• 제목/요약/키워드: Structural Conversion

검색결과 321건 처리시간 0.031초

TiO2/ITO 나노구조체 광전극의 합성 및 염료감응 태양전지에의 적용 (Synthesis of TiO2/ITO Nanostructure Photoelectrodes and Their Application for Dye-sensitized Solar Cells)

  • 김대현;박경수;최영진;최헌진;박재관
    • 한국세라믹학회지
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    • 제48권1호
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    • pp.94-98
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    • 2011
  • A Sn-doped $In_2O_3$ (ITO) nanowire photoelectrode was produced using a simple metal evaporation method at low synthesis temperature (< $540^{\circ}C$). The nanowire electrodes have large surface area compared with that of flat ITO thin film, and show low electrical resistivity of $5.6{\times}10^{-3}{\Omega}cm$ at room temperature. In order to apply ITO nanowires to the photoelectrodes of dye-sensitized solar cell (DSSC), those surfaces were modified by $TiO_2$ nanoparticles using a chemical bath deposition (CBD) method. The conversion efficiency of the fabricated $TiO_2$/ITO nanostructure-based DSSC was obtained at 1.4%, which was increased value by a factor of 6 than one without ITO nanowires photoelectrode. This result is attributed to the large surface area and superior electrical property of the ITO nanowires photoelectrode, as well as the structural advantages, including short diffusion length of photo-induced electrons, of the fabricated $TiO_2$/ITO nanostructure-based DSSC.

글로벌기업, 글로벌지역, 그리고 투자유인의 인센티브 팩키지: 한국기업의 유럽연차 Objective 1${\cdot}$2지역 해외직접투자를 중심으로 (Global Firms, Global Regions and Incentive Packages for Foreign Investors: Korean Foreign Direct Investment in EU Objective 1.2 Regions)

  • 정성훈
    • 한국경제지리학회지
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    • 제5권2호
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    • pp.209-228
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    • 2002
  • 이 논문의 목적은 1980년대 후반~1990년대 후반까지 한국기업들의 대유럽연합(EU) 직접투자를 중심으로 EU Objective 1(저발전지역).2(구조재편지역)지역의 투자유치전략을 평가하는 것이다. 이 지역들의 투자유치전략 중 가장 중요했던 것은 한국기업들의 유치를 위해 제공되었던 막대한 인센티브 팩키지였다. 그럼에도 불구하고, 이와 같은 인센티브 팩키지는 한국기업이 지닌 경쟁력의 한계(비용경쟁력)와 EU Objective 1.2지역 지방노동시장의 경쟁력의 한계(저생산성.저숙련)로 인해 기업 및 지역발전에 기여하지 못했다. 결국, 기업과 지역의 내.외적 환경에 대한 고려없이 제공되었던 EU의 인센티브 팩키지 전략은 기업과 지역 모두에게 성공적인 발전경로를 밟을 수 있는 기회를 주지 못했다.

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10 MW급 복합재 풍력 블레이드의 굽힘-비틀림 커플링 거동 연구 (Bend-Twist Coupling Behavior of 10 MW Composite Wind Blade)

  • 김수현;신형기;방형준
    • Composites Research
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    • 제29권6호
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    • pp.369-374
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    • 2016
  • 본 연구에서는 굽힘-비틀림 커플링(bend-twist coupled, BTC) 설계개념을 적용한 10 MW급 복합재 풍력 블레이드의 구조 최적 설계를 수행하였다. BTC 설계개념은 동적 하중 상황에서 블레이드의 굽힘과 비틀림 거동 사이의 연동을 유도하여, 단면 받음각 변화에 의한 수동적인 적응 하중저감이 가능하다. 인자연구를 통해 최적의 BTC 설계인자를 추출하여 블레이드 구조설계에 적용하였다. BTC 개념이 동적 하중 감소에 미치는 영향을 가늠하기 위해 블레이드 루트 부에서의 피로등가하중을 계산한 결과, BTC 개념이 적용된 블레이드를 적용한 경우 피로등가하중이 2-3% 정도 감소하는 것을 확인할 수 있었다. BTC 효과를 시험적으로 검증하기 위해 1:29 비율의 블레이드 stiffener 축소모델을 제작하였으며, 정하중 시험을 통해 처짐 거동 시 끝단에서의 비틀림을 측정하였다.

녹색물류기업 인증이 녹색물류성과에 미치는 영향 (The Influences of Certification of Green Logistics Company on Performance)

  • 김영민
    • 한국항만경제학회지
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    • 제31권1호
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    • pp.111-125
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    • 2015
  • 본 연구는 물류기업을 대상으로 녹색물류기업 인증이 녹색물류성과에 미치는 영향을 실증적으로 분석하고, 그에 대한 시사점을 제시하고자 하였다. 녹색물류와 관련된 선행연구를 통해 물류성과, 환경성과, 자원성과 및 기업성과와 같은 성과 변수를 도출하고, 녹색물류기업 인증 기준과의 영향관계를 분석하였다. 물류기업 종사자를 대상으로 녹색물류기업 인증과 녹색물류성과의 관계에 대하여 설문조사를 실시하고, 탐색적 요인분석, 신뢰성분석 및 확인적 요인분석을 실시하였으며, 가설검증을 위해 구조방정식 모형분석을 실시하였다. 연구결과, 녹색물류 목표관리는 물류성과와 환경성과에 유의한 영향을 미쳤으며, 물류에너지 및 온실가스 산정은 물류성과, 환경성과 및 자원성과에 유의한 영향을 미쳤고, 녹색물류 효과관리는 기업성과에 유의한 영향을 미치는 것으로 분석되었다. 그러나 녹색물류 전환사업은 녹색물류성과라고 할 수 있는 물류성과, 환경성과, 자원성과 및 기업성과에 유의한 영향을 미치지 못하였다.

In vitro and in vivo evaluation of kenaf (Hibiscus cannabinus L.) as a roughage source for beef cattle

  • Oh, Seongjin;Mbiriri, David Tinotenda;Ryu, Chaehwa;Lee, Kangheon;Cho, Sangbuem;Choi, Nag-Jin
    • Asian-Australasian Journal of Animal Sciences
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    • 제31권10호
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    • pp.1598-1603
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    • 2018
  • Objective: The goal of this study was to evaluate kenaf as a roughage source in vitro and its effects on meat quality of Hanwoo (Korean native) cattle. Methods: Three roughage materials, rice straw silage, ryegrass silage, and kenaf silage, were tested in a batch culture and feeding trial. Rumen fermentation parameters, including gas, pH, volatile fatty acid (VFA), and ammonia were analyzed. In the feeding trial, Hanwoo steers ($373.5{\pm}5.1kg$, n = 36, 11 month of age) were divided into three feeding groups (n = 12 each). Animals were fed with each silage and concentrate until the fattening stage. Results: Crude protein, ether extract, and non-structural carbohydrates were greater in kenaf silage. Total gas production was higher in ryegrass silage, followed by kenaf silage and rice straw silage (p<0.05). Total VFA and individual VFA (acetate, propionate, and n-butyrate) were greater in kenaf silage than rice straw silage (p<0.05). In vitro dry matter digestibility showed a similar trend to that of total gas and VFA production; it was higher in ryegrass silage and lower in rice straw (p<0.05). Throughout the feeding trial, the rice straw silage group showed significantly greater average daily gain than did the others (p<0.05). The feed conversion ratio in the group fed kenaf silage was significantly greater than that of others (p<0.05). No significant differences were observed in yield or quality traits, including carcass weight, ribeye area, backfat thickness, and scores for marbling, meat color, and fat color (p>0.05). Conclusion: The results indicated that no negative effects on growth performance and carcass characteristics occurred across treatments. Therefore, kenaf could be substituted for rice straw, which is most widely used as a roughage source in Korea.

가변 데이터 전송 가능한 텔레메트리(Telemetry) 송신기 (The Telemetry Transmitter with Variable Data rate Transmission)

  • 김장희;홍승현;박병관;김복기;김효종
    • 한국항행학회논문지
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    • 제24권1호
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    • pp.53-60
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    • 2020
  • 본 논문에서는 가변 데이터 전송 가능한 텔레메트리 송신기의 구조에 대해 연구하였다. 가변 데이터 전송을 위하여 가변 컷오프 특성을 가지는 VPMF (variable pre-modulation filter)와 가변입력 샘플레이트 변환기 (variable input sample rate converter)가 결합된 구조를 제안한다. VPMF는 일반적인 PMF (pre-modulation filter)와 동일하게 변조 전 신호의 고주파 성분을 억제하여 RF (radio frequency)신호의 대역을 제한하는 특성을 지니며, 추가적으로 입력 데이터율에 따라 가변 컷오프 특성을 갖는다. 가변입력 샘플레이트 변환기는 입력 데이터율 변경 시 추가적인 구조변경 없이 입력 데이터율과 무관하게 출력을 일정한 샘플링 속도로 변환하는 기능을 갖는다. 추가적으로 실시간 변화하는 데이터양에 대응하기 위해 VPMF와 가변입력 샘플레이트 변환기를 능동적으로 제어하는 소프트웨어 프로그램 기법을 제안한다. 제안 방법을 적용하여 시뮬레이션과 실제 제작을 통하여 입력 데이터율 390 kbps ~ 25 Mbps 범위에서 IRIG (inter-range instrumentation group) 표준의 99% 전력 대역폭, null-to-null 대역폭, 1st IMD (inter modulation distortion) 비교 결과 규격을 만족하는 데이터 전송이 가능함을 확인하였다.

Buffer and Anode Combined Ta Doped In2O2 Electrodes Prepared by Co-sputtering for PEDOT:PSS-free Organic Solar Cells

  • Lee, Hye-Min;Noh, Yong-Jin;Na, Seok-In;Park, Hyun-Woo;Chung, Kwun-Bum;Kima, Han-Ki
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.168.1-168.1
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    • 2014
  • We developed poly (3,4-ethylene dioxylene thiophene):poly (styrene sulfonic acid) (PEDOT:PSS)-free organic solar cells (OSCs) using buffer and anode combined Ta doped $In_2O_3$ (ITaO) electrodes. To optimize the ITaO electrodes, we investigated the effect of $Ta_2O_5$ doping power on the electrical, optical, and structural properties of the co-sputtered ITaO films. The optimized ITaO film doped with 20 W $Ta_2O_5$ radio frequency power showed sheet resistance of 17.11 Ohm/square, a transmittance of 93.45%, and a work function of 4.9 eV, all of which are comparable to the value of conventional ITO electrodes. The conventional bulk heterojunction OSC with ITaO anode showed a power conversion efficiency (PCE) of 3.348% similar to the OSCs (3.541%) with an ITO anode. In addition, OSCs fabricated on an ITaO electrode successfully operated without an acidic PEDOT:PSS buffer layer and showed a PCE of 2.634%, which was much higher than the comparable no buffer OSC with an ITO anode. Therefore, co-sputtered ITaO electrodes simultaneously acting as a buffer and an anode layer can be considered promising transparent electrodes for cost-efficient and reliable OSCs because they can eliminate the use of an acidic PEDOT:PSS buffer layer.

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High Transparent, High Mobility MoO3 Intergraded InZnO Films for Use as a Transparent Anode in Organic Solar cells

  • Kim, Hyo-Jung;Kang, Sin-Bi;Na, Seok-In;Kim, Han-Ki
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.343-343
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    • 2014
  • We reported on the electrical, optical, structural and morphological properties fabricated by co-sputtering for use as an anode for organic solar cells (OSCs). By adjusting RF and DC power of $MoO_3$ and IZO targets during co-sputtering, we fabricated the $MoO_3$-IZO electrode with graded content of the $MoO_3$ on the IZO films. At optimized $MoO_3$ thickness of 20 nm, the $MoO_3$ graded IZO electrode showed a higher mobility ($33cm^2/V-Sec$) than directly deposited $MoO_3$ on IZO film ($26cm^2/V-Sec$). At visible range (400nm~800nm), optical transmittance of the $MoO_3$ graded IZO electrode is higher than that of directly deposited $MoO_3$ on IZO film. High mobility of $MoO_3$ graded on IZO is attributed to less interface scattering between $MoO_3$ and IZO. To investigate the feasibility of $MoO_3$ graded IZO films, we fabricated conventional P3HT:PCBM based OSCs with $MoO_3$ graded IZO as a function of MoO3 thickness. The OSC fabricated on the $MoO_3$ graded IZO anode showed a fill factor of 66.53%, a short circuit current of $8.121mA/cm^2$, an open circuit voltage of 0.592 V, and a power conversion efficiency of 3.2% comparable to OSC fabricated on ITO anode and higher than directly deposited $MoO_3$ on IZO film. We suggested possible mechanism to explain the high performance of OSCs with a $MoO_3$ graded IZO.

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Brush-painted Ti-doped In2O3 Transparent Conducting Electrodes Using Nano-particle Solution for Printable Organic Solar Cells

  • 정진아;김한기
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.458.2-458.2
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    • 2014
  • We have demonstrated that simple brush-painted Ti-doped $In_2O_3$(TIO) films can be used as a cost effective transparent anodes for organic solar cells (OSCs). We examined the RTA effects on the electrical, optical, and structural properties of the brush painted TIO electrodes. By the direct brushing of TIO nanoparticle ink and rapid thermal annealing (RTA), we can simply obtain TIO electrodes with a low sheet resistance of 28.25 Ohm/square and a high optical transmittance of 85.48% under atmospheric ambient conditions. Furthermore, improvements in the connectivity of the TIO nano-particles in the top region during the RTA process play an important role in reducing the resistivity of the brush-painted TIO anode. In particular, the brush painted TIO films showed a much higher mobility ($33.4cm^2/V-s$) than that of previously reported solution-process transparent oxide films ($1{\sim}5cm^2/V-s$) due to the effects of the Ti dopant with higher Lewis acid strength (3.06) and the reduced contact resistance of TIO nanoparticles. The OSCs fabricated on the brush-painted TIO films exhibited cell-performance with an open circuit voltage (Voc) of 0.61 V, shot circuit current (Jsc) of $7.90mA/cm^2$, fill factor (FF) of 61%, and power conversion efficiency (PCE) of 2.94%. This indicates that brush-painted TIO film is a promising cost-effective transparent electrode for printing-based OSCs with its simple process and high performance.

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염료감응형 태양전지의 비백금 상대전극을 위한 Co가 내재된 Graphitic 다공성 탄소나노섬유 (Co-Embedded Graphitic Porous Carbon Nanofibers for Pt-Free Counter Electrode in Dye-Sensitized Solar Cells)

  • 안혜란;강혜린;선효정;한지호;안효진
    • 한국재료학회지
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    • 제25권12호
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    • pp.672-677
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    • 2015
  • Co-embedded graphitic porous carbon nanofibers(Co-GPCNFs) are synthesized by using an electrospinning method. Their morphological, structural, electrochemical, and photovoltaic properties are investigated. To obtain the optimum condition of Co-GPCNFs for dye-sensitized solar cells(DSSCs), the amount of cobalt precursor in an electrospinning solutuion are controlled to be 0 wt%(conventional CNFs), 1 wt%(sample A), and 3 wt%(sample B). Among them, sample B exhibited a high degree of graphitization and porous structure compared to conventional CNFs and sample A, which result in the performance improvement of DSSCs. Therefore, sample B showed a high current density(JSC, $12.88mA/cm^2$) and excellent power conversion efficiency(PCE, 5.33 %) than those of conventional CNFs($12.00mA/cm^2$, 3.78 %). This result can be explained by combined effects of the increased contact area between the electrode and elecytolyte caused by improved porosity and the increased conductivity caused by the formation of a high degree of graphitization. Thus, the Co-GPCNFs may be used as a promising alternative of Pt-free counter electrode in DSSCs.