• Title/Summary/Keyword: Stability Agent

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Analysis of cyanide free electroless Au plating solution by capillary elecrophoresis (캐피라리 전기 영동법에 의한 비시안 무전해 Au 도금액의 분석)

  • Han, Jaeho;Kim, DongHyun
    • Journal of the Korean institute of surface engineering
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    • v.55 no.2
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    • pp.120-132
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    • 2022
  • In the non-cyanide-based electroless Au plating solution using thiomalic acid as a complexing agent and aminoethanethiol as a reducing agent, analysis of each component constituting the plating solution is essential for the analysis of the reaction mechanism. And component analysis in the plating solution is important for monitoring component changes in the plating process and optimizing the management method. Capillary Electrophoresis (CE) method is rapid, sensitive and quantitative and could be readily applied to analysis of Aun+ ion, complexing agent and reducing agent in electroless Au plating solution. In this study, the capillary electrophoresis method was used to analyze each component in the electroless Au plating solution in order to elucidate the complex bonding form and the plating mechanism of the non-cyanide-based electroless Au plating bath. The purpose of this study was to establish data for optimizing the monitoring and management method of plating solution components to improve the uniformity of precipitation and stability. As a result, it was confirmed that the analysis of thiomalic acid as a complexing agent and Aun+ ions and the analysis of aminoethanethiol as a reducing agent were possible by capillary electrophoresis. In the newly developed non-cyanide-based electroless Au plating solution, it was confirmed that Aun+ ions exist in the form of Au+ having a charge of +1, and that thiomalic acid and Au+ are combined in a molar ratio of 2 : 1. In addition, it was confirmed that aminoethanethiol can form a complex by combining with Au+ ions depending on conditions as well as acting as a reducing agent.

Multi-agent Q-learning based Admission Control Mechanism in Heterogeneous Wireless Networks for Multiple Services

  • Chen, Jiamei;Xu, Yubin;Ma, Lin;Wang, Yao
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.7 no.10
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    • pp.2376-2394
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    • 2013
  • In order to ensure both of the whole system capacity and users QoS requirements in heterogeneous wireless networks, admission control mechanism should be well designed. In this paper, Multi-agent Q-learning based Admission Control Mechanism (MQACM) is proposed to handle new and handoff call access problems appropriately. MQACM obtains the optimal decision policy by using an improved form of single-agent Q-learning method, Multi-agent Q-learning (MQ) method. MQ method is creatively introduced to solve the admission control problem in heterogeneous wireless networks in this paper. In addition, different priorities are allocated to multiple services aiming to make MQACM perform even well in congested network scenarios. It can be observed from both analysis and simulation results that our proposed method not only outperforms existing schemes with enhanced call blocking probability and handoff dropping probability performance, but also has better network universality and stability than other schemes.

Effects of Coal Fly Ash as a Bulking Agent under Co-composting with Swine Manure and Saw Dust

  • Lee, Chang Hoon;Park, Seong Jin;Kim, Myung Sook;Yun, Sun Kang;Sonn, Yeon Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.5
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    • pp.356-361
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    • 2014
  • The coal fly ash (CFA) may be utilized as an extender for organic waste composting at the same time fully expected to solve all industrial waste disposal and sawdust tribe. The main objective in this study was to evaluate the effect of CFA addition as a bulking agent for swine manure composting. To determine the suitable addition rate of CFA as a bulking agent, 0, 10, 20 and 30% of saw dust were mixed with 30, 20, 10 and 0% of coal fly ash, respectively. Compost quality for swine manure composting was to evaluate temperature, pH, C/N ratio, and phytotoxicity as germination index. Stability of compost increased with increasing levels of CFA as bulking agent during swine manure composting due to the high alkaline materials including CFA. C to N ratio in treatment added CFA was higher than that of the control without CFA. After finishing composting, germination index of lettuce and cabbage in swine manure compost added 10% of CFA was similar to the control, all the heavy metal contents were far below the stipulated standard for organic farming. These results indicated tahr coal fly ash as bulking agents might be alternative materials to save saw dust and apply industrial products for swine manure composting.

A Dynamic Pricing Negotiation Model in the Online Ticket Resale Market (온라인 티켓 재판매 시장에서의 Dynamic Pricing 협상모델)

  • Cho, Jae-Hyung
    • The Journal of Society for e-Business Studies
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    • v.14 no.4
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    • pp.133-148
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    • 2009
  • This study has tried to suggest a new model that can effectively redistribute the tickets in the online ticket resale market, while suggesting a new allocation mechanism based on an agent negotiation. To this end, this study has analyzed an auction in the online ticket resale market through Game theory. As a result of new agent mechanism, it has been proved that the price stability of ticket resale market leads to an increase. An agent negotiation helps to stabilize the ticket prices that are usually inclined to rise at auction, benefiting all the participants in the negotiations, consequently showing a Pareto solution. Especially, a framework for a negotiation process is suggested and domain and processes ontology are designed interrelatedly. With this modeling, a possibility of Ontology based agent negotiation is suggested.

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Mechanical Properties of Talc-Filled Polypropylene : Coupling Agent Effect (Talc로 충전된 폴리프로필렌의 기계적 물성 : 커플링제 효과)

  • 김주성;최미애;박태욱;김덕준
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.770-776
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    • 2000
  • The effect of unreactive coupling agent on mechanical and thermal properties of talc-filled polypropylene (PP) composites was studied. Stearic and oleic acids were introduced as coupling agents, and tensile, flexural, and impact strength, thermal stability and melting transition temperature were measured and analyzed according to the types and concentration of coupling agents. Tensile and flexural strength were enhanced by introduction of coupling agent and the maximum effect was observed at the concentration of 3 wt% of coupling agent. Tensile and flexural strength of PP treated with oleic acid were higher than those of PP treated with stearic acid. but impact strength vice-versa. The reasons for these results were postulated by analyzing morphologies of talc-filled PP observed by SEM.

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A Study on the Corrosion Effects by Addition of Complexing Agent in the Copper CMP Process

  • Kim, Sang-Yong;Kim, Nam-Hoon;Kim, In-Pyo;Chang, Eui-Goo;Seo, Yong-Jin;Chung, Hun-Sang
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.6
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    • pp.28-31
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    • 2003
  • Copper CMP in terms of the effect of slurry chemicals (oxidizer, corrosion inhibitor, complexing agent) on the process characteristics has been performed. Corrosion inhibitors, benzotriazole (BTA) and tolytriazol (TTA) were used to control the removal rate and avoid isotropic etching. When complexing agent is added with H$_2$O$_2$ 2 wt% in the slurry, the corrosion rate was presented very well. In the case of complexing agent, it was estimated that the proper concentration is 1 wt%, because the addition of tartaric acid to alumina slurry causes low pH and the slurry dispersion stability become unstable. There was not much change of the removal rate. It was assumed that BTA 0.05 wt% is suitable. Most of all, it was appeared that BTA is possible to be replaced by TTA. TTA was distinguished for the effect among complexing agents.

Collaboration and Node Migration Method of Multi-Agent Using Metadata of Naming-Agent (네이밍 에이전트의 메타데이터를 이용한 멀티 에이전트의 협력 및 노드 이주 기법)

  • Kim, Kwang-Jong;Lee, Yon-Sik
    • The KIPS Transactions:PartD
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    • v.11D no.1
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    • pp.105-114
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    • 2004
  • In this paper, we propose a collaboration method of diverse agents each others in multi-agent model and describe a node migration algorithm of Mobile-Agent (MA) using by the metadata of Naming-Agent (NA). Collaboration work of multi-agent assures stability of agent system and provides reliability of information retrieval on the distributed environment. NA, an important part of multi-agent, identifies each agents and series the unique name of each agents, and each agent references the specified object using by its name. Also, NA integrates and manages naming service by agents classification such as Client-Push-Agent (CPA), Server-Push-Agent (SPA), and System-Monitoring-Agent (SMA) based on its characteristic. And, NA provides the location list of mobile nodes to specified MA. Therefore, when MA does move through the nodes, it is needed to improve the efficiency of node migration by specified priority according to hit_count, hit_ratio, node processing and network traffic time. Therefore, in this paper, for the integrated naming service, we design Naming Agent and show the structure of metadata which constructed with fields such as hit_count, hit_ratio, total_count of documents, and so on. And, this paper presents the flow of creation and updating of metadata and the method of node migration with hit_count through the collaboration of multi-agent.

EFFECT OF ANTIOXIDANT ON THE STABILITY AND EFFICACY ON ANTI-WRINKLE OF INDOLE-3-ACETIC ACID

  • H. S. Jung;Park, Y. H.;Kim, J. H.;Park, K. H.;J. S. Koh;Kim, E. J.
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.617-629
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    • 2003
  • A recent development in cosmetics has been the pursuit of wrinkling in the skin. The cosmetics composed of anti-wrinkle agent stand out from the point of view of environmental contamination and pollution. Among them, Indole-3-acetic acid (IAA), studied with wrinkling pigmentation and swelling conditions in the area of the eye, showed clinically significant reduction in depth of lines during one month trial using skin treatment. But, IAA has shown some problems when used in cosmetic formulations, such as stability, permeability and toxicity. The results of the clinical examination were shown that its permeability and toxicity didn't matter. To increase the stability of IAA, antioxidants such as Licorice, ubiquinone, tocopherol, Baicalin, ferulic acid, BHT, ascorbic acid, sodium metabisulfite, and so on were employed in cosmetic formulations. Our main purpose is the study for the stability efficiency and effect of each other of cream formulations containing optimal dosage antioxidants (o/w type emulsion), This study evaluated wrinkle reduction effect of IAA, which is used in cosmetics.

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Preparation and Characterization of Chemically Stable PVDF-HFP Asymmetric Microfiltration (MF) Membranes

  • Lee, Yeon-Ee;JeGal, Jong-Geon
    • Membrane Journal
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    • v.22 no.2
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    • pp.104-112
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    • 2012
  • Chemically stable Polyvinylidene fluoride-hexa-fluoropropane (PVDF-HFP) copolymer asymmetric membranes were prepared by the conventional phase inversion process, using Dimethyacetamide (DMAc) as a solvent and water as a non-solvent. To control the pore size and porosity of the PVDF-HFP membranes, tetra-ethoxysilane (TEOS) was used as a pore-forming agent. The prepared membranes were characterized, using several analytical methods such as Fourier Transform Infrared spectroscopy (FTIR), Thermo-gravimetric analyzer (TGA), Field Emission Scanning Electronic Microscopy (FESEM). TEOS turned out to increase porosity and make homogeneous pores on the membranes. Depending on the composition of the dope solutions, the pore size was ranged from 0.1 to 1.0 ${\mu}m$. The flux of the PVDF-HFP membranes prepared by using TEOS as a pore forming agent was increased substantially without much decrease in the rejection. When 15 wt% PVDF-HFP solution was blended with 13 wt% TEOS solution at composition ratio of 70/30 in wt%, the water flux at 2 bars was about 2 $m^3/m^2day$.

Synthesis of L-Ascorbic Acid Derivative Including 3-Aminopropane Phosphoric Acid as a Novel Whitening Agent

  • Kang, Hak-Hee;Oh, Seong-Geun
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1169-1171
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    • 2003
  • A stable derivative of L-ascorbic acid, 2-O-[(3-aminopropyl)phosphinooxy]-L-ascorbic acid (LAAP), was synthesized in moderate yield and its chemical stability and effects on melanin synthesis were investigated. LAscorbic acid was decomposed completely within about 1 hour, while 93% of LAAP remained even after 10 days. Treatment of L-ascorbic acid and LAAP decreased melanin content in normal human melanocytes to 33.8% and 49.1% of control at 2 mM, respectively. Considering chemical instability of L-ascorbic acid, LAAP is a much better whitening agent.