• 한국해양공학회지
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• 제20권2호
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• pp.52-58
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• 2006

The effect of various environmental conditions on the durability of E-glass fiber/vinylester resin composites have been investigated using the tensile test specimen of strand type. It was found that the durability test method performed by the stand type specimen was more convenient and reliable than other conventional test method. The weight gains increased with the immersion time in both water and alkaline solution, and the Weight gains at $50^{\circ}C$. were much bigger than those at $20^{\circ}C$ in both conditions. The tensile strength decreased with the pass of immersion time in all aqueous solution, and the tensile strength at $80^{\circ}C$ in alkaline solution decreased very steeply at beginning of immersion time. The decrement of tensile strength according to the immersion time in various environmental conditions was mainly caused by the degradation of interface and the damage of glass fiber surface.

• Advances in concrete construction
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• 제4권2호
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• pp.107-121
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• 2016

This concrete is one of the most versatile construction material widely used for almost a century now. It was considered to be very durable material and required a little or no maintenance since long time. The assumption is very true, except when it is subjected to highly aggressive environments. The deterioration of concrete structures day by day due to aggressive environment is compelling engineers to assess the loss in advance so that proper preventive measure can be taken to achieve required durability to concrete structures. The compounds present in cement concrete are attacked by many salt solutions and acids. These chemicals are encountered by almost all concrete structures. The present study has been undertaken to investigate the effect of attack of chlorides and sulphates with varying severity on compressive strength of ground granulated blast furnace slag (GGBFS) concrete after immersion in salt solution for 28 days. The results indicate that the durability of GGBFS concrete increases with the increase in percentage replacement of cement by GGBFS for 20% and then gradually decreases with increases in percentage of GGBFS with cement (as in the study for 40% and 60%). Also there is increase in strength of GGBFS concrete with increase in age. Thus the durability of concrete improves when GGBFS is added as partial replacement of cement. In this study the strength of GGBFS concrete is less affected by chemicals as compared to conventional concrete when exposed to aggressive environment.

• Journal of Electrochemical Science and Technology
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• 제12권4호
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• pp.440-452
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• 2021

Enhancement of durability and reduction of maintenance cost of concrete, with the implementation of various approaches, has always been a matter of concern to researchers. The integration of pozzolans as a substitute for cement into the concrete is one of the most desirable technique. Silica fume (SF) and colloidal nanosilica (CS) have received a great deal of interest from researchers with their significant performance in improving the durability of concrete. The synergistic role of the micro and nano-silica particles in improving the main characteristics of cemented materials needs to be investigated. This work aims to examine the utility of partial substitution of cement by SF and CS in binary and ternary blends in the improvement of the durability characteristics linked to resistance for electrochemical corrosion using electrical resistivity and half-cell potential analysis and chloride penetration trough rapid chloride penetration test. Furthermore, the effects of this silica mixture on the compressive strength of concrete under normal and aggressive environment have also been investigated. Based on the maximum compression strength of the concrete, the optimal cement substituent ratios have been obtained as 12% SF and 1.5% CS for binary blends. The optimal CS and SF combination mixing ratios has been obtained as 1.0% and 12% respectively for ternary blends. The ternary blends with substitution of cement by optimal percentage of CS and SF exhibited decreased rate for electrochemical corrosion. The strength and durability studies were found in consistence with the microstructural analysis signifying the beneficiary role of CS and SF in upgrading the performance of concrete.

• Steel and Composite Structures
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• 제48권6호
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• pp.649-666
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• 2023

In the current scenario, conventional concrete faces a substantial challenge in the modern era of the construction industry. Today's structures are massive, featuring innovative designs and strict time constraints. Conventional concrete does not provide the required compressive strength, tensile strength, flexural strength, toughness, and cracking resistance. As a result, most of engineers and professionals prefer to use ultra-high-performance concrete (UHPC), based on its wide advantages. Several advantages like mechanical and durability properties of UHPC provides dominant properties than the traditional concrete. Mix proportions of UHPC consists of higher powder content which provides maximum hydration and pozzolanic reaction, thereby contributing to the enhancement of the UHPC properties. Apart from that the nanomaterials provides the filler behavior, which will further improve the density. Enhanced density and mechanical properties lead to improved durability properties against water absorption and other typical chemicals. Nanomaterials are the most adopted materials for various applications, ranging in size from 0.1 nanometers to 100 nanometers. This article explores the effects of nanomaterial application in UHPC as a replacement for cementitious material or as an additive in the UHPC mix. The physical and durability properties modifications and improvements of UHPC, as well as negative effects, limitations, and shortcomings, are also analyzed.

• Steel and Composite Structures
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• 제31권1호
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• pp.69-83
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• 2019

This paper investigates the structural behavior of very high strength concrete encased steel composite columns via combined experimental and analytical study. The experimental programme examines stub composite columns under pure compression and eccentric compression. The experimental results show that the high strength encased concrete composite column exhibits brittle post peak behavior and low ductility but has acceptable compressive resistance. The high strength concrete encased composite column subjected to early spalling and initial flexural cracking due to its brittle nature that may degrade the stiffness and ultimate resistance. The analytical study compares the current code methods (ACI 318, Eurocode 4, AISC 360 and Chinese JGJ 138) in predicting the compressive resistance of the high strength concrete encased composite columns to verify the accuracy. The plastic design resistance may not be fully achieved. A database including the concrete encased composite column under concentered and eccentric compression is established to verify the predictions using the proposed elastic, elastoplastic and plastic methods. Image-oriented intelligent recognition tool-based fiber element method is programmed to predict the load resistances. It is found that the plastic method can give an accurate prediction of the load resistance for the encased composite column using normal strength concrete (20-60 MPa) while the elastoplastic method provides reasonably conservative predictions for the encased composite column using high strength concrete (60-120 MPa).

• Korean Chemical Engineering Research
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• 제61권1호
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• pp.45-51
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• 2023

PEMFC(고분자전해질 연료전지) 고분자막의 내구성을 향상시키기 위해서 라디칼 제거제와 지지체가 사용되고 있다. 본 연구에서는 화학적 내구성과 물리적 내구성을 향상시키기 위해서 해조류에서 추출한 후코이단과 가교제 역할을 하는 탄닌산을 첨가한 고분자막의 내구성을 평가하였다. 물리적 내구성은 인장강도를 측정해 확인했고, 화학적 내구성은 Fenton 실험으로 측정하였다. 막과 전극합체(MEA)를 제조하여 셀에서 가속 내구 평가를 통해 기계적 내구성과 화학적 내구성을 평가하였다. 인장강도 측정으로 후코이단과 탄닌산의 변형율과 항복강도 등을 향상시켜 고분자막의 기계적 내구성을 향상시킬 수 있음을 보였다. 후코이단이 라디칼 제거제 역할을 함을 Fenton 실험에서 확인했다. 단위전지에서 가속 내구 실험 결과 후코이단은 화학적 내구와 기계적 내구를 모두 향상시켜 무첨가막보다 가속 내구 평가 시간을 38.1% 증가시켰고, 탄닌산을 추가하면 기계적 내구성 향상에 의해 고분자막의 내구성이 13.9% 향상되었다.

• Advances in concrete construction
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• 제5권3호
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• pp.241-255
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• 2017

Concrete is known to be the most used construction material worldwide. The environmental and economic aspects of Ordinary Portland Cement (OPC) containing concrete have led research studies to investigate the possibility of incorporating supplementary cementitious materials (SCMs) in concrete. Metakaolin (MK) is one SCM with high pozzolanic reactivity generated throughout the thermal activation of high purity kaolinite clay at a temperature ranging from $500^{\circ}C$ to $800^{\circ}C$. Although many studies have evaluated the effect of MK on mechanical properties of concrete and have reported positive effects, limited articles are considering the effect of MK on durability properties of concrete. Considering the lifetime assessment of concrete structures, the durability of concrete has become of particular interest recently. In the present work, the influences of MK on mechanical and durability properties of concrete mixtures are evaluated. Various experiments such as slump flow test, compressive strength, water permeability, freeze and thaw cycles, rapid chloride penetration and surface resistivity tests were carried out to determine mechanical and durability properties of concretes. Concretes made with the incorporation of MK revealed better mechanical and durability properties compared to control concretes due to combined pozzolanic reactivity and the filler effect of MK.

• Computers and Concrete
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• 제29권 5호
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• pp.335-346
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• 2022

Geopolymers are an important alternative material supporting recycling, sustainability, and waste management. Durability properties are among the most critical parameters to be investigated; in this study, the durability of manufactured geopolymer samples under the attack of 10% magnesium sulfate and 10% sodium sulfate solution was investigated. 180 cycles of freezing and thawing were also tested. The experimentally obtained results investigate the durability of geopolymer mortar prepared with fly ash (class F) and alkali activator. Three different quarry dust wastes replaced the river sand aggregate: limestone, marble, and basalt powder as fine filler aggregate in three different replacement ratios of 25%, 50%, and 75% to produce ten series of geopolymer composites. The geopolymer samples' visual appearance, weight changes, UPV, and strength properties were studied for up to 12 months at different time intervals of exposure to sulfate solutions to investigate sulfate resistance. In addition, Scanning Electron Microscopy (SEM), EDS, and XRD were used to study the microstructure of the samples. It was beneficial to include quarry waste as a filler aggregate in durability and mechanical properties. The compact matrix was demonstrated by microstructural analysis of the manufactured specimens. The geopolymer mortars immersed in sodium sulfate showed less strength reduction and deterioration than magnesium sulfate, indicating that magnesium sulfate is more aggressive than sodium sulfate. Therefore, it is concluded that using waste dust interrogation with partial replacement of river sand with fly ash-based geopolymers has satisfactory results in terms of durability properties of freeze-thaw and sulfate resistance.

• 지질공학
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• 제34권1호
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• pp.67-105
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• 2024

This study compares the quartzites of four quartzite units: The Fagfog Quartzite, Dunga Quartzite (member of the Robang Formation), Pandrang Quartzite (member of the Kalitar Formation) and the Chisapani Quartzite. The analysis shows variations in flakiness and elongation, as the Fagfog Quartzite displays low flakiness whereas the Pandrang and the Chisapani have moderate and the Dunga Quartzite has shown variations. The density values of the four quartzite units remain consistent, indicating uniform physical properties and porosity levels. However, bulk density values differ among the quartzites, suggesting variations in particle arrangement, porosity, and density. Regarding strength measures, the Pandrang and the Chisapani Quartzite have higher strength characteristics as compared to the Fagfog and the Dunga Quartzites. The Pandrang Quartzite has the highest average point load strength index, classifying it as "Extremely Strong". The resistance to impact and crushing forces varies among the quartzites, with lower Aggregate Impact Value (AIV) and Aggregate Crushing Value (ACV) indicating higher strength and durability. Durability tests show that the Fagfog Quartzite has high durability against slaking, with a slight decrease observed after the fifth cycle. The Dunga Quartzite shows varying degrees of weathering, while the Pandrang and the Chisapani Quartzite have minimal weight changes, indicating strong resistance to weathering. Magnesium sulfate soundness tests indicate high durability and resistance to degradation for all four units. The Los Angeles abrasion value (LAAV) tests indicate favorable resistance to abrasion for the majority of the Fagfog, Dunga, and the Pandrang Quartzites samples, while Chisapani Quartzite shows more variability in LAAV values. The Pandrang Quartzite shows a higher proportion of elongated particles but lower flakiness index values as compared to Fagfog and Dunga Quartzites while Chisapani Quartzite stands out with a significantly higher presence of flaky particles and lower elongation index values. Mechanically, the Fagfog and Dunga Quartzite show higher strength and better resistance to abrasion and freeze and thaw. The Pandrang Quartzite shows moderate resistance to crushing and sudden effect, while the Chisapani Quartzite has variable resistance to effect. This comparative study emphasizes the diversity and complexity of quartzite rock types, showing the need for comprehensive characterization and assessment to determine their suitability for specific applications.

• International Journal of Concrete Structures and Materials
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• 제7권3호
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• pp.215-223
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• 2013

This study presents the effect of incorporating metakaolin (MK) on the mechanical and durability properties of high strength concrete for a constant water/binder ratio of 0.3.MK mixtures with cement replacement of 5, 10 and 15 % were designed for target strength and slump of 90 MPa and $100{\pm}25mm$. From the results, it was observed that 10 % replacement level was the optimum level in terms of compressive strength. Beyond 10 %replacement levels, the strength was decreased but remained higher than the control mixture. Compressive strength of 106 MPa was achieved at 10 % replacement. Splitting tensile strength and elastic modulus values have also followed the same trend. In durability tests MK concretes have exhibited high resistance compared to control and the resistance increases as the MK percentage increases. This investigation has shown that the local MK has the potential to produce high strength and high performance concretes.