• Title/Summary/Keyword: Structural effect

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The Role of Acid in the Synthesis of Red-Emitting Carbon Dots (장파장 형광 탄소 양자점 제조에 있어서 산의 역할에 대한 연구)

  • Yun, Sohee;Lee, Jinhee;Choi, Jin-sil
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.309-314
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    • 2022
  • Carbon dots (CDs) are few nanometer-sized carbon-based nanoparticles and emerging candidate materials in various fields such as biosensors and bioimaging due to their excellent optical properties and high biocompatibility. However, most CDs, emitting blue light, have limited their application in biomedical fields due to the low penetration of short-wavelength lights into the biological system. Therefore, there has been enormous need to develop long-wavelength emitting CDs. In this study, red-emitting CDs were successfully synthesized through the hydrothermal reaction of p-phenylenediamine with hydrochloric acid. In addition, the effect of the amount of hydrochloric acid on the formation of carbon dots, resulting in the variation of the chemical structures of CDs, were investigated, which was confirmed with the intensive structural analyses using infrared and X-ray photoelectron spectroscopy. It was found that the chemical structure of CDs governed their optical properties and quantum yield. Therefore, this study provides an insight into the role of acid in forming red-emitting CDs as the optimal probe for biomedical application.

Effect of Zephyr Producing Method on Properties of Bamboo Zephyr Boards (대나무 Zephyr의 제조 조건에 따른 보드의 물성비교)

  • Kim, Yu-Jung;Roh, Jeang-Kwan;Park, Sang-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.4
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    • pp.24-30
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    • 2003
  • In order to develop structural 'bamboo zephyr board', properties of boards produced by various methods making zephyr were estimated. All of boards were tested with KS(Korean Standards) F 3014 Particle board, and results were summarized as follow. The zephyr boards produced by final 1.5 mm roller space had the best properties(MOR, MOE and IB strength) among boards produced by different final roller space. Also, they had the best properties(MOR and MOE) in bending test after 1 hour soaking treatment after 2 hour-boiling in water, which were similar to properties of boards in dry-condition. Thickness swelling(TS) of all boards was less than 12% required to the Korean Standards A 3014. Zephyr boards produced by final 1.5 mm roller space also had the lowest values among all of boards. Boards produced by non-treatment (in green condition) had the better strength than those of boards produced by different pre-treatment methods(boiling in water and in 0.3% NaOH) in bending test.

A study on the Influence of Enterprise Content Management System Success Factors and Task Characteristics on Intention to Use (기업콘텐츠관리시스템 성공 요인과 업무적 특성이 시스템 사용 의도에 미치는 영향)

  • Hwang, Inho
    • The Journal of the Korea Contents Association
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    • v.21 no.11
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    • pp.333-349
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    • 2021
  • As information is recognized as an important asset of an organization, organizations are increasing their resource input for knowledge management. In particular, the enterprise content management system(ECMS) is a solution for organization-oriented content management, and it has high utility by helping to achieve business performance through systematic utilization of content and improve the level of internal information security. The purpose of this study is to suggest a plan to improve the intention to use organizational employee's ECMS and to suggest the effect of the relationships between information system quality characteristics and work environment characteristics on intention to use. In this study, a research hypothesis was presented based on previous studies, a questionnaire was conducted on workers of organizations that adopted an ECMS, and the hypothesis was verified by applying structural equation modeling. As a result of the analysis, information and service quality of the ECMS and task interdependence increased the intention to use, but task conflict decreased the intention to use. In addition, task interdependence and task conflict moderated the positive relationship between the quality factors of the ECMS and the intention to use it. This study has implications in terms of suggesting the direction of the organization's behavior through factors that increase the use of ECMS.

Fatigue Behavior of Composites with different Fiber Orientation (섬유 방향에 따른 복합재 피로특성에 관한 연구)

  • Kang, Tae-Young;An, Hyo-Seong;Chun, Heoung-Jae;Park, Jong-Chan
    • Composites Research
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    • v.34 no.2
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    • pp.77-81
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    • 2021
  • Due to the high specific strength and stiffness of the composite materials, the composite materials have been extensively used in various industries. In particular, carbon fiber reinforced composites are widely used in many mechanical structures. In addition, since carbon fiber reinforced composites have anisotropic properties, to understand the fatigue behavior of composites with different fiber orientation is very important for the efficient structural design. Therefore, in this paper, the effect fiber orientation on the fatigue life of composite materials was experimentally evaluated. For this purpose, tensile and fatigue tests were performed on the off-axis specimens (0°, 10°, 30°, 45°, 60°, 90°) of the composite materials. As a result of the fatigue tests, the fatigue strength of the composites decreased significantly as the fatigue strength slightly deviated from 0 degrees. On the other hand, the more deviated, the less decreased. This is because the role of supporting the load of fibers decreased as the stacking angle increased. In addition, the fatigue behavior was analyzed by introducing a fatigue strength ratio (Ψ) that eliminates the fiber orientation dependence of the off-axis fatigue behaviors on the unidirectional composites. The off-axis fatigue S-N lines can be reduced to a single line regardless of the fiber orientation by using the fatigue strength ratio (Ψ). Using the fatigue Ψ-N line, it is possible to extract back to any off-axis fatigue S-N lines of the composites with different fiber orientations.

A Study on the Influence of Innovative Structure to Corporate Entrepreneurship and Business Performance (혁신적 조직 구조 확립이 사내 기업가정신과 기업 성과에 미치는 영향)

  • Kim, Jin-soo;Hwang, Inho
    • Korean small business review
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    • v.42 no.3
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    • pp.245-274
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    • 2020
  • The 4th Industrial Revolution is rapidly changing the business environment and enterprises are required to accelerate various innovative activities for sustainable competitiveness. Recently corporate entrepreneurship is widely spread to organization for establishing innovative corporate culture and stimulating corporate ventures. However, many enterprises are not successful and productive due to lack of readiness of corporate entrepreneruship. Therefore, finding the factors influencing corporate entreprensurship, innovative activities and business performance is a very important research issues. A research model and hypothesis are developed by through literature review to analyze positive effects of corporate entrepreneurship to corporate performance and influential effects of factors such as innovation-based efforts at the organizational level, vision and organizational strategies and innovative operating system to corporate entrepreneurship and business performance. The result of Entrepreneurship Survey with Corporates conducted by Korea Entrepreneurship Foundation in 2017 is used for the research sample. Hypothesis test used 1,326 samples and the structural equation modeling is applied. The results show that corporate entrepreneurship improves innovative idea activity performance and business performance. And, establishing innovative vision and strategies and innovative organizational culture enhances corporate entrepreneurship. In addition, it was confirmed that the innovative operational system has a moderating effect that strengthens the positive influence relationship between corporate entrepreneurship and innovative idea performance. The results of this study have implications for previous research on corporate entrepreneurship in Korea by presenting the relationship between corporate entrepreneurship and business performance and the multilateral relationships between innovative organizational structure and corporate entrepreneurship.

A Study on the Occupation Performance of the Leader of Fitness Club by Emotional Labor (피트니스 클럽 지도자의 감정노동에 의한 직업성과에 관한 연구)

  • Yoon, Jae-Soon
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.8
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    • pp.381-390
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    • 2020
  • This purpose of study was to influence of fitness club leader's emotional labor on job involvement and occupation performance. This study aims at providing fundamental data and information on fitness club leader's emotional labor. The survey was done through 250 copies and excluding 23 copies ran an analysis on the remaining 227(90.8%) copies. After question investigating the data which is collected used IBM SPSS statistics 21 and IBM AMOS 21 program, frequency analysis, Exploratory factor analysis and confirmatory factor analysis, convergent validity, discriminant validity, Cronbach's α, correlation analysis, path analysis through Structural Equation Model(SEM). The result of this study were as follows. First, fitness club leader's emotional labor showed (-) effects on job involvement. Second, fitness club leader's emotional labor showed (-) effect on occupation performance. Third, job involvement showed (+) effects on occupation performance. Fitness instructors have severe emotional labor. Therefore fitness instructors manage their emotional labor. This can increase job commitment and job performance. For teeth manager need to increase support options from fitness instructors.

A Study on the Perception of Information Search Process(ISP) and the Verification of Effectiveness of Scaffolding Strategy (정보탐색과정(ISP)에 대한 인식조사 및 스캐폴딩 전략의 효과성 검증)

  • Jeong-Hoon, Lim;Byeong-Ki, Lee
    • Journal of the Korean Society for Library and Information Science
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    • v.56 no.4
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    • pp.239-267
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    • 2022
  • In this study, the adolescents' perception of the Information Search Process(ISP); their anxiety and the need for intervention during the process were investigated based on Kuhlthau's ISP model, and the relationship among the factors was analyzed with structural equations. In addition, the effectiveness of scaffolding strategy to the experimental group during the class was verified. The main findings are as follows. First, as a result of exploring the anxiety felt by learners and the need for intervention in the information search process, it was found that the presentation stage had a significant effect on the anxiety, and the collection, presentation, and assessment stages had significant effects on the need for intervention. Second, as a result of controlling each variable to investigate the anxiety felt by learners and necessity of intervention in the information search process, it was confirmed that among the demographic variables, the difference between the first graders and the second ones was significant; and the difference in the metropolitan area was more significant than that in the Gangwon province. Third, as a result of paired t-test and covariance analysis on the control group and the experimental group, it was confirmed that the anxiety and need for intervention of the experimental group were statistically significantly reduced. The significance of this study lies in the point that it presents a practical basis for applying scaffolding strategies appropriate to information search process in the field of education.

The Effect of Structure and Acidity of Fluorinated HZSM-5 on Ethylene Aromatization (불소화 HZSM-5의 구조 및 산도가 에틸렌 방향족화에 미치는 영향)

  • Kyeong Nan, Kim;Seok Chang, Kang;Geunjae, Kwak
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.15-22
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    • 2023
  • Recent studies have actively investigated ways to improve the economic feasibility and efficiency of the Fischer-Tropsch process by increasing the yields of the monocyclic aromatic compounds (BTEX). In this study, ethylene was selected as a model of F-T-derived hydrocarbons, and the ethylene-to-aromatics (ETA) reaction was investigated according to changes in acid characteristics, mesopores, and crystallinity of HZSM-5 (HZ5). Fluorinated HZ5 was prepared by calcination followed by impregnation of an aqueous NH4F solution having different molar concentrations in HZ5, and the structural and chemical properties of F/HZ5 were investigated through Brunauer-Emmett-Teller (BET), solid-state nuclear magnetic resonance (NMR), X-ray photoelectron spectroscopy (XPS), NH3-temperature-programmed desorption (TPD), and pyridine-IR spectroscopy. The ETA reactions were performed at 673 K under 0.1 MPa, and fluorinating HZ5 by an aqueous NH4F solution of 0.17 M improved ethylene conversion, BTEX selectivity, and catalytic stability due to acidity, mesopore fraction, and crystallinity.

A Study on Policy Acceptance Intention to Use Artificial Intelligence-Based Public Services: Focusing on the Influence of Individual Perception & Digital Literacy Level (인공지능 기반 공공서비스 정책수용 의도에 관한 연구: 개인의 인식과 디지털 리터러시 수준이 미치는 영향을 중심으로)

  • Jang, Changki;Sung, WookJoon
    • Informatization Policy
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    • v.29 no.1
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    • pp.60-83
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    • 2022
  • The purpose of this study is to empirically analyze the effect of individual perception of artificial intelligence and the level of digital literacy on the acceptance of artificial intelligence-based public services. For empirical analysis, a research model was set up based on the technology acceptance model and planned behavior theory using survey data of 2017 and analyzed through structural equations. To summarize the results of the analysis, firstly, the positive perception of individuals about artificial intelligence technology plays a role in reinforcing attitudes toward benefits and reducing concerns about public service in which artificial intelligence technology has been introduced. Secondly, the level of digital literacy reinforces both benefits and concerns about artificial intelligence technology, but it was found that the intention to use public services was reinforced through the benefits of artificial intelligence technology perceived by individuals, rather than privacy concerns about artificial intelligence technology. Thirdly, it was confirmed that the perceived benefits of individuals on artificial intelligence technology reinforced the intention to use public civil services, and privacy concerns negatively influenced the intention to use. It was confirmed that the influence of a perceived ease of use and usefulness, as opposed to privacy concerns, further reinforces the intention to use. Both citizens' positive perceptions regarding the accuracy and reliability of information provided through artificial intelligence technology and institutional complementation of responsibility for errors caused by artificial intelligence technology are strengthened, and technical problems related to privacy protection are solved.

Real-time flood prediction applying random forest regression model in urban areas (랜덤포레스트 회귀모형을 적용한 도시지역에서의 실시간 침수 예측)

  • Kim, Hyun Il;Lee, Yeon Su;Kim, Byunghyun
    • Journal of Korea Water Resources Association
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    • v.54 no.spc1
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    • pp.1119-1130
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    • 2021
  • Urban flooding caused by localized heavy rainfall with unstable climate is constantly occurring, but a system that can predict spatial flood information with weather forecast has not been prepared yet. The worst flood situation in urban area can be occurred with difficulties of structural measures such as river levees, discharge capacity of urban sewage, storage basin of storm water, and pump facilities. However, identifying in advance the spatial flood information can have a decisive effect on minimizing flood damage. Therefore, this study presents a methodology that can predict the urban flood map in real-time by using rainfall data of the Korea Meteorological Administration (KMA), the results of two-dimensional flood analysis and random forest (RF) regression model. The Ujeong district in Ulsan metropolitan city, which the flood is frequently occurred, was selected for the study area. The RF regression model predicted the flood map corresponding to the 50 mm, 80 mm, and 110 mm rainfall events with 6-hours duration. And, the predicted results showed 63%, 80%, and 67% goodness of fit compared to the results of two-dimensional flood analysis model. It is judged that the suggested results of this study can be utilized as basic data for evacuation and response to urban flooding that occurs suddenly.