• Title/Summary/Keyword: Structural Conversion

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An atomistic model for hierarchical nanostructured porous carbons in molecular dynamics simulations

  • Chae, Kisung;Huang, Liping
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.403.2-403.2
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    • 2016
  • Porous materials play a significant role in energy storage and conversion applications such as catalyst support for polymer electrolyte membrane fuel cell. In particular, hierarchical porous materials with both micropores (poresize, ${\delta}$ < 2 nm) and regularly arranged mesopores (2 nm < ${\delta}$ < 50 nm) are known to greatly enhance the efficiency of catalytic reactions by providing enormous surface area as well as fast mass transport channels for both reactants and products from/to active sites. Although it is generally agreed that the microscopic structure of the porous materials directly affects the performance of these catalytic reactions, neither detailed mechanisms nor fundamental understanding are available at hand. In this study, we propose an atomistic model of hierarchical nanostructured porous carbons (HNPCs) in molecular dynamics simulations. By performing a systematic study, we found that structural features of the HNPC can be independently altered by tuning specific synthesis parameters, while remaining other structures unchanged. In addition, we show some structure-property relations including mechanical and gas transport properties.

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A Study on the Preparation of the Eco-friendly Carbon Fibers-Reinforced Composites

  • Choi, Kyeong-Eun;Seo, Min-Kang
    • Carbon letters
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    • v.14 no.1
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    • pp.58-61
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    • 2013
  • In this work, the effect of catalysts on the mechanical properties of carbon fibers-reinforced epoxy matrix composites cured by cationic latent thermal catalysts, i.e., N-benzylpyrazinium hexafluoroantimonate (BPH) was studied. Differential scanning calorimetry was executed for thermal characterization of the epoxy matrix system. Mechanical interfacial properties of the composites were studied by interlaminar shear strength (ILSS), critical stress intensity factor ($K_{IC}$), and specific fracture energy ($G_{IC}$). As a result, the conversion of neat epoxy matrix cured by BPH was higher than that of one cured by diaminodiphenyl methane (DDM). The ILSS, $K_{IC}$, $G_{IC}$, and impact strength of the composites cured by BPH were also superior to those of the composites cured by DDM. This was probably the consequence of the effect of the substituted benzene group of BPH catalyst, resulting in an increase in the cross-link density and structural stability of the composites studied.

Noble metal catalysts for water gas shift reaction and their effectiveness factor (귀금속 계열 촉매의 수성가스전환반응특성과 유효인자)

  • Lim, Sung-Kwang;Bae, Joong-Myeon;Kim, Ki-Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.514-517
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    • 2008
  • Water gas shift(WGS) is an important step in fuel process for fuel cells, and improperness of commercial WGS catalysts for use in fuel cell systems has prompted numerous researches on noble metal catalysts. A selected noble metal catalyst for water gas shift reaction(WGS) was prepared with various metal loadings. The prepared catalysts were tested under two feeding conditions. At moderate residence time, carbon monoxide conversion was much higher on the noble metal catalysts as compared to commercial high-temperature shift catalyst. Effects of metal loading were examined by activity tests at short residence time. Higher metal loading effected higher reaction rate. The kinetic data was fitted to simple reaction equations and effectiveness factor was estimated. The results suggest the necessity of a structural design for the highly active noble metal catalysts.

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Characterization of thin film Si solar cell with FTO transparent electrode (FTO 투명전극에 따른 박막 실리콘 태양전지 특성평가)

  • Kim, S.H.;Kim, Y.J.;No, I.J.;Cho, J.W.;Lee, N.H.;Kim, J.S.;Shin, P.K.
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1351_1352
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    • 2009
  • We deposited $SnO_2$:F thin films by atomospheric pressure chemical vapor deposition(APCVD) on corning glass. $SnO_2$:F films were used as transparent conductive oxide (TCO) electrode for Si thin film solar cells. We have investigated structural, electrical and optical properties of $SnO_2$:F thin films and fabricated thin film Si solar cells by plasma enhanced CVD(PECVD) on $SnO_2$:F thin films The cells were characterized by I-V measurement using AM1.5 spectra. Conversion efficiency of our cells were between 5.61% and 6.45%.

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Synthesis and Characterization of Graphene Counter Electrode By Electrophoretic Deposition for Dye-Sensitized Solar Cells

  • Choe, Yun-Su;Gong, Jae-Seok;Choe, Hyeon-Gwang;Jeon, Min-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.160-160
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    • 2013
  • Dye-sensitized solar cells (DSSCs) have attracted much attention because of their moderate light-to-electricity conversion efficiency, easy fabrication, and low cost. At present, platinum (Pt) is used as a counter electrode in DSSCs. However, it is found that Pt dissolves in iodide electrolyte solutions and creates chemical compound such as PtI4 and H2PtI6. Carbon based materials are one of candidates for a counter electrode of DSSCs. We prepare two types of graphite oxides by different chemical treatments; original graphite oxide, hydrazine treated graphite oxide. Each graphite oxide and magnesium nitrate dispersed in deionized water are prepared as solutions for electrophoretic deposition (EPD). Each graphite oxide electrode is deposited on fluorine-doped tin oxide (FTO) substrate by EPD method. Structural and electrochemical properties of each electrode are investigated by field-emission scanning electron microscopy and electrochemical impedance spectroscopy, respectively.

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On magnetostrictive materials and their use in adaptive structures

  • Dapino, Marcelo J.
    • Structural Engineering and Mechanics
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    • v.17 no.3_4
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    • pp.303-329
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    • 2004
  • Magnetostrictive materials are routinely employed as actuator and sensor elements in a wide variety of noise and vibration control problems. In infrastructural applications, other technologies such as hydraulic actuation, piezoelectric materials and more recently, magnetorheological fluids, are being favored for actuation and sensing purposes. These technologies have reached a degree of technical maturity and in some cases, cost effectiveness, which justify their broad use in infrastructural applications. Advanced civil structures present new challenges in the areas of condition monitoring and repair, reliability, and high-authority actuation which motivate the need to explore new methods and materials recently developed in the areas of materials science and transducer design. This paper provides an overview of a class of materials that because of the large force, displacement, and energy conversion effciency that it can provide is being considered in a growing number of quasistatic and dynamic applications. Since magnetostriction involves a bidirectional energy exchange between magnetic and elastic states, magnetostrictive materials provide mechanisms both for actuation and sensing. This paper provides an overview of materials, methods and applications with the goal to inspire novel solutions based on magnetostrictive materials for the design and control of advanced infrastructural systems.

A Study on 2D/3D image Conversion Method using Optical flow of Level Simplified and Noise Reduction (Optical flow의 레벨 간소화와 잡음제거를 이용한 2D/3D 변환기법 연구)

  • Han, Hyeon-Ho;Lee, Gang-Seong;Eun, Jong-Won;Kim, Jin-Soo;Lee, Sang-Hun
    • Proceedings of the KAIS Fall Conference
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    • 2011.12b
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    • pp.441-444
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    • 2011
  • 본 논문은 2D/3D 영상 처리에서 깊이지도 생성을 위한 Optical flow에서 레벨을 간소화하여 연산량을 감소시키고 객체의 고유벡터를 이용하여 영상의 잡음을 제거하는 연구이다. Optical flow는 움직임추정 알고리즘의 하나로 두 프레임간의 픽셀의 변화 벡터 값을 나타내며 블록 매칭과 같은 알고리즘에 비해 정확도가 높다. 그러나 기존의 Optical flow는 긴 연산 시간과 카메라의 이동이나 조명의 변화에 민감한 문제가 있다. 이를 해결하기 위해 연산 시간의 단축을 위한 레벨 간소화 과정을 거치고 영상에서 고유벡터를 갖는 영역에 한해 Optical flow를 적용하여 잡음을 제거하는 방법을 제안하였다. 제안한 방법으로 2차원 영상을 3차원 입체 영상으로 변환하였고 SSIM(Structural SIMilarity Index)으로 최종 생성된 영상의 오차율을 분석하였다.

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A Study on Photocatalytic Degradation Properties by Oxygen Partial Pressure for Tio2Thin Films Fabricated by DC Magnetron Sputtering (DC 마그네트론 스퍼터링법으로 제조된 Tio2 박막의 산소분압비에 따른 광분해 특성에 관한 연구)

  • Jeong, W.J.;Park, J.Y.;Park, G.C.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.3
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    • pp.226-230
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    • 2005
  • This paper describes the photocatalytic degradation properties by oxygen partial pressure for TiO$_2$ thin films fabricated by dc magnetron reactive sputtering. And the structural, chemical, optical and photocatalytic properties were investigated at various analysis system. When TiO$_2$ thin film was made at deposition time of 120 min and Ar:O$_2$ ratio of 60:40, the best properties were obtained. That results were as follows: thickness; 360∼370 nm, gram size; 40 nm, optical energy band gap; 3.4 eV and Benzene conversion in the photocatalytic degradation; 11 %.

Buried Contact Solar Cells using Tri-crystalline Silicon Wafer

  • Lee Soo-Hong
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.3
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    • pp.29-33
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    • 2003
  • Tri-crystalline silicon wafers have three different orientations and three-grain boundaries. In this paper, tri-crystalline silicon (tri-Si) wafers have been used for the fabrication of buried contact solar cells. The optical and micro-structural properties of these cells after texturing in KOH solution have been investigated and compared with those of cast mult- crystalline silicon (multi-Si) wafers. We employed a cost effective fabrication process and achieved buried contact solar cell (BCSC) energy conversion efficiencies up to $15\%$ whereas the cast multi-Si wafer has efficiency around $14\%$.

DEVELOPMENT OF THE JOINING PROCESSES IN A GLOBAL PERSPECTIVE

  • Pekari, Bertil
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.1-14
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    • 2002
  • There is a continuous development of the most common welding processes like MMA, MIG/MAG, PAW and SAW. At the same time there is a conversion from stick electrodes to solid and cored wires with an increased productivity as a result. In parallel with these changes new processes are introduced and implemented. The number of Friction Stir Welding installations is starting to grow fast Hybrid laser welding has probably made a technical break through. The Magnetic Pulse Welding process is taking off. The different mechanical joining methods; clinching and self-piercing riveting; must not be forgotten. Structural adhesive is another method to consider.

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