• Title/Summary/Keyword: Sr-85

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Optimal Conditions for Pretreated Sample for Sr Isotope Analysis by MC-ICP-MS: A Comparison Between Eichrom (SR-R50-S)'s and Bio-Rad(AG®50W-X8)'s Resins (다검출기 유도결합 플라즈마 질량분석기에 의한 Sr 동위원소 분석을 위해 전처리된 시료의 최적 조건: Eichrom사 Sr 수지(SR-R50-S)와 Bio-Rad사 수지(AG®50W-X8) 비교)

  • Myoung Jung, Kim;Seung-Gu, Lee
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.4
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    • pp.507-520
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    • 2022
  • The Sr isotope ratio, which is used as basic data for rock formation time, crustal and mantle evolution studies, is determined by mass spectrometer such as thermal ionization mass spectrometry (TIMS) or multi-detector inductively coupled plasma mass spectrometry (MC-ICP-MS). In this technical report, we compared how incomplete chemical separation of elements affects the determination of Sr isotope ratios. For the experiment, commercial resin, NBS987(NIST SRM987) Sr isotope standard, and rock standard samples from the Geological Survey of Japan (GSJ) such as JG1a, JB3 and JA1 were used. As a result of the comparative experiment, it was clearly observed that the measured values of 87Sr/86Sr change when Rb remains due to incomplete separation of the NBS987 Sr isotope standard sample as well as the rock standard samples of GSJ. This indicates that complete separation is an important factor since the calculated value deviates from the true value even though correction for isotope interference by isobar is performed when measuring the isotope ratio with MC-ICP-MS. This also suggests that, when reporting the measurement result of Sr isotope ratio using MC-ICP-MS, the measurement strength of 85Rb should be reported together with the measurement strength of all isotopes of Sr so that isotope interference by isobar can be judged.

Study on the Sr-ferrite sintered magnets using mill scale (밀 스케일을 활용한 Sr-페라이트 소결자석의 연구)

  • 조태식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.82-85
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    • 2002
  • High-quality Sr-ferrite sintered magnets have been studied by using mill scale added SrCO$_3$ and oxidents before oxidation process. The pre-added SrCO$_3$ powders were improved the degree of oxidation and crush of mill scale and the magnetic properties of Sr-ferrite sintered magnets. The small added NaNO$_3$ oxidant was also highly improved the degree of oxidation and crush of mill scale and the magnetic properties of Sr-ferrite sintered magnets; 3805 G of remanent flux density, 3240 Oe of intrinsic coercivity, and 3.45 MGOe of maximum energy product.

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The Effect of Calcium and Chitosan Metabolism to the Excretion of Radiostrontium in Mice (마우스에서 칼슘 및 Chitosan metabolism이 방사성스트론튬의 체외배출 효과에 미치는 명향)

  • Kim, Young-Ho;Bom, Hee-Seung;Kim, Ji-Yeul;Roh, Young-Bok
    • Journal of Radiation Protection and Research
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    • v.22 no.1
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    • pp.9-14
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    • 1997
  • Chitosan, a natural nontoxic chelator, was reported to reduce whole body retention of radiostrontium in mice. As calcium has a simillar chemical properties to strontium both of which be easily bound with hydroxyapatite structure, calcium can be either a competitor or enhancer to chitosan on the removal of radiostrontium. We compared the effect of chitosan and calcium on the excretion of ingested radiostrontium ($^{85}$Sr). Chitosan or calcium($Cacl_2$) and usual food was mixed as 1:99 by weight. The mixed food to chitosan (group 1) or calcium (group 2) were given orally for 30 days before $^{85}$Sr administration. In other groups, mixed calcium and chitosan solution (group 3), 1% calcium (group 4), or 1% chitosan solution (group 5) was given for 7 days immediately after oral administration of $^{85}SrC1_2$ ($0.25{\mu}Ci$). In control group, no chitosan or calcium were given. Either chitosan or calcium was effective on the removal of $^{85}Sr$ from mouse body(Table. 1). Addition of calcium on chitosan did not improve or deteriorate the effect of chitosan on the removal of $^{85}Sr$ from mouse body. In conclusion, calcium was similarly effective on the removal of $^{85}Sr$ from mouse body.

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Contamination of Chinese Cabbage with $^{85}Sr$, $^{103}Ru$ and $^{134}Cs$ Related to Time of Foliar Application ($^{85}Sr$, $^{103}Ru$, $^{134}Cs$의 엽면처리 시기에 따른 배추의 방사능 오염)

  • Choi, Yong-Ho;Lim, Kwang-Muk;Park, Hyo-Guk;Lee, Won-Yun;Lee, Chang-Woo
    • Journal of Radiation Protection and Research
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    • v.23 no.4
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    • pp.219-227
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    • 1998
  • A solution containing $^{85}Sr$, $^{103}Ru$ and $^{134}Cs$ was applied to Chinese cabbage in a greenhouse via foliar spraying at 5 different times during its growth. Interception of the applied activity by plant showed no difference among radionuclides and increased with decreasing time interval between application and harvest. The maximum interception factor observed was 0.87. Percentages of the intercepted activity remaining in the whole leaves at harvest varied $16{\sim}58%$ for $^{85}Sr$, $15{\sim}73%$ for $^{103}Ru$ and $33{\sim}64%$ for $^{134}Cs$, with application time and those for the inner leaves (without 6 outmost leaves) varied $2{\sim}35%$, $0.4{\sim}46%$ and $14{\sim}40%$, respectively. It was demonstrated that rain plays an important role in weathering loss of the activity. Tying the upper end of the plant prior to the last application lowered interception and remaining activity in the inner leaves by factors of $3{\sim}4$. Present results can be referred to in predicting the radionuclide concentration in Chinese cabbage and deciding counter-measures at the time of an accidental release from the nuclear installation.

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Underground Migration of $^{54}Mn,\;^{60}Co,\;^{85}Sr\;and\;^{137}Cs$ Deposited during the Growth of Major Crop Plants (주요 작물의 생육중에 침적한 $^{54}Mn,\;^{60}Co,\;^{85}Sr,\;^{137}Cs$ 의 지하이동)

  • Choi, Yong-Ho;Jo, Jae-Seong;Lee, Chang-Woo;Lee, Myung-Ho;Kim, Sang-Bog;Hong, Kwang-Hee;Choi, Geun-Sik;Lee, Jeong-Ho
    • Journal of Radiation Protection and Research
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    • v.21 no.1
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    • pp.51-58
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    • 1996
  • Underground migration of $^{54}Mn,\;^{60}Co,\;^{85}Sr\;and\;^{137}Cs$ in paddy and upland conditions was studied through two years' greenhouse experiment. At early and late growth stages of rice, soybean, Chinese cabbage and radish, a mixed solution of the radionuclides was applied to the water or soil surfaces of the culture boxes filled with an acidic loamy-sandy soil for the upper 20cm. Soil was sampled in layers upto $15{\sim}20cm$ down after harvest. Soil concentrations of the radionuclides decreased exponentially with increasing soil depth and more than 80% of the radioactivities remained in top $3{\sim}4cm$. The mobility of the radionuclides decreased in the order of $^{85}Sr>^{54}Mn>^{60}Co{\geq}^{137}Cs$. Downward migrations of the radionuclides were the greatest in rice soil and the lowest in soybean soil which was fertilized with the least amount of N, P and K. Differences in depth profiles between two application times indicate that the amount of daily migration from $0{\sim}1cm$ layer to the lower area decreases with increasing time after deposition. By a simultaneous addition of KCl and lime following the earlier application, downward migration in soybean, Chinese cabbage and radish soils changed little or retarded more or less but that in rice soil accelerated a little.

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Cell Properties for SOFC Using Synthesized Powder of Electrolyte LSGM System and Cathode LSM System (LSGM 전해질과 LSM 양극의 합성분말을 이용한 SOFC 단위전지의 특성)

  • Lee, Mi-Jai;Nam, Jeong-Hee;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.39 no.4
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    • pp.359-366
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    • 2002
  • The purpose of this study is to investigate the properties of LSGM electrolyte and LSM cathode. The unit cell based on the optimum conditions and processing for high performance was fabricated and measured. The single phase of $LaGaO_3$ was obtained on sintering at $1500^{\circ}$ for 6h with composition of $(La_{0.85}Sr_{0.15})(Ga_{0.8}Mg_{0.2})O_{3-\delta}와 (La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$ and $(La_{0.85}Sr_{0.15})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$. The grain size of the sintered body was about $10∼30{\mu}m$ and electrical conductivity was 0.13 S/cm measured at $800^{\circ}$. The single phase of $LaMnO_3$ structure in $(La1-xSrx)MnO_3$ system was obtained at x=0∼0.2 and the particle size of the synthesized powder was about 40 nm. The unit cell was prepared by firing at $1200^{\circ}$ for 1h with $(La_{0.9}Sr_{0.1})MnO_3$ cathode and 0.9NiO-0.1YSZ anode screen-printed on surfaces of $(La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$ electrolyte. The grain size of the electrode was close to $1{\mu}m$ and the electrode had porous structure. The maximum power density of unit cell showed $0.3W/cm^2$ at $800^{\circ}$.

Positron Annihilation Study of Vacancy Type Defects in Ti, Si, and BaSrFBr:Eu

  • Lee, Chong Yong
    • Applied Science and Convergence Technology
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    • v.25 no.5
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    • pp.85-87
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    • 2016
  • Coincidence Doppler broadening and positron lifetime methods in positron annihilation spectroscopy has been used to analyze defect structures in metal, semiconductor and polycrystal, respectively. The S parameter and the lifetime (${\tau}$) value show that the defects were strongly related with vacancies. A positive relationship existed between the scanning electron microscope (SEM) images and the positron annihilation spectroscopy (PAS). According to the SEM images and PAS results, measurements of the defects with PAS indicate that it was more affected by the defect than the purity.

The Measurement of National Standard ${\beta}$-Rays Energy Spectrum (기준 베타선장의 에너지 스펙트럼 측정)

  • Kim, Chul-Hang;Yi, Chul-Young;Kim, Hyun-Moon;Hah, Suck-Ho;Jeon, Gook-Jin
    • Progress in Medical Physics
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    • v.23 no.4
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    • pp.285-291
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    • 2012
  • In the present study, we measured the pure beta particle energy spectra of $^{147}Pm$, $^{85}Kr$, $^{90}Sr+^{90}Y$ radionuclide sources. We confirmed the residual maximum energies of KRISS sources meet the requirement of ISO 6980 and calculated mass collision stopping power ratio, which is essential for absolute measurement of absorbed dose from the reference ${\beta}$-rays. The residual maximum energies of KRISS $^{147}Pm$, $^{85}Kr$, $^{90}Sr+^{90}Y$ sources are 0.14, 0.57 and 0.93 MeV, respectively and the mass collision stopping power ratios are 1.123, 1.120 and 1.109, respectively.

Soil-to-Plant Transfer of $^{54}Mn,\;^{60}Co,\;^{85}Sr$ and $^{137}Cs$ Deposited during the Growing Season of Potato (감자의 재배기간 중 토양에 침적한 $^{54}Mn,\;^{60}Co,\;^{85}Sr,\;^{137}Cs$의 작물체로의 전이)

  • Choi, Yong-Ho;Lim, Kwang-Muk;Jun, In;Keum, Dong-Kwon
    • Journal of Radiation Protection and Research
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    • v.33 no.3
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    • pp.105-112
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    • 2008
  • To measure the soil-to-plant transfer factors ($TF_a,\;m^2\;kg^{-1}$-fresh) of radionuclides deposited during the growing season of potato, a radioactive solution containing $^{54}Mn,\;^{60}Co,\;^{85}Sr$ and $^{137}Cs$ was applied to the soil surfaces in soil boxes 2 d before seeding and three different times during the plant growth. For the pre-seeding application (PSA), radionuclides were mixed with the topsoil (loamy sand and 5.2 in pH). The plant parts investigated were leaves, stems, tuber skin and tuber flesh. The $TF_a$ values of $^{54}Mn,\;^{60}Co,\;^{85}Sr$ and $^{137}Cs$ from the PSA were in the ranges of $1.9{\times}10^{-4}{\sim}1.5{\times}10^{-2}$, $1.8{\times}10^{-4}{\sim}7.5{\times}10^{-4}$, $4.0{\times}10^{-4}{\sim}1.6{\times}10^{-2}$, $1.5{\times}10^{-4}{\sim}3.9{\times}10^{-4}$ respectively, for different plant parts. The TFa values from the growing-time applications were on the whole a few times lower than those from the PSA. For $^{54}Mn,\;^{85}Sr$ and $^{137}Cs$, the $TF_a$ values from the early- or middle-growth-stage application were higher than those from the late-growth-stage application, whereas the opposite was true for $^{60}Co$. Leaves and tuber flesh had the highest and lowest $TF_a$ values, respectively, in most cases. The total uptake from soil by the four plant parts was in the range of $0.05{\sim}3.16%$. In the third year following the PSA, the $TF_a$ values of $^{54}Mn,\;^{60}Co$ and $^{137}Cs$ were $11{\sim}25%$, $21{\sim}25%$ and $38{\sim}67%$ of those in the first year, respectively, depending on the plant parts. The present results can be used for estimating the radiological impact of an acute radioactive deposition during the growing season of potato and for testing the validity of relevant food-chain models.

Nd Model Age and Nd Isotopic Evidence of Granitoid Rocks in the Gwangju-Naju Area, Korea (광주-나주지역 화강암류에 대한 네오디움 표본연령 및 동위원소 특성연구)

  • Park, Young Seog
    • Economic and Environmental Geology
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    • v.30 no.2
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    • pp.153-161
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    • 1997
  • Diagrams of $^{87}Sr/^{86}Sr$ versus Ba/Nb and MgO/FeO are scattered, and $^{87}Sr/^{86}Sr$ variation with the increase of $SiO_2$ are scattered in Gwangju granitoid. Diagrams of $(^{87}Sr/^{86}Sr)$i versus $(^{143}Nd/^{144}Nd)$i and ${\varepsilon}Nd$ versus 1/Nd variation are also scattered in Gwangju granitoid. It shows that the source magma of Gwangju granitoid are derived from partial melting materials of heterogeneous upper crust. Very low ${\varepsilon}Nd$ values (-15.19~-19.49) and very high ${\varepsilon}Sr$ values (92.72~308.85) mean that the source magma of Gwangju granitoid is derived from sedimentary substance melting. According to $(^{87}Sr/^{86}Sr)$ 180Ma, and the plot of ${\varepsilon}Sr$ versus ${\varepsilon}Nd$, the Gwangju granitoid shows that the source magma is derived from upper crust materials. Nd model ages of Gwangju granitoid (1.82~2.42G.A.) are older than meta-sediments of Okcheon formation (1.15~1.60G.A.) and similar or close to Pre-Cambrian gneiss complex of Ryoungnam massif (2.17~2.47G.A.or 2.11~2.38G.A.).Therefore, the source magma of the Gwangju granitoid could be derived from the partial melting of Pre-Cambrian gneiss complex of Ryoungnam massif.

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