• Title/Summary/Keyword: Structure Modification

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Surface Modification of Screen-Mesh Wicks to Improve Capillary Performance for Heat Pipes (히트파이프 모세관 성능 개선을 위한 스크린-메쉬 윅의 표면 개질)

  • Jeong, Jiyun;Lim, Hyewon;Kim, Hyewon;Lee, Sangmin;Kim, Hyungmo
    • Tribology and Lubricants
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    • v.38 no.5
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    • pp.185-190
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    • 2022
  • Among the operating limits of a heat pipe, the capillary limit is significantly affected by the characteristics of the wick, which is determined by the capillary performance. The major parameters for determining capillary performance are the maximum capillary pressure and the spreading characteristics that can be expected through the wick. A well-designed wick structure improves capillary performance and helps improve the stability of the heat pipe by enhancing the capillary limit. The capillary performance can be improved by forming a porous microstructure on the surface of the wick structure through surface modification techniques. In this study, a microstructure is formed on the surface of the wick by using a surface modification method (i.e., an electrochemical etching process). In the experiment, specimens are prepared using stainless-steel screen mesh wicks with various fabrication conditions. In addition, the spreading and capillary rise performances are observed with low-surface-tension fluid to quantify the capillary performance. In the experiments, the capillary performance, such as spreading characteristics, maximum capillary pressure, and capillary rise rate, improves in the specimens with microstructures formed through surface modification compared with the specimens without microstructures on the surface. The improved capillary performance can have a positive effect on the capillary limit of the heat pipe. It is believed that the surface microstructures can enhance the operational stability of heat pipes.

Electrosorption of U(IV) by Electochemically Modified Activated Carbon Fibers

  • Jung, Chong-Hun;Oh, Won-Zin;Lee, Yu-Ri;Park, Soo-Jin
    • Carbon letters
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    • v.6 no.1
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    • pp.25-30
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    • 2005
  • The electrosorption of U(VI) from waste water was carried out by using an activated carbon fiber (ACF) felt electrode in a continuous electrosorption cell. In order to enhance the electrosorption capacity at a lower potential, the ACF was electrochemically modified in an acidic and a basic solution. Pore structure and functional groups of the electrochemically modified ACF were examined, and the effects of the modification conditions were studied for the adsorption of U(VI). Specific surface area of all the ACFs was decreased by this modification. The amount of the acidic functional groups decreased with a basic modification, while the amount increased a lot with an acidic modification. The electrosorption capacity of U(VI) decreased on the acid modified electrode due to the shielding effect of the acidic functional groups. The base modified electrode enhanced the capacity due to a reduction of the acidic functional groups. The electrosorption amount of U(VI) on the base modified electrode at .0.3 V corresponds to that of the as-received ACF electrode at .0.9 V. Such a good adsorption capacity was due to a reduction of the shielding effect and an increase of the hydroxyl ions in the electric double layer on the ACF surface by the application of negative potential.

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Enhanced Electrochemical Properties of All-Solid-State Batteries Using a Surface-Modified LiNi0.6Co0.2Mn0.2O2 Cathode

  • Lim, Chung Bum;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.411-420
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    • 2020
  • Undesirable interfacial reactions between the cathode and sulfide electrolyte deteriorate the electrochemical performance of all-solid-state cells based on sulfides, presenting a major challenge. Surface modification of cathodes using stable materials has been used as a method for reducing interfacial reactions. In this work, a precursor-based surface modification method using Zr and Mo was applied to a LiNi0.6Co0.2Mn0.2O2 cathode to enhance the interfacial stability between the cathode and sulfide electrolyte. The source ions (Zr and Mo) coated on the precursor-surface diffused into the structure during the heating process, and influenced the structural parameters. This indicated that the coating ions acted as dopants. They also formed a homogenous coating layer, which are expected to be layers of Li-Zr-O or Li-Mo-O, on the surface of the cathode. The composite electrodes containing the surface-modified LiNi0.6Co0.2Mn0.2O2 powders exhibited enhanced electrochemical properties. The impedance value of the cells and the formation of undesirable reaction products on the electrodes were also decreased due to surface modification. These results indicate that the precursor-based surface modification using Zr and Mo is an effective method for suppressing side reactions at the cathode/sulfide electrolyte interface.

A Study on the Ultrasonic Nano Crystal Surface Modification(UNSM) Technology and It's Application (초음파 나노표면개질기술의 특성과 활용방안 연구)

  • Pyoun, Young-Sik;Park, Jeong-Hyeon;Cho, In-Ho;Kim, Chang-Sik;Suh, Chang-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.3
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    • pp.190-195
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    • 2009
  • All the failure in fatigue of torsion, bending and rolling contact, and in sliding wear begins mostly from surface. So much efforts have been invested to the surface technology which deal these problems during past decades, but the industrial demand keeps growing and more significant requirements are added to researchers and engineers. Nano crystal surface modification technology which makes the surface layers into nano crystalline, induces big and deep compressive residual stress, increases surface hardness, improves surface hardness, and make micro dimples structure on surface is an emerging technology which can break limits of current surface technology and relieve the burden of researchers and engineers. In this study, a nano crystal surface modification technology which is calling UNSM(Ultrasonic nano crystal surface modification) technology, is introduced and how it has been applied to industry to solve these failure problems is explained.

Verification of Structural Dynamics Modification Using Surface Grooving Technique : Using Optimization with Fully Embossed HDD cover model (극한값으로부터의 최적화를 이용한 그루브를 통한 표면형상변형 동특성 변경법 검증)

  • Park, Mi-You;Sung, Rock-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.1
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    • pp.19-24
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    • 2009
  • Structural Dynamics Modification (SDM) is a very effective technique to improve structure's dynamic characteristics by adding or removing auxiliary structures, changing material properties and shape of structure. Among those of SDM technique, the method to change shape of structure has been mostly relied on engineer's experience and trial-and-error process which are very time consuming. In order to develop a systematic method to change structure shape, surface grooving technique is studied and successfully applied to HDD cover model. To verify Surface Grooving Technique, fully embossed HDD cover model was optimized. And comparing with previous optimization result, the effectiveness of this surface grooving technique was checked. The shape of groove and 1 st natural frequency were converged to the same result of previous optimization.

ON SOME PROPERTIES OF PRETOPOLOGICAL CONVERGENCE STRUCTURES

  • Park, Sang-Ho;Kang, Myeong-Jo
    • East Asian mathematical journal
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    • v.17 no.1
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    • pp.47-56
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    • 2001
  • In this paper we introduce generalized q-interior operator and n-th pretopological modification of q. Furthermore we establish a characterization of ${\pi}_n(q)=\lambda(q)$.

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Surface Modification of PET Irradiated by Ultra-Violet (Part I) -Transformation of Chemical Structure and Surface Properties- (UV조사를 통한 PET의 표면개질 (제1보) -화학구조 변화 및 표면특성 변화-)

  • Choi Hae Young;Lee Jung Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.3_4 s.141
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    • pp.561-568
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    • 2005
  • The irradiation of Ultra-Violet (UV) is an efficient treatment for polymer to improve hydrophilic properties. 4-Channel PET knit fabrics were treated with UVA and UVC to develop functional and environment-friendly fabric. The fabric was treated with various treatment times and distances from UV lamps having different wavelength. FT-IR and XPS investigated the chemical changes. To confirm the change of surface properties, contact angle, surface energy and SEM were examined. The study of UV as a treatment for PET knit fabric shows significant changes in chemical and surface properties, which is proved by analyses. FT-IR and XPS analyses prove the augmentation of carboxylic, Hydrophilic groups on the surfaces treated by UV. The increase of water contact angle and surface energy means more water wettable and surface energy of PET film was substantially increased by UV irradiation time. The ageing after surface treatment had little influence on the surface energy of the irradiated PET film. SEM proves the surface modification of PET such as etching, bubble and crack. The negative effects are increased in accordance with increasing treatment time.

Improvement of Solar Cell Efficiency by Modification of Cellulose Acetate Propionate for Ag paste (전극용 Ag Paste의 Cellulose Acetate Propionate(CAP) 개질에 따른 태양전지 효율 향상)

  • Kim, Dong Min;Lim, Jong Chan;Kim, Jin Hyun;Cha, Sang-Ho;Lee, Jong-Chan
    • Korean Journal of Materials Research
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    • v.28 no.4
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    • pp.227-234
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    • 2018
  • We investigate the effect of the modification of cellulose acetate propionate as an organic vehicle for silver paste on solar cell efficiency. For the modification of cellulose acetate propionate, poly(ethylene glycol) is introduced to the hydroxyl groups of a cellulose acetate propionate backbone via esterification reaction. The chemical structure and composition of poly(ethylene glycol) functionalized cellulose acetate propionate is characterized by Attenuated total reflectance Fourier transform infrared, $^1H$ nuclear magnetic resonance, differential scanning calorimetry and thermogravimetric analysis. Due to the effect of structural change for poly(ethylene glycol) functionalized cellulose acetate propionate on the viscosity of silver paste, the solar cell efficiency increases from 18.524 % to 18.652 %. In addition, when ethylene carbonate, which has a structure similar to poly(ethylene glycol), is introduced to cellulose acetate propionate via ring opening polymerization, we find that the efficiency of the solar cell increases from 18.524 % to 18.622 %.