• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2012.05a
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• pp.259-261
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• 2012

The effect of high-temperature on the flexural modulus of epoxy resin were evaluated using universal testing machine with 3-point bending and dynamic mechanical analyzer. Temperatures of $30^{\circ}C$, $100^{\circ}C$, and $140^{\circ}C$ were considered for flexural test. The specimens having aspect ratio of 16, 32, and 40 were used. The results of storage modulus from DMA were similar to those from flexural test along with given temperatures. It is found that the flexural modulus increased with increasing aspect ratio and the specimen having aspect ratio of above 32 would be suitable for the evaluation of composite material properties under high temperature condition.

• Journal of Pharmaceutical Investigation
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• v.36 no.1
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• pp.31-38
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• 2006

Using a Rheometries Dynamic Analyzer (RDA II), the dynamic viscoelastic properties of a semi-solid ointment base (vaseline) in large amplitude oscillatory shear flow fields were measured over a temperature range of $25{\sim}45^{\circ}C$ and the linear viscoelastic behavior in small amplitude oscillatory shear flow fields was investigated over a wide range of angular frequencies. In this article, the nonlinear viscoelastic behavior was reported from the experimentally obtained data and the effect of temperature on this behavior was discussed in detail. In addition, the angular frequency and temperature dependencies of a linear viscoelastic behavior were explained. Finally, the applicability of a time-temperature superposition principle originally developed for polymeric materials was examined using a shift factor. Main results obtained from this study can be summarized as follows : (1) At very small strain amplitude region, vaseline shows a linear viscoelastic behavior independent of the imposed deformation magnitudes. Above a critical strain amplitude $({\gamma}_{0}=0.1{\sim}0.2%)$, however, vaseline exhibits a nonlinear viscoelastic behavior ; indicating that both the storage modulus and dynamic viscosity are sharply decreased with increasing deformation magnitude. (2) In large amplitude oscillatory shear flow fields, an elastic behavior (storage modulus) has a stronger strain amplitude dependence and begins to show a nonlinear behavior at a smaller strain amplitude region than does a viscous behavior (dynamic viscosity). (3) In small amplitude oscillatory shear flow fields, the storage modulus as well as the loss modulus are continuously increased as an increase in angular frequency and an elastic nature is always superior to a viscous behavior over a wide range of angular frequencies. (4) A time-temperature superposition principle can successfully be applicable to vaseline. This finding allows us to estimate the dynamic viscoelastic behavior of vaseline over an extraordinarily extended range (11 decades) of angular frequencies inaccessible from the experimentally measured range (4 decades).

• Journal of the Korean Ceramic Society
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• v.35 no.7
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• pp.726-732
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• 1998

• Journal of the Korean Society for Nondestructive Testing
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• v.28 no.3
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• pp.279-284
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• 2008

The firmness of fruit is one of the most important quality factors and is highly correlated to the elastic modulus. In this study, the ultrasonic transmission method was applied to evaluate the elastic modulus of the apple. In order to transmit and receive the ultrasonic wave through the whole apple, the ultrasonic measurement setup consisted of ultrasonic pulser, two specially fabricated ultrasonic transducers for fruit and digital storage oscilloscope. Ultrasonic parameters such as ultrasonic wave velocity, apparent attenuation, and peak frequencies were analyzed. The elastic modulus of apple was measured by using compression test apparatus. The correlations between ultrasonic parameters and elastic modulus were analyzed. A multiple linear regression model describing the relationship between elastic modulus and ultrasonic parameters was proposed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.213-214
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• 2005

To measure modulus and damping of semiconductive materials in power cable, we have investigated the modulus and damping of semiconductive materials showed by changing the content of carbon black. Then they were produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[$kg/cm^2$]. The content of conduct ive carbon black was the vailable, and their contents were 20, 30 and 40[wt%], respectively. The modulus and $Tan\delta$ experiments were measured by DMA 2980. Ranges of measurement temperature from -50[$^{\circ}C$] to 100[$^{\circ}C$] and measurement frequency is 1[Hz]. The modulus of specimens was increased according to a increment of a carbon black content. And modulus was rapidly decreased at the glass transition temperature. The $Tan\delta$ of specimens was decreased according to a increment of a carbon black content.

• Advanced Composite Materials
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• v.16 no.4
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• pp.259-267
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• 2007

Mechanical reinforcement of an all-sustainable composite, composed of papyrus stem-milled particles as reinforcement and poly-L-lactic acid (PLLA) resin as matrix, was investigated. The papyrus particles (average diameter of $70{\mu}m$) could be well dispersed in PLLA resin up to 50 wt% without any surface modification. Young's modulus of the composite was 4.2 GPa at 50 wt% of the papyrus content. This is a two-fold increment in modulus as compared to that of the PLLA matrix. The tensile strength of the composite was almost constant around 48 MPa irrespective of the papyrus content. Temperature dependence of the storage modulus demonstrated that the incorporation of papyrus restricts the large drop in the modulus above the glass transition of PLLA.

• Food Science and Biotechnology
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• v.17 no.5
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• pp.1119-1121
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• 2008

The effects of storage time (0, 1, and 2 month) and temperature (5, 15, and $25^{\circ}C$) on the dynamic rheological properties of hot pepper-soybean paste (HPSP) mixed with acetylated starches (AS) were studied by small-deformation oscillatory measurements. Dynamic moduli (G', G", and $\eta^*$) values of HPSP-AS mixtures increased with an increase in storage time and also decreased with increasing storage temperature. However, dynamic moduli values of the control (no added AS) were independent on storage time and temperature. Tan $\delta$ values (ratio of G"/G') in all HPSP samples did not change much with an increase in storage time and temperature. After 2 months of storage, the dynamic moduli of the HPSP-AS mixture samples were much lower than those of the control, indicating that the addition of AS can inhibit the retrogradation that developed over a long period of storage. Structural and rheological properties of HPSP samples seem to be stabilized by the presence of AS.

• Journal of Adhesion and Interface
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• v.3 no.4
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• pp.1-9
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• 2002

The main goal of this study was to analyze the effect of process additives, i.e. maleated polypropylene (MAPP), and nucleating agent on the viscoelastic properties of different types of extruded polypropylene-wood plastic composites manufactured from either PP homopolymer, high crystallinity PP or PP impact copolymer using dynamic mechanical thermal analysis. And also, the esterification reaction between wood flour and maleated polypropylene, and its role in determining the mechanical properties of wood flour-polypropylene composites was investigated. The wood plastic composites were manufactured using 60% pine wood flour and 40% polypropylene on a Davis-Standard $Woodtruder^{TM}$. Dynamic mechanical thermal properties, polymer damping peaks(than ${\delta}$), storage modulus (E') and loss modulus (E") were measured using a dynamic mechanical thermal analyzer. XPS (X-ray Photoelectron Spectroscopy), also known as ESCA (Electron Spectroscopy for Chemical Analysis) study of wood flour treated with MAPP was performed to obtain information on the chemical nature of wood fiber before and after treatment. To analyze the effect of frequency on the dynamic mechanical properties of the various composites, DMA tests were performed over a temperature range of -20 to $100^{\circ}C$, at four different frequencies (1, 5, 10 and 25 Hz), and at a heating rate of $5^{\circ}C/min$. From these results, the activation energy of the various composite was measured using an Arrhenius relationship to investigate the effect of maleated PP and nucleating agent on the measurement of the interphase between the wood and plastic of the extruded polypropylene wood plastic composites.

• Fibers and Polymers
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• v.2 no.3
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• pp.141-147
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• 2001

The effect of compositions of isophorone diisocyanate (IPDl)/4.4'-diphenylmethane diisocyalate (MDI) and polypropylene oxide diol (PPG, $M_w$: 3000)/1,4-butane diol (BD) on the properties of UV-cured polyurethane acrylate films based on 2-hydroxyethyl acrylate (HEA) was examined. UV-curable polyurethane acrylates were formulated from the prepolymer. trimethylol propane triacrylate (TMPTA) as a reactive diluent, and 1-hydroxycyclohexyl ketone (Irgacure 184) as a photoinitiator. Dynamic mechanical thermal properties and elastic properties of UV-cured polyurethane acrylates was fecund to depend on the chemical composition of IPDl/MDl and PPG/BD. As the BD content increased, the tensile storage modulus of all series samples increased significantly. The storage modulus increased in the order of samples A (IPDI based samples)> samples B (IPDI/MDl (7/3 molar ratio) based samples) > samples C (IPDI/MDl (5/5 molar ratio) based samples at the same composition. Two distinct louts modulus peaks for all samples are observed owing to the softs segment glass transition temperature ($T_gh$) and hard segment glass transition temperature ($T_gh$). The difference between $T_gh$, and $T_gh$, (Δ$T_g$) increases in the order of A > B > C at the same composition. In cycle test, the initial onset strain (%) was found to decrease with increasing BD content in PPG/BD and with increasing MDI content in IPDI/MDl.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.11b
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• pp.210-215
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• 2002

MR(Magnetorheogical) fluid composed of fine iron powders dispersed in silicon oil is utilized to many smart structures and devices because of its significant rheological property change by the application of an external magnetic field. When we deal with the shock wave attenuation of warship structures, we should be able to characterize the high frequency behavior of MR fluids. So far, however, many efforts have been focused on the material characterization of MR fluids at low frequencies below 100Hz. In this paper, the MR fluid property characterization at high frequency region is performed. An experimental setup based on wave transmission technique is made and the storage modulus as well as the loss modulus of MR fluids are found from the measured data of speed sound and attenuation. Details of the experiment are addressed and the obtained storage and loss moduli are addressed at $50kHz{\sim}100kHz$.