. Further, $T_{1{\rho}}$ for B(1) and B(2) showed very similar trends, although the $T_{1{\rho}}$ value of B(2) was shorter than that of B(1). The 3-coordinate $BO_3$ and 4-coordinate $BO_4$ were distinguished by $^{11}B$ MAS NMR spectrum and $T_{1{\rho}}$.

Application of CRAMPS for a Phase Transition in H+-ion irradiated TlH2PO4

  • Kim, Se-Hun;Han, J.H.;Lee, Cheol-Eui;Lee, Kwang-Sei;Kim, Chang-Sam;Dalal, N.S.;Han, Doug-Young
    • 한국자기공명학회논문지
    • /
    • 제14권2호
    • /
    • pp.134-143
    • /
    • 2010
  • We studied the hydrogen-bonded $TlH_2PO_4$ (TDP) ferroelectrics treated with the proton-beam bombardment. The TDP material was irradiated with 1-MeV proton beam at a dose of $10^{15}/cm^2$. In order to analyze the hydrogen environment in TDP, we carried out the $^1H$ high resolution nuclear magnetic resonance (NMR) - i.e., Combined Rotation And Multiple Pulse Spectroscopy (CRAMPS) measurement. The isotropic chemical shift of hydrogen indicates its displacive property is related to the $PO_4$ lattice deformation which occurs throughout the antiferroelectric-, the ferroelastic- and the paraelastic-phase transitions. The temperature dependence of $\sigma_{iso}$ reveals the electronic charge redistribution is induced by the proton-beam irradiation and the elastic property.

핵자기공명분석법을 이용한 수용성 아민 CO2 흡수제인 MEA의 열적변성 분석 (Thermal Degradation of Aqueous MEA Solution for CO2 Absorption by Nuclear Magnetics Resonance)

  • 최정호;윤여일;박성열;백일현;김영은;남성찬
    • 한국수소및신에너지학회논문집
    • /
    • 제27권5호
    • /
    • pp.562-570
    • /
    • 2016
  • At the carbon dioxide capture process using the aqueous amine solution, degradation of absorbents is main factor to reducing the process performance. Also, degradation mechanism of absorbent is important for understanding the environmental risk, route of degradation products, health risk etc. In this study, the degradation products of MEA were studied to clarify mechanism in thermal degradation process. The degradation products were analyzed using a $^1H$ NMR (nuclear magnetic resonance) and $^{13}C$ NMR. The analysis methods used in this study provide guidelines that could be used to develop a degradation inhibitor of absorbent and a corrosion inhibitor.

부분적인 상태궤환과 공진비제어를 이용한 2관성계의 H제어 (H control of 2-mass system using partial state feedback and resonance ratio control)

  • 김진수;유상봉
    • 조명전기설비학회논문지
    • /
    • 제17권4호
    • /
    • pp.36-44
    • /
    • 2003
  • 전동기와 부하가 강성이 작은 축으로 연결되는 산업용 전동기 구동시스템에 있어서 전동기의 관성과 부하의 관성에 의해 축에 비틀림 진동이 발생한다. 이러한 문제를 해결하기 위하여 기존에 2자유도 H$_{\infty}$제어기가 제안되었다. 그러나 이 제어기는 구현하는데 어려움이 있다. 본 논문에서는 부분적인 상태궤환과 공진비제어를 이용한 2관성계의 H$_{\infty}$제어가 제안되었다. 제안된 제어기는 간단하면서도 외란 및 진동억제 성능을 만족한다.어기는 간단하면서도 외란 및 진동억제 성능을 만족한다.

Contribution of Microbleeds on Microvascular Magnetic Resonance Imaging Signal

  • Chang Hyun Yoo;Junghwan Goh;Geon-Ho Jahng
    • 한국의학물리학회지:의학물리
    • /
    • 제33권4호
    • /
    • pp.88-100
    • /
    • 2022
  • Purpose: Cerebral microbleeds are more susceptible than surrounding tissues and have been associated with a variety of neurological and neurodegenerative disorders that are indicative of an underlying vascular pathology. We investigated relaxivity changes and microvascular indices in the presence of microbleeds in an imaging voxel by evaluating those before and after contrast agent injection. Methods: Monte Carlo simulations were run with a variety of conditions, including different magnetic field strengths (B0), different echo times, and different contrast agents. ΔR2* and ΔR2 and microvascular indices were calculated with varying microvascular vessel sizes and microbleed loads. Results: As B0 and the concentration of microbleeds increased, 𝜟R2* and 𝜟R2 increased. 𝜟R2* increased, but 𝜟R2 decreased slightly as the vessel radius increased. When the vessel radius was increased, the vessel size index (VSI) and mean vessel diameter (mVD) increased, and all other microvascular indices except mean vessel density (Q) increased when the concentration of microbleeds was increased. Conclusions: Because patients with neurodegenerative diseases often have microbleeds in their brains and VSI and mVD increase with increasing microbleeds, microbleeds can be altered microvascular signals in a voxel in the brain of a neurodegenerative disease at 3T magnetic resonance imaging.

Ag@Fe3O4 코어-쉘 나노입자의 광학적 특성 (Optical Properties of Ag@Fe3O4 Core-Shell Nanoparticles)

  • 송윤성;고광락;김규정;이재범
    • 한국광학회지
    • /
    • 제28권3호
    • /
    • pp.97-102
    • /
    • 2017
  • 본 논문에서는 플라즈모닉 코어와 자성 쉘로 구성된 $Ag@Fe_3O_4$ 나노입자의 흥미로운 광학적 특성에 대해 연구를 하였다. 기존의 60 nm의 지름을 갖는 은 나노입자의 표면에 높은 굴절률을 갖는 $Fe_3O_4$ 쉘이 형성됨에 따라 국소 표면 플라즈몬 공명(Localized surface plasmon resonance; LSPR) 파장이 420 nm에서 650 nm로 이동하는 red-shift 현상을 관찰 할 수 있었고, 또한, 세 가지 시뮬레이션 모델들 ($Ag@Fe_3O_4$ 나노입자, $Fe_3O_4$ 쉘 나노입자, 은 나노입자)을 통해서 410 nm 파장의 peak이 60 nm의 두께를 가진 $Fe_3O_4$ 쉘에 의해 발생하는 산란이 주된 원인이라는 것을 규명하였다. 이 결과는 비슷한 종류의 나노입자를 이용한 추후 다양하고 복잡한 나노어셈블리의 광학적 현상을 이해하는데 사용될 것이다.

Magnetic Properties of Cr-doped LiNbO3 by Using the Projection Operator Technique

  • Park, Jung-Il;Lee, Hyeong-Rag;Lee, Haeng-Ki
    • Journal of Magnetics
    • /
    • 제16권2호
    • /
    • pp.108-113
    • /
    • 2011
  • The electron spin resonance lineshape (ESRLS) function for the electron spin resonance linewidth (ESRLW) of $Cr^{3+}$ (S = 3/2) in ferroelectric lithium niobate single crystals doped with 0.05 wt% of Cr, is obtained by using the projection operator technique (POT), developed by Argyres and Sigel. The ESRLS function is calculated to be axially symmetric about the c - axis and analyzed by using the spin Hamiltonian $H_{SP}={\mu}_B(B{\cdot}{^\leftrightarrow_{g}}{\cdot}S)+S{\cdot}{^\leftrightarrow_{D}}{\cdot}S$ with the parameters g = 1.972 and D = $0.395\;cm^{-1}$. In the ca plane, the linewidths show a strong angular dependence, whereas in the ab plane, they are independent of the angle. This result implies that the resonance center has an axial symmetry along the c - axis. Further, from the temperature dependence of the linewidths that is shown, it can be seen that the linewidths increase as the temperature increases, at a frequency of v = 9.27GHz. This result implies that the scattering effect increases with increasing temperature. Thus, the POT is considered to be more convenient to explain the scattering mechanism as in the case of other optical resonant systems.

Prototype Electromagnetic-Noise Filters Incorporated with Nano-Granular Co41Fe38Al13O8 Soft Ferromagnetic Thin Films on Coplanar Transmission Lines

  • Sohn, Jae-Cheon;Byun, Dong-Jin
    • 한국세라믹학회지
    • /
    • 제43권2호
    • /
    • pp.74-78
    • /
    • 2006
  • A non-integrated type noise filter on a Coplanar Waveguide (CPW) transmission line is demonstrated by using a highly resistive $Co_{41}Fe_{38}Al_{13}O_8$ nanogranular thin film with the dimensions of $4\;mm (\iota)\times4\;mm(\omega)\times0.1\;{\mu}m(t)$. The noise suppression characteristics are evaluated without placing an insulating layer between the CPW line and the magnetic thin film. The insertion loss is very low being less than 0.3 dB and this low value is maintained up to 2 GHz. At a ferromagnetic resonance frequency of 3.3 GHz, the power loss is very large and the degree of noise attenuation is measured to be 3 dB. This level of noise attenuation is still small for real applications; however, considering the small magnetic volume used in this work, further improvement is expected by simply increasing the magnetic volume and by integrating the magnetic thin film into the CPW transmission line.