• 한국수소및신에너지학회논문집
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• 제14권1호
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• pp.1-7
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• 2003

In this study, activity changes of $Ni/Ce-ZrO_2$ catalyst for steam reforming reaction in the various steam treatment condition were investigated and BET, XRD and XPS analysis were introduced to characterize the catalyst before and after treatment. Activity test showed that $Ni/Ce-ZrO_2$ catalyst had good activity after reduction in steam reforming reaction but deactivated rapidly after steam treatment at high temperature. Activities of deactivated catalyst by steam was recovered to die previous activity level after reduction using hydrogen rich gas. It was observed that catalytic activity was preserved after repeated steam treatment, too. It showed that change of catalytic activity due to steam treatment is perfectly reversible. From the BET, XRD and XPS analysis, deactivation of $Ni/Ce-ZrO_2$ catalyst was due to the transition from Ni, that is activity site for steam reforming reaction, to $NiAl_2O_4$ in steam treatment at high temperature.

• 한국수소및신에너지학회논문집
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• 제21권6호
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• pp.493-499
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• 2010

Steam reforming (SR) of glycerol, a main by-product of manufacturing process of bio-diesel, for the production of hydrogen was investigated over the Ni-based catalysts. The Ni-based catalysts were prepared by an impregnation method, and characterized by $N_2$ physisorption, CO chemisorption, XRD and TEM techniques. It was found that the Ni/${\gamma}-Al_2O_3$ catalyst showed higher conversion and catalytic stability for the carbon formation than the other catalysts in the steam reforming of glycerol under the tested conditions. The results suggest that the steam reforming of glycerol over modified Ni/${\gamma}-Al_2O_3$ catalyst minimized carbon formation can be applied in hydrogen station for fuel-cell powered vehicles and fuel processor for stationary and portable fuel cells.

• 한국수소및신에너지학회논문집
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• 제15권4호
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• pp.301-308
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• 2004

The methane reforming with $CO_2$ and steam for manufacture of synthesis gas over $Ni/ZrO_2$ catalyst was investigated. Mixed reforming carried out $CO_2$ dry reforming with $O_2$ and steam for development of DME process in pilot plant. To improve a catalyst deactivation by coke formation, the mixed reforming added carbon dioxide and steam as a oxidizer of the methane reforming was suggested. The result of experiments over commercial catalyst in $CO_2$ dry reforming has shown that the catalyst activity decrease rapidly after 20 hours. In case of $NiO-MgO/Al_2O_3$ catalyst, the deactivation of 20 percent after 30 hours was occurred. The activity of Ni/C catalyst still was not decreased dramatically after 100 hours. The effect of $H_2$ reforming with steam over $Ni/CO_2$ catalyst obtained the optimal conversion of methane and carbon dioxide, and could be produced synthesis gas at ratio of $H_2/CO$ under 1.5.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.172-175
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• 2006

Steam reforming of methane using Xe-arc solar simulator was studied for converting solar radiation into energy foam that one can readily utilize. The Xe-arc lamp produce a spectrum similar to that of the sun. SiC ceramic foam, resist high temp.$(>900^{\circ}C)$, is used to catalytically active foam absorber, and to support of reforming catalyst. The catalyst on the surface of foam were directly irradiated with solar simulated xe-light in order to carry out the steam reforming of methane. The reactor was made of stainless steel and quartz window was located on a place of the xe-light irradiation and temperature was controlled using K-type thermocouple in contact with catalyst located inside the reactor. The result show that a possibility of solar reforming using catalytically active foam absorber is exist.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.63-66
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• 2007

Reformers which produce hydrogen from natural gas are essential for the operation of residential PEM fuel cells. For this purpose, steam-methane reforming reactions with Ni catalysts is primarily utilized. Commercial Ni catalysts are generally made to have porous pellet shapes in which Ni catalyst particles are uniformly dispersed over Alumina support structures. This study numerically investigates the reduction of catalyst effectiveness due to the mass transport resistances posed by porous structures of spherical catalyst pellets. The multi-component diffusion through porous media and the accurate kinetics of reforming reaction is fully considered in the numerical model. The preliminary results on the variation of the effectiveness factor according to different operation conditions are presented, which is planned to be used to develop correlations in future studies.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.477-480
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• 2006

In this study, we investigated operating characteristics of the LNG burner for steam methane reforming. The developed LNG burner and catalytic reactor to supply an efficient heat transfer between the combustion gas and catalyst got a good response of various operating load within 5-7 minute and high efficiency for steam methane reforming as a conversion of methane over 90%. We calculated the volume of catalyst for $1Nm^3/hr$ steam LNG reforming as $211cc/(Nm^3/hr\;H_2)$ and got the operating condition and design data of the burner and steam reforming for LNG.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.129-136
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• 2017

Characteristics of $ZrO_2$ felt supported Cu/Zn catalysts have been investigated for the production of hydrogen via methanol steam reforming. Cu and Zn in different weight percent were loaded using wet impregnation over $ZrO_2$ felt support. The catalysts were characterized with BET and FE-SEM. The performance of these synthesized catalysts were investigated at SCR=1.5, $GHSV=2000h^{-1}$, temperature=$300{\sim}400^{\circ}C$, and pressure=2.5~19.5 barA. The results showed that the $Cu^{32.5}Zn^{7.5}ZrO_2$ catalyst was most active in terms of methanol conversion and hydrogen production. The methanol conversion in steam reforming of methanol was 84.6% at 19.5 barA and furnace $400^{\circ}C$ over $Cu^{32.5}Zn^{7.5}ZrO_2$ catalyst. The catalysts prepared using $ZrO_2$ felt show higher reactor temperature than the pellet type catalyst at same furnace temperature.

• 신재생에너지
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• 제19권2호
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• pp.1-12
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• 2023

In this study, an efficient one-dimensional model was developed for predicting microchannel steam/methane reformers with thin washcoat catalyst layers with a focus on low-pressure reforming conditions suitable for distributed hydrogen production systems for fuel cell applications. The governing equations for steam/methane mixture gas flowing through the microchannel reformer were derived considering the species conservation with reforming reactions and energy conservation with external convective heat supply. The reaction rates for the developed model were simply determined through the catalyst effectiveness factor correlations instead of performing complicated calculations for the steam/methane reforming process occurring inside the washcoat catalyst layers. The accuracy of the developed was verified by comparing the results obtained herein with those obtained by the detailed computational fluid dynamics calculation for the same microchannel reformer.

• 한국수소및신에너지학회논문집
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• 제31권2호
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• pp.202-209
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• 2020

In methanol steam reforming, commercial catalysts in the form of pellets are mainly used, but there are limitations to directly apply them to underwater weapon systems that require shock resistance and heat transfer characteristics. In this study, to overcome this problem, a multi-layer cup structure (MLCS) was applied to support a pellet type catalyst. The characteristics of pellet catalyst supported by MLCS and the pellet catalyst supported by conventional structure (CS) were compared by the reforming experiment. In the case of MLCS, a high methanol conversion rate was shown in the temperature range 200 to 300℃ relative to the CS manufactured with the same catalyst weight as MLCS. CS shown similar characteristics to MLCS when it manufactured in the same volume as MLCS by adding an additional 67% of the catalyst. In conclusions, MLCS can not only reduce catalyst usage by improving heat transfer characteristics, but also support pellet catalyst in multiple layers, thus improving shock resistance characteristics.

• Korean Chemical Engineering Research
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• 제59권2호
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• pp.232-238
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• 2021

The development of a low cost catalyst with high performance and small amount of carbon deposition on catalyst from toluene steam reforming were investigated by using coal ash as a support material. Ni-loaded coal ash catalyst showed similar catalytic activity for toluene steam reforming compared with the Ni/Al2O3. At 800 ℃, the toluene conversion was 77% for Ni/TAL, 68% for Ni/KPU and 78% for Ni/Al2O3. Ni/TAL showed similar toluene conversion to Ni/Al2O3. However, Ni/KPU produced higher hydrogen yield at relatively lower toluene conversion. Ni/KPU catalyst showed a remarkable ability of suppressing the carbon deposition. The difference in coke deposition and hydrogen yield is due to the composition of KPU ash (Ca and Fe) which increase coke resistance and water gas shift reaction. This study suggests that coal ash catalysts have great potential for the application in the steam reforming of biomass tar.