Magnesium (Mg) present in carbonate minerals as impurities has been used as a geochemical proxy to infer the environmental conditions where the minerals precipitated. The reliability of Mg geochemical proxies requires fundamental understanding of Mg incorporation into minerals based on accurate speciation of Mg 2+ in the crystal structure, which is determined mainly by application of X-ray absorption spectroscopy (XAS). However, high uncertainties are involved in interpreting the XAS spectra of minerals containing trace amount of Mg 2+. Because density function theory (DFT) can predict an XAS spectrum for a crystal structure, DFT calculations can reduce the uncertainties in the interpretation of the XAS spectrum. In this study, we calculated ab initio Mg K-edge absorption spectra of Mg silicates and (hydr)oxides based on DFT and analyzed the correlation between the calculated spectra and Mg structural parameters. Our ab initio Mg K-edge absorption spectra well reproduced the key features of the experimental spectra. The absorption-edge positions of the calculated spectra showed the weak positive correlation with the average Mg-O bond distance or Mg effective coordination number. The current study shows that DFT-based core-level spectroscopy method is a powerful tool in providing standard Mg K-edge spectra of diverse Mg minerals and determining the Mg chemical species within carbonate minerals.
Usable capacity is one of the most important parameters for evaluating the performance of an adsorbent for $CO_2$ capture from flue gas streams. In the pressure swing adsorption (PSA) process, the usable capacity is calculated as the difference between the quantity adsorbed in flue gas at high pressure (ca. 20 bar) and the quantity adsorbed at lower purge pressure (ca. 2 bar). In this paper, two stereo-types of metal-organic framework (MOF) were evaluated as an promising adsorbent for $CO_2$ capture: flexible structured MOF (MIL-53) and MOF possessing strong binding sites (MOF-74). The results showed that a total $CO_2$ capture capacity is strongly related to the specific surface area and heat of adsorption, revealing high uptake in MOF-74. However, the usable capacity was more pronounced in MIL-53 due to a structural transition.
Kim, Won-Seop;Lee, Jong-Hun;LeeSeo, Han-Seop;Park, Sang-Heup
Journal of the Korea Academia-Industrial cooperation Society
/
v.20
no.8
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pp.133-138
/
2019
This study evaluated the tensile properties of SAPH440, a hot-rolled steel for automotive structural applications, based on GMAW lap welding, the welding current, the welding voltage, and the feed rate. Tensile tests were performed according to the joint parameters of the GMAW process, for which specimens were fabricated according to KS B ISO 9018 by lap welding. The bead appearance was observed in each condition, and the weldability was evaluated by the tensile test. Higher the welding current resulted in a deeper weld, but the tensile strength was not significantly different from when the parameter was fixed due to the fracture of the base material. When the current was higher than the voltage, as in the case of a welding current of 200 A and welding voltage of 17 V, a large amount of spatter is generated, the welding is unstable, and the welded part breaks. Higher the voltage resulted in the bead not causing defects in general, and it also affected the weldability. If the current and voltage were too low, the welding was not performed normally, and the tensile strength could not be measured. However, as the current increased, the increase of the voltage and the feed rate did not affect the tensile strength.
Strengthening with near surface mounted carbon fibre reinforced polymers (NSM-CFRP) is a strengthening technique that have been used for several decades to increase the load carrying capacity of reinforced concrete members. In Iraq, many concrete buildings and bridges were subjected to a wide range of damage as a result of the last war and many other events. Accordingly, there is a progressive increase in the strengthening of concrete structures, bridges in particular, by using CFRP strengthening techniques. Near-surface mounted carbon fibre polymer has been recently proved as a powerful strengthening technique in which the CFRP strips are sufficiently protected against external environmental conditions especially the high-temperature rates in Iraq. However, this technique has not been examined yet under repeated loading conditions such as traffic loads on bridge girders. The main objective of this research was to investigate the effectiveness of NSM-CFRP strips in reinforced concrete beams under repeated loads. Different parameters such as the number of strips, groove size, and two types of bonding materials (epoxy resin and cement-based adhesive) were considered. Fifteen NSM-CFRP strengthened beams were tested under concentrated monotonic and repeated loadings. Three beams were non-strengthened as reference specimens while the remaining were strengthened with NSM-CFRP strips and divided into three groups. Each group comprises two beams tested under monotonic loads and used as control for those tested under repeated loads in the same group. The experimental results are discussed in terms of load-deflection behavior up to failure, ductility factor, cumulative energy absorption, number of cycles to failure, and the mode of failure. The test results proved that strengthening with NSM-CFRP strips increased both the flexural strength and stiffness of the tested beams. An increase in load carrying capacity was obtained in a range of (1.47 to 4.49) times that for the non-strengthened specimens. Also, the increase in total area of CFRPs showed a slight increase in flexural capacity of (1.02) times the value of the control strengthened one tested under repeated loading. Increasing the total area of CFRP strips resulted in a reduction in ductility factor reached to (0.71) while the cumulative energy absorption increased by (1.22) times the values of the strengthened reference specimens tested under repeated loading. Moreover, the replacement of epoxy resin with cement-based adhesive as a bonding material exhibited higher ductility than specimen with epoxy resin tested under monotonic and repeated loading.
Journal of the Korean Society of Propulsion Engineers
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v.25
no.1
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pp.1-11
/
2021
POGO is a dynamic axial instability phenomenon that occurs in liquid-propelled rockets. As the natural frequencies of the fuselage and those of the propellant supply system become closer, the entire system will become unstable. To predict POGO, the propellant (oxidant and fuel) tank in the first stage is modeled as a shell element, and the remaining components, the engine and the upper part, are modeled as mass-spring, and structural analysis is performed. The transmission line model is used to predict the pressure and flow perturbation of the propellant supply system. In this paper, the closed-loop transfer function is constructed by integrating the fuselage structure and fluid modeling as described above. The pogo suppressor consists of a branch pipe and an accumulator that absorbs pressure fluctuations in a passive manner and is located in the middle of the propellant supply system. The design parameters for its design optimization to suppress the decay phenomenon are set as the diameter, length of the branch pipe, and accumulator. Multiple-objective function optimization is performed by setting the energy minimization of the closed loop transfer function in terms of to the mass of the pogo suppressor and that of the propellant as the objective function.
This study was approached from the perspective of leadership as a study on innovation, a concept that can develop and maintain a continuous competitive advantage in the rapidly changing environment of management and public service organizations. the purpose of this study is as follows. first, it defines the concept of creative leadership and tests the relationship with innovation behavior through various variables. second, the relationship between conceptually defined creative leadership and job enthusiasm and organizational trust is tested in the organization of public officials in the educational administration. third, it examines the relationship between job enthusiasm and organizational trust, which are parameters, innovation behaviors of public officials in the educational administration. the finddings are as follows. job enthusiasm, organizational trust, and creative leadership were suggested as prerequisites that directly influence the innovation behavior of the organizational members of the educational administration office.
Wi, Sung Hee;Kang, Min Jin;Hwang, Eui Sun;Baek, Gi Hyeon;Kim, Jin Hwan;Park, Hyeon Uk;Cheong, Byoung-Ho
Korean Journal of Optics and Photonics
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v.33
no.2
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pp.67-73
/
2022
In a head-mounted display (HMD) for virtual-reality applications, a narrow viewing angle is preferred to the usual, wide viewing angle because the HMD is positioned close in front of the user's eyes, and the display position is fixed. In this paper, we propose a new back-light unit (BLU) for implementing a narrow viewing angle, which is suitable for a HMD. By optimizing the scattering patterns in the light-guide-plate and inverse-prism structures, the viewing angle and correlations between structural parameters in the BLU components are analyzed with ray-tracing simulations. As a result, a double-angle inverse-prism structure incorporating the scattering patterns of a light-guide plate is chosen, which results in a 14% increase in center luminance, a 16% decrease in the vertical viewing angle, and a light efficiency of up to 70%, compared to a conventional BLU. Thus, the new BLU system is expected to be applied in a high-efficiency liquid crystal display.
Most humans live at work and continue their lives through work. This study aims to understand the influence of job crafting on job satisfaction and knowledge sharing behavior, innovation behavior, and smart work environment variables in the rapidly changing labor market. In addition, a study was conducted on the effect of job crafting on job satisfaction by dividing it into male and female groups. The study was conducted on 453 office workers who responded to the survey, and SPSS 26.0 and Amos 26.0 were used. Frequency analysis, exploratory factor analysis, confirmatory factor analysis, reliability analysis, descriptive statistics, correlation, structural model analysis and Multi-group analysis were performed. Multiple mediating effects were analyzed and Process macro model 7 was used as the smart work environment effect. As a result of the analysis, first, job crafting had a significant effect on job satisfaction, and second, job crafting had a significant effect on knowledge sharing behavior and innovation behavior. Third, knowledge sharing behavior had a significant effect on job satisfaction, but innovation behavior did not affect job satisfaction. Fourth, for the parameters of knowledge sharing behavior and innovation behavior, knowledge sharing behavior had a partial mediating effect, but innovation behavior did not affect it. Fifth, it was found that the moderating effect of the smart work environment had no effect, and sixth, the results of a study on the effect of job crafting on job satisfaction divided into men and women had a greater effect than men.
To realize the recycling utilization of waste concrete and alleviate the shortage of resources, 11 specimens of steel reinforced recycled concrete (SRRC) filled circular steel tube columns were designed and manufactured in this study, and the cyclic loading tests on the specimens of columns were also carried out respectively. The hysteretic curves, skeleton curves and performance indicators of columns were obtained and analysed in detail. Besides, the finite element model of columns was established through OpenSees software, which considered the adverse effect of recycled coarse aggregate (RA) replacement rates and the constraint effect of circular steel tube on internal RAC. The numerical calculation curves of columns are in good agreement with the experimental curves, which shows that the numerical model is relatively reasonable. On this basis, a series of nonlinear parameters analysis on the hysteretic behaviors of columns were also investigated. The results are as follows: When the replacement rates of RA increases from 0 to 100%, the peak loads of columns decreases by 7.78% and the ductility decreases slightly. With the increase of axial compression ratio, the bearing capacity of columns increases first and then decreases, but the ductility of columns decreases rapidly. Increasing the wall thickness of circular steel tube is very profitable to improve the bearing capacity and ductility of columns. When the section steel ratio increases from 5.54% to 9.99%, although the bearing capacity of columns is improved, it has no obvious contribution to improve the ductility of columns. With the decrease of shear span ratio, the bearing capacity of columns increases obviously, but the ductility decreases, and the failure mode of columns develops into brittle shear failure. Therefore, in the engineering design of columns, the situation of small shear span ratio (i.e., short columns) should be avoided as far as possible. Based on this, the calculation model on the skeleton curves of columns was established by the theoretical analysis and fitting method, so as to determine the main characteristic points in the model. The effectiveness of skeleton curve model is verified by comparing with the test skeleton curves.
In this work a multi-fidelity non-intrusive polynomial chaos (MF-NIPC) has been applied to a structural wind engineering problem in architectural design for the first time. In architectural design it is important to design structures that are safe in a range of wind directions and speeds. For this reason, the computational models used to design buildings and bridges must account for the uncertainties associated with the interaction between the structure and wind. In order to use the numerical simulations for the design, the numerical models must be validated by experi-mental data, and uncertainties contained in the experiments should also be taken into account. Uncertainty Quantifi-cation has been increasingly used for CFD simulations to consider such uncertainties. Typically, CFD simulations are computationally expensive, motivating the increased interest in multi-fidelity methods due to their ability to lev-erage limited data sets of high-fidelity data with evaluations of more computationally inexpensive models. Previous-ly, the multi-fidelity framework has been applied to CFD simulations for the purposes of optimization, rather than for the statistical assessment of candidate design. In this paper MF-NIPC method is applied to flow around a rectan-gular 5:1 cylinder, which has been thoroughly investigated for architectural design. The purpose of UQ is validation of numerical simulation results with experimental data, therefore the radius of curvature of the rectangular cylinder corners and the angle of attack are considered to be random variables, which are known to contain uncertainties when wind tunnel tests are carried out. Computational Fluid Dynamics (CFD) simulations are solved by a solver that employs the Finite Element Method (FEM) for two turbulence modeling approaches of the incompressible Navier-Stokes equations: Unsteady Reynolds Averaged Navier Stokes (URANS) and the Large Eddy simulation (LES). The results of the uncertainty analysis with CFD are compared to experimental data in terms of time-averaged pressure coefficients and bulk parameters. In addition, the accuracy and efficiency of the multi-fidelity framework is demonstrated through a comparison with the results of the high-fidelity model.
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