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Effect of Al2O3 on Crystallization Behavior and Microstructure of Na2O-CaO-P2O5-SiO2 Glass-ceramic System

  • Mirhadi, Bahman;Mehdikhani, Behzad
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.146-150
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    • 2012
  • The effects of $Al_2O_3$ on the crystallization behavior of glass compositions in the $Na_2O$-CaO-$SiO_2$ system were investigated by differential thermal analysis (DTA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The effect of $Al_2O_3$ content on the mechanical properties, density, phase formation, and microstructures of $Na_2O$-CaO-$P_2O_5$-$SiO_2$ glass ceramics were studied. The thermal parameters of each glass were studied by DTA. The density of the glass ceramic samples was measured by Archimedes' method. It was found that the glass-ceramic containing 2.0 molar percent $Al_2O_3$ had desirable sintering behavior and reached an acceptable density. Phase investigation and micro-structural analysis were performed by XRD and SEM, respectively.

Studies on Incombustibility Improvement of EPDM-based Insulation with Al(OH)3 and Sb2O3 (EPDM계 내열재의 Al(OH)3와 Sb2O3 함량에 따른 난연 효과 연구)

  • Kim, Jinyong;Lim, Daehyun;Lee, Wonbok
    • Journal of Aerospace System Engineering
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    • v.7 no.4
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    • pp.36-41
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    • 2013
  • In order to improve incombustibility of EPDM(Ethylene propylene diene monomer)-based rubber, inorganic materials as $Al(OH)_3$ and $Sb_2O_3$ were added. The mechanical and thermal properties have been measured for vulcanized rubber loaded with different concentrations of $Al(OH)_3$ and $Sb_2O_3$. As inorganic material contents increases from 5phr to 30phr, the specific gravity and hardness increase while elongation at break decreases. This study performed incombustibility test and thermal analysis through TGA(Thermogravimetric Analyzer). As a results, incombustible and thermal properties of EPDM-based rubber were improved as $Al(OH)_3$ and $Sb_2O_3$ contents increase.

Refractive Indices and Densities of B2O3-Al2O3-SiO2 Glass System for Photosensitive Barrier Ribs of Plasma Display Panel (플라즈마 디스플레이 패널의 감광성 격벽을 위한 B2O3-Al2O3-SiO2 유리계의 굴절률과 밀도)

  • Won, Ju-Yeon;Hwang, Seong-Jin;Lee, Sang-Ho;Kim, Hyung-Sun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.506-511
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    • 2009
  • For the application of the photosensitive barrier ribs with optimal properties such as glass transition temperature, refractive index and coefficient thermal expansion, the boro-silicate glasses was studied. The glass transition temperature, coefficient thermal expansion, and refractive index of the glasses based on the $B_2O_3-Al_2O_3-Al_2O_3-SiO_2$ glass system have been investigated with the different ratio of BaO/$Na_2O$ and $B_2O_3/Na_2O$. Increasing the ratio of $B_2O_3/Na_2O$ was led to the increase of coefficient thermal expansion and the decrease of glass transition temperature. The increase of refractive index of boro-silicate glasses increased with the density of glasses. We suggest the empirical equation for the prediction of refractive index with the glass density, $n=0.123{\rho}+1.182$ with 0.042 as the standard deviation in the boro-silicate glass system. The aim of the present paper is to give a basic result of the thermal and optical properties for designing the composition of photosensitive barrier ribs in PDP.

Physical and Chemical Properties of Chlorine Bypass System-Dust from Cement Manufacturing (시멘트 생산 시 발생하는 Chlorine Bypass System-dust의 물리 및 화학적 특성)

  • Han, Min-Cheol;Lee, Dong-Joo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.310-315
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    • 2019
  • This study conducted a series of studies to find alternative ways to use Chlorine Bypass System-dust(CBS-dust) in cement production. The results of engineering characteristics of CBS-dust are summarized as follows. First of all, the density of CBS-dust is 2.40, lighter than cement and the pH was 12.50 which was strong alkaline. In terms of particle size, it was 11.70 ㎛ which was finer than cement. With chemical properties, calcium oxide(CaO) was the highest as 35.10%, potassium oxide(K2O) was 32.43%, potassium chloride(KCl) was 19.46%, sulfur oxide(SO3) was 6.81%, and the remaining chemical components are SiO2, Fe2O3, Al2O3, MgO, and the like. Therefore, if CBS-dust is used as early-strength chemical admixtures in the concrete secondary products that use a large amount of mineral admixtures without rebar, it can be an effective method for increasing the strength of concrete as an alkali activator and preventing early-frost damage of Cold Weather Concrete.

Experimental Evaluation of Developed Ultra-low NOx Coal Burner Using Gas in a Bench-scale Single Burner Furnace (Bench-scale 연소로에서 가스 혼소를 통한 초 저 NOx 석탄 버너 개발 연구)

  • Chae, Taeyoung;Lee, Jaewook;Lee, Youngjae;Yang, Won
    • Clean Technology
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    • v.28 no.2
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    • pp.117-122
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    • 2022
  • This study developed and tested an ultra-low NOx burner in an 80 kW combustion furnace. The experiment was conducted in an 80 kW single burner combustion furnace with changing the swirl numbers, total equivalence ratios, and primary/secondary oxidizer ratios. In this study, liquefied natural gas (LNG) was used as an auxiliary fuel to significantly reduce NOx production. In a thermal power plant, the amount of NOx generated during coal combustion is about 300 ppm. However, using the burner tested in this study, it was possible to reduce the amount of NOx generated via LNG co-firing to 40 ppm. If the input amount of the primary oxidizer is enough for the gas to be completely combusted and the gas and coal are added simultaneously, the combusted gas forms a high-temperature region at the burner outlet and volatilizes the coal. As a result, the N contained in the devolatilized coal is discharged. Therefore, when the coal is subsequently burned, the amount of NOx produced decreases because there is almost no N remaining in the coal. If a thermal power plant burner is developed based on the results of this study, it is expected that the NOx generation will be significantly lower in the early stage of combustion.

Hybrid Double Direction Blocking Sub-Module for MMC-HVDC Design and Control

  • Zhang, Jianpo;Cui, Diqiong;Tian, Xincheng;Zhao, Chengyong
    • Journal of Power Electronics
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    • v.19 no.6
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    • pp.1486-1495
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    • 2019
  • Dealing with the DC link fault poses a technical problem for an HVDC based on a modular multilevel converter. The fault suppressing mechanisms of several sub-module topologies with DC fault current blocking capacity are examined in this paper. An improved half-bridge sub-module topology with double direction control switch is also designed to address the additional power consumption problem, and a sub-module topology called hybrid double direction blocking sub module (HDDBSM) is proposed. The DC fault suppression characteristics and sub-module capacitor voltage balance problem is also analyzed, and a self-startup method is designed according to the number of capacitors. The simulation model in PSCAD/EMTDC is built to verify the self-startup process and the DC link fault suppression features.

Design of Cooling System for Thermochemical CO2 Methanation Isothermal Reactor (열화학적 CO2 메탄화 등온반응기의 수순환 냉각시스템 설계)

  • LEE, HYUNGYU;KIM, SU HYUN;YOO, YOUNGDON
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.451-461
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    • 2022
  • CFD analysis including optimization process was conducted to design shell and tube CO2 methanation reactor cooling system. The high-pressure saturated water flowed into the cooling system and was evaporated by heat flux from reacting tubes. The optimization process decided the gap between tubes and reactor diameter to satisfy objective functions related to temperature. The results showed that the gap and diameter reduced about 30% and 3.6% respectively. Averaged surface temperature satisfied the target value and the min-max deviation was minimized.

Low Temperature Sintering of B2O3 -added (Zn0.8Mg0.2)TiO3 Microwave Dielectric Ceramics (B2O3 가 첨가된 (Zn0.8Mg0.2)TiO3 마이크로파 유전체 세라믹스의 저온소결)

  • Bang, Jae-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.1
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    • pp.29-34
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    • 2006
  • The effects of $B_2O_3$ addition on the low-temperature sintering behavior and microwave dielectric properties of $(Zn_{0.8}Mg_{0.2})TiO_3$ ceramic system were investigated. Highly dense samples were obtained at the sintering temperatures below $900^{\circ}C$. The $Q{\times}f_o$ values were determined by the microstructures and sintering shrinkages which are affected by the amount of $B_2O_3$ and sintering temperature. Temperature coefficient of resonance frequency($T_f$) changes to a positive value with increasing the amount of $B_2O_3$ due to the increased amount of rutile phase which is one of the reaction products between $(Zn_{0.8}Mg_{0.2})TiO_3$ and $B_2O_3$. For $6.19 moi.{\%}B_2O_3$-added $(Zn_{0.8}Mg_{0.2})TiO_3$ system, it exhibits ${\epsilon}_r$ = 23.5, $Q{\times}f_o$ = 53,000 GHz, and $T_f$ = 0 ppm/$^{\circ}C$ when sintered at $900^{\circ}C$ for 5 h.

Sticking Characteristics in Bi2Sr2CanCun+1Ox Thin Films Fabricated by using the Evaporation Method to Improve the Sticking Ratio (부착율 개선을 위해 증발 법으로 제작한 Bi2Sr2CanCun+1Ox 박막의 부착 특성)

  • 천민우;박용필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.11
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    • pp.1029-1034
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    • 2003
  • The Bi$_2$Sr$_2$Ca$_{n}$Cu$_{n+1}$ O$_{x}$, superconducting thin films arc fabricated by using the sputtering and evaporation method. Because we confirmed the sticking ratio of Bi element in the Bi$_2$Sr$_2$Ca$_{n}$Cu$_{n+1}$ O$_{x}$ superconducting thin film fabricated by using the sputtering method was much lower than the expected value, to get the enough number of the flakes of Bi, faraday cup was used to evaporate Bi clement. As a result of the fabrication, Bi 2201 and Bi 2212 single phases could be made by the optima of deposition condition. And we confirmed the sticking coefficient of Bi element was clearly related to the temperature change of the substrate and the generation of Bi22l2 phase

Behavior of Ag+ and Sn2+ After Reaction Between the Transparent Dielectric PbO-B2O3-SiO2-Al2O3 and Ag Electrodes (투명 유전체 (PbO-B2O3-SiO2-Al2O3 계)와 Ag 전극과의 반응에 의한 Ag+과 Sn2+의 거동)

  • Hong, Gyeong-Jun;Park, Jun-Hyeon;Heo, Jeung-Su;Kim, Hyeong-Jun
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.347-352
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    • 2002
  • A transparent dielectric of the $PbO-B_2O_3-SiO_2-A1_2O_3$ system which was a low melting glass has been used for PDP (Plasma Display Panel), but it has a problem which is a reaction to be occurred between a transparent dielectric layer and electrodes (Ag, ITO) after firing. This research was conducted for ion migration of $Ag^+\$ and $Sn^ {2+}$ during firing three different frits of low melting glass. The result showed that yellowing phenomena occurred through a chemical reaction between $Ag^+\$and $Sn^ {2+}$ at 550~58$0^{\circ}C$ for 20~60 min. In addition, it was confirmed that the migration of $Sn^{2+}$ from ITO electrode made a strong effect on the yellowing phenomena.