• Journal of Magnetics
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• v.9 no.1
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• pp.1-4
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• 2004

Three successive phase transitions in bis-n-octhylammonium hexachlorostannate, $(n-C_8H_{17}NH_3)_2SnCl_6$, were studied by means of the ^1H nuclear magnetic resonance linewidth and spin-lattice relaxation measurements. Unlike the compounds with longer hydrocarbon chains, the order-disorder and conformational nature were found to coexist in the phase transitions.

• Journal of the Korean Magnetic Resonance Society
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• v.23 no.2
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• pp.40-45
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• 2019

The phase transition temperatures and thermodynamic properties of $(NH_4)_2MnCl_4{\cdot}2H_2O$ grown by the slow evaporation method were studied using differential scanning calorimetry and thermogravimetric analysis. A structural phase transition occurred at temperature $T_{C1}$ (=264 K), whereas the changes at $T_{C2}$ (=460 K) and $T_{C3}$ (=475 K) seemed to be chemical changes caused by thermal decomposition. In addition, the chemical shift and the spin-lattice relaxation time $T_{1{\rho}}$ were investigated using $^1H$ magic-angle spinning nuclear magnetic resonance (MAS NMR), in order to understand the role of $NH_4{^+}$ and $H_2O$. The rise in $T_{1{\rho}}$ with temperature was related to variations in the symmetry of the surrounding $H_2O$ and $NH_4{^+}$.

• Journal of the Korean Magnetic Resonance Society
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• v.20 no.1
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• pp.1-6
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• 2016

The proton NMR line widths and spin-lattice relaxation rates, $T_1^{-1}$, of ferroelectric $LiH_3(SeO_3)_2$, $Li_2SO_4{\cdot}H_2O$, and $LiN_2H_5SO_4$ single crystals were measured as a function of temperature. The line width measurements reveal rigid lattice behavior of all the crystals at low temperatures and line narrowing due to molecular motion at higher temperatures. The temperature dependences of the proton $T_1^{-1}$ for these crystals exhibit maxima, which are attributed to the effects of molecular motion by the Bloembergen - Purcell - Pound theory. The activation energies for the molecular motions of $^1H$ in these crystals were obtained. From these analysis, $^1H$ in $LiH_3(SeO_3)_2$ undergoes molecular motion more easily than $^1H$ in $LiN_2H_5SO_4$ and $Li_2SO_4{\cdot}H_2O$ crystals.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1998.04a
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• pp.160-165
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• 1998

The sub-resonance modes can be easily excited by the assembling tolerance in the asymmetric type optical pick-up actuators, compared with the symmetric type. In this paper, we propose the novel method for reducing the vibration due to the sub-resonance modes where undesirable modes can be decreased by adding the damping, which can be achieved by increasing the flexibility of holder PCB, against to the sub-resonance modes. Using the finite element method, the change of mode shapes is investigated as the shape of holder PCB is modified. Experimental results support that the proposed method reduces remarkably the vibration of sub-resonance modes of the optical pick-up actuator.

• Journal of KSNVE
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• v.8 no.4
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• pp.643-653
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• 1998

The sub-resonance modes can be easily excited by the assembling tolerance in the asymmetric type optical pick-up actuators, compared with the symmetric type. In this paper, we propose the novel method for reducing the vibration due to the sub-resonance modes whose amplitude can be decreased by adding the damper and increasing the flexibility of holder PCB. Using the finite element method, the change of mode shapes is investigated as the shape of holder PCB is modified. Experimental results support that the propopsed method reduces remarkably the vibration of sub-resonance modes of the optical pick-up actuator.

• Journal of the Korean Magnetic Resonance Society
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• v.24 no.1
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• pp.16-22
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• 2020

Based on quantum transport theory, we investigated theoretically the magnetic field dependence of the quantum optical transition of quasi 2-dimensional Landau splitting system, in CdS and ZnO Through the analysis of the current work, we found the increasing properties of the cyclotron resonance line-profiles (CRLPs) which show the absorption power and the cyclotron resonance line-widths (CRLWs) with the magnetic field in CdS and ZnO We also found that that CRLWs, γ_total(B) of CdS < γ_total(B) of ZnO in the magnetic field region B < 15 Tesla.

• Korean Journal of Materials Research
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• v.21 no.7
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• pp.403-409
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• 2011

Micro speakers are used to reproduce sound in small electric and information and communications devices, such as cellular phones, PMPs, and MP3 players. The acoustical properties and sound quality, which are changed due to the decreased size of the speaker, are often adjusted varying the type and thickness of the diaphragm. The most widely used diaphragm material is thin polymer. It was previously reported by the author of this paper that the resonance frequency of a micro speaker is changed by the type and thickness of a polymer diaphragm. In this paper, the frequency response near the resonance frequency of a micro speaker was studied as functions of the type and thickness of the polymer diaphragm. While $R_{max}$ and $R_{DC}$ were affected by the type and thickness, an analysis of the electrical impedance curve revealed that $R_o(= R_{max}/R_{DC})$ and ${\Delta}f$ were not changed. Thus, $Q_{TS}$ which was function of $R_o$, ${\Delta}f$, and the resonance frequency, is only related to the resonance frequency. The increase of the resonance frequency led to a proportional rise of $Q_{TS}$. The change of the frequency response near the resonance frequency was not dependent on the type or thickness of the polymer diaphragm, but was affected by the resonance frequency.

• Journal of the Korean Magnetic Resonance Society
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• v.14 no.2
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• pp.76-87
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• 2010

The structural phase transition of $Cs_2MnCl_4{\cdot}2H_2O$ single crystals was investigated by determining the $^{133}Cs$ spin-lattice relaxation time $T_1$. The number of resonance lines in the $^{133}Cs$ spectrum changes from seven to one near 375 K, which means that above 375 K the Cs sites are symmetric. Further, the $T_1$ of the $^{133}Cs$ nucleus undergoes a significant change near 375 K, which coincides with the change in the splitting of the $^{133}Cs$ resonance lines. The change in $T_1$ near $T_C$ is related to the loss of $H_2O$, and means that the forms of the octahedra of water molecules surrounding $Cs^+$ are disrupted.

• Journal of the Korean Magnetic Resonance Society
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• v.26 no.1
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• pp.10-16
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• 2022

The phase transition temperatures of CsCoCl₃·2H₂O crystals are investigated via differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Three endothermic peaks at temperatures of 370 K (=T_C1), 390 K (=T_C2), and 416 K (=T_C3) were observed for phase transitions from CsCoCl₃·2H₂O to CsCoCl₃·1.5H₂O, to CsCoCl₃·H₂O, and then to CsCoCl₃·0.5H₂O, respectively. In addition, the spin-lattice relaxation time T_1ρ in the rotating frame and T₁ in the laboratory frame as well as changes in chemical shifts for ¹H and ¹³³Cs near T_C1 were found to be temperature dependent. Our analyses results indicated that the changes of chemical shifts, T_1ρ, and T₁ are associated with structural phase transitions near temperature T_C1. The changes of chemical shifts, T_1ρ, and T₁ near T_C1 were associated with structural phase transitions, owing to the changes in the symmetry of the structure formed of H₂O and Cs⁺ ions. Consequently, the structural symmetry in CsCoCl₃·2H₂O crystals based on temperature is discussed by the environments of their H and Cs nuclei.

• Journal of the Korean Magnetic Resonance Society
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• v.21 no.2
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• pp.63-66
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• 2017

The $^{14}N$ NMR spectra for $(NH_4)_2SO_4$ crystals were obtained near the phase transition temperature $T_C=223K$, and were found to precisely reflect the symmetry change in the crystal at this first-order phase transition. Changes in the resonance frequencies near $T_C$ were attributed to the structural phase transition. In the ferroelectric and paraelectric phases, two inequivalent NH4 groups were distinguished in the $^{14}N$ NMR spectra. The two types, $NH_4$(1) and $NH_4$(2), have slightly different local environments. Consequently, we conclude that the phase transition is caused by the change in the environment of the $^{14}N$ nuclei in the $NH_4$ groups, rather than by the $SO_4$ groups.