• Title/Summary/Keyword: Sr(II)

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Soft X-ray Nano-spectroscopy for Electronic Structures of Transition Metal Oxide Nano-structures

  • Oshima, Masaharu
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.317-327
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    • 2014
  • In order to develop nano-devices with much lower power consumption for beyond-CMOS applications, the fundamental understanding and precise control of the electronic properties of ultrathin transition metal oxide (TMO) films are strongly required. The metal-insulator transition (MIT) is not only an important issue in solid state physics, but also a useful phenomenon for device applications like switching or memory devices. For potential use in such application, the electronic structures of MIT, observed for TMO nano-structures, have been investigated using a synchrotron radiation angle-resolved photoelectron spectroscopy system combined with a laser molecular beam epitaxy chamber and a scanning photoelectron microscopy system with 70 nm spatial resolution. In this review article, electronic structures revealed by soft X-ray nano-spectroscopy are presented for i) polarity-dependent MIT and thickness-dependent MIT of TMO ultrathin films of $LaAlO_3/SrTiO_3$ and $SrVO_3/SrTiO_3$, respectively, and ii) electric field-induced MIT of TMO nano-structures showing resistance switching behaviors due to interfacial redox reactions and/or filamentary path formation. These electronic structures have been successfully correlated with the electrical properties of nano-structured films and nano-devices.

Study on the electrical properties in the ceramic of (Sr¡¤Ca)Ti${O}_{2}$ system ((Sr.Ca)Ti${O}_{3}$계 세라믹의 전기적 특성에 관한 연구)

  • 최운식;김용주;이준웅
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.44 no.12
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    • pp.1610-1616
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    • 1995
  • The (Sr$_{1-x}$ .Ca$_{x}$)TiO$_{3}$(0.05.leq.x.leq.0.2) ceramics were fabricated to form semiconducting ceramics by sintering at about 1350[.deg. C] in a reducing atmosphere (N$_{2}$ gas). After being fired in a reducing atmosphere, metal oxides, CuO, was painted on the both surface of the specimens to diffuse to the grain boundary. They were annealed at 1100[.deg. C] for 2 hours. The 2nd phase formed by thermal diffusing from the surface lead to a very high apparent dielectric constant. The results of the capacitance-valtage measurements indicated that the grain boundary was composed of the continuous insulating layers. The capacitance is almost unchanged below about 20[V], but decreased slowly over 20[V]. The conduction mechanism of the specimens observed in the temperature range of 25~125[.deg. C], and is divided into three regions having different mechanism as the current increased: the region I below 200[V/cm] shows the ohmic conduction. The region II between 200[V/cm] and 2000[V/cm] can be explained by the Poole-Frenkel emission theory, and the region III above 2000[V/cm] is dominated by the tunneling effect.ct.

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Behavior of Charged Particles do $(Sr_{0.85}{\cdot}Ca_{0.15})_mTiO_3$ Grain Boundary Layer Ceramics ($(Sr_{0.85}{\cdot}Ca_{0.15})_mTiO_3$ 입계층 세라믹의 하전입자 거동)

  • 김진사;정동효;김상남;박재세;최운식;이준용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.209-212
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    • 1995
  • In this paper, the $(Sr_{0.85}{\cdot}Ca_{0.15})TiO_3$ of paraelectric grain boundary layer (GBL) ceramics were fabricated. The characteristics of electrical conduction and the thermally stimulated current(TSC) were measured respectively. The region I below 200[V/cm] shows the ohmic conduction, the region II between 200[V/cm] and 1000[V/cm] can be explained by the Pool-Frenkel emission theory, and the region III above 2000[V/cm] is dominated by the tunneling effect. As a result, The origins of these peaks are that the ${\alpha}$ peak observed at $-20[^{\circ}C]$ looks like to be ascribed to the ionization excitation from donor level in the grain, and the ${\alpha}^{\prime}$ peak observed at $-20[^{\circ}C]$ appears to show up by detrap of the trapped carrier of border between the oxidation layer and the grain, and the ${\beta}$ peak observed at $80[^{\circ}C]$ seems to be resulted from hopping conduction of existing carrier in the trap site of the border between the oxidation and second phase.

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SHRIMP Zircon U-Pb Geochronology, Geochemistry and Sr-Nd Isotopic Study of the Cheongju granitoid rocks (청주 화강암의 SHRIMP 저어콘 U-Pb 연대, 지구화학 및 Sr-Nd 동위원소 연구)

  • Cheong, Won-Seok;Kim, Yoon-Sup;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
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    • v.20 no.4
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    • pp.191-206
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    • 2011
  • The emplacement ages, whole-rock geochemistry and Sr-Nd isotopic compositions of granitoid rocks from Cheongju area, South Korea, were investigated for delineating their petrogenetic link to the Jurassic Daebo granitoid rocks. Zircon crystals were collected from the diorite, biotite granite and acidic dyke samples in a single outcrop. Cross-cutting relationships show that the emplacement of diorite was postdated by the intrusion of biotite granite. Both rocks have been subsequently intruded by acidic dyke. The U-Pb isotopic compositions of zircon from the diorite, biotite granite, and acidic dyke were measured using a SHRIMP-II ion microprobe, yielding the crystallization ages of $174{\pm}2Ma$, $170{\pm}2Ma$, and $170{\pm}5Ma$, respectively, with 95% confidence limits ($t{\sigma}$). The emplacement ages are consistent with those determined from the above relative ages. The major and trace element patterns of the rocks are consistent with those of the Jurassic Daebo granitoid rocks, possibly suggesting a subduction-related I-type granite. The geochemical signature is, however, betrayed by the Sr and Nd isotopic compositions of these rocks. The isotopic signatures suggest that the rocks were produced either by the partial melting of lower-crust or by the mantle-derived magma contaminated by the basement rocks during its ascent and/or emplacement. In addition, the inherited ages of zircons of the rocks (ca. 2.1, 1.8, 0.8 and 0.4 Ga) suggest a possible assimilation with crustal rocks from the Gyeonggi massif and Ogcheon metamorphic belt.

The Formulation and Bioavailability of Oral Sustained Release Sulindac Delivery System (설린닥의 경구용 지속성 제제설계 및 생체이용율)

  • Rhee, Gye-Ju;Park, Sun-Hee;Whang, Sung-Joo
    • YAKHAK HOEJI
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    • v.41 no.1
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    • pp.60-73
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    • 1997
  • In order to design a 24 hr sustained release preparation of sulindac for oral administration, fast release pellet (FR), slow release pellet (SR) and two combined formulation (1 : 1 and 1 : 2) were prepared. The pharmacokinetic effect of such preparations has been evaluated using rabbits as a suitable in vivo model, and tested in man. Dose determination was carried out using curve fitting according to RSTPJP II program. In bioavailability test using rabbit, AUCs of sulindac in a few designed formulations were similar to each other. $C_{max}$- of RF and SR were 1.8 times and 1.2 times higher, respectively, compared to that of combined formulation (FR:SR=1:1). While plasma concentration of FR and SR decreased rapidly, that of combined formulation (FR:SR 1:1) lasted at the level close to $C_{max}$ for 24 hrs. Plasma concentration of sulfide form from the combined pellet(FR:SR=1:1) lasted for 24 hrs, and its AUC value was 1.4-fold, 2.7-fold. and 1.2-fold greater than FR pellet, SR pellet and combined pellet (FR:SR 1 : 2). Thus, the combined pellet of 1:1 ratio was found to be the most effective for oral sustained release formulation. Bioavailability test in human showed that AUC of sulfide from TSRP (1 : 1) was approximately 1.5 times greater than total AUC of Immbaron$^{\circledR}$ administered twice in a day. While $T_{max}$ of sulfide from lmmbaron$^{\circledR}$ was 4.33 +/- 1.37 hr (lst administration) and 3.33 ${pm}$ 0.82 hr (2nd administration), respectively, that of sulfide from TSRP increased to 7.17 ${pm}$ 2.86 hr. Plasma concentration of sulfide from TSRP was sustained at more, than 1.0 ${\mu}g{\cdot}$hr/ml until 24 hrs after one dose administration. In addition, TSRP may decrease local adverse reaction in the stomach, since plasma concentration of sulfide from the combined pellet was low within 2hrs in the stomach. In conclusion, it is suggested that TSRP formulation may be effective for oral 24 hr sustained release formulation of sulindac dosing 300 ~ 350mg once a day.

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The Effect of Sr Addition and Holding Time on Mechanical Property and Electrical Conductivity of Al-10.5%Si-2%Cu Secondary Die-casting Alloys (Al-10.5wt%Si-2wt%Cu 다이 캐스팅용 2차 지금의 기계적 특성과 전기전도도에 미치는 Sr 양과 유지시간의 영향 II)

  • Shin, Sang-Soo;Kim, Myung-Yong;Yeom, Gil-Yong
    • Journal of Korea Foundry Society
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    • v.30 no.6
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    • pp.205-209
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    • 2010
  • This study evaluates the influence of strontium addition and holding time on mechanical properties for Al-10.5wt%Si-2wt%Cu secondary die-casting alloy and the measured electrical conductivity of modified alloys. A general improvement in the mechanical properties of the alloy was observed after adding the strontium. Ultimate tensile strength, elongation and electrical conductivity of modified alloys were improved by increasing strontium content and holding time. From these results, the optimal strontium content and holding time were identified on the mechanical properties of Al-10.5wt%Si-2wt%Cu secondary die-casting alloys.

Flux Loss and Neutron Diffraction Measurement Ag-sheathed Bi-2223 Tapes in terms of Flux Creep

  • Jang Mi-Hye
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.5
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    • pp.204-210
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    • 2005
  • Alternating current (AC) losses of two Bi-2223 ([Bi, Pb]: Sr: Ca: Cu: O = 2:2:2:3) tapes [(Tape I, un-twist-pitch) and the other with a twist-pitch of 10 mm (Tape II)] were measured and compared. These samples, produced by the powder-in-(Ag) tube (PIT) method, are multi-filamentary. Also, it's produced by non-twist and different twist pitch (8, 10, 13, 30, 50 and 70 mm). The critical current measurement was carried out under the environment in liquid Nitrogen and in zero-field by 4-probe method. Susceptibility measurements were conducted while cooling in a magnetic field. Flux loss measurements were conducted as a function of ramping rate, frequency and field direction. The AC flux loss increases as the twist-pitch of the tapes decreased, in agreement with the Norris Equation. Neutron-diffraction measurements have been carried out investigate the crystal structure, magnetic structures, and magnetic phase transitions in Bi-2223([Bi, Pb]:Sr:Ca:Cu:O)

An Assessment of the Role of Rare Earth in the Eutetic Modification of Cast Aluminum-Silicon Alloys (알루미늄-실리콘 합금주물의 공정조직 개량처리에 미치는 희토류 금속의 역할에 관한 평가)

  • Ye, B.J.
    • Journal of Korea Foundry Society
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    • v.6 no.2
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    • pp.104-115
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    • 1986
  • I A쪽과 II A쪽이 Al-Si 합금의 공정조직개량 처리에 효과적인 것은 잘 알려진 사실이나 Na(Sodium)과 Sr(Strontium)만 상업적으로 쓰여지고 있다. 그러나 휘발성과 산화하기 쉬운점때문에 Na 은 그 양을 정확하게 조절하기가 어렵고 특히 온도가 높은 경우 더욱 곤란하나 Sr 은 휘발성이나 산화성은 없으나 micro-또한 macro-porocity의 주 원인으로 보고 되고 있다. 희토류 금속 (예 : Cerium, Lanthanum,etc )도 개량처리 효과가 있다는 논문들(ref. 2, 3, 4, 5) 이 있고, 계속 연구되어 오고 있으나 그 세부사항과 효율성에 관해 정립된 바가 없다. 이런 연유로 Al-Si 합금의 생산을 위한 개량 처리제로서의 희토류 금속의 역할에 대해 구체적이고 세부적인 개량처리기구의 구명을 위해 이 연구가 이루어졌다. Al-Si 합금 356가 채택된 이유는 상업적 Al 주물의 생산을 감안해서 였다.

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Effect of Floor Space Allowance on Pig Productivity across Stages of Growth: A Field-scale Analysis

  • Lee, Joon H.;Choi, Hong L.;Heo, Yong J.;Chung, Yoon P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.5
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    • pp.739-746
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    • 2016
  • A total of 152 pig farms were randomly selected from the five provinces in South Korea. During the experiment, the average temperature and relative humidity was $24.7^{\circ}C$ and 74% in summer and $2.4^{\circ}C$ and 53% in winter, respectively. The correlation between floor space allowance (FSA) and productivity index was analyzed, including non-productive sow days (NPD), number of weaners (NOW), survival rate (SR), appearance rate of A-grade pork (ARA), and days at a slaughter weight of 110 kg (d-SW) at different growth stages. The objectives of the present study were i) to determine the effect of FSA on the pig productivity index and ii) to suggest the minimum FSA for pigs based on scientific baseline data. For the pregnant sow, NPD could be decreased if pregnant sows were raised with a medium level (M) of FSA (3.10 to $3.67m^2/head$) while also keeping the pig house clean which improves hygiene, and operating the ventilation system properly. For the farrowing sows, the NOW tended to decrease as the FSA increased. Similarly, a high level of FSA (H) is significantly negative with weaner SR of farrowing sows (p-value = 0.017), indicating this FSA tends to depress SR. Therefore, a FSA of 2.30 to $6.40m^2/head$ (very low) could be appropriate for weaners because a limited space can provide a sense of security and protection from external interruptions. The opposite trend was observed that an increase in floor space (> $1.12m^2/head$ leads to increase the SR of growing pigs. For the fattening pigs, H level of FSA was negatively correlated with SR, but M level of FSA was positively correlated with SR, indicating that SR tended to increase with the FSA of 1.10 to $1.27m^2/head$. In contrast, ARA of male fattening pigs showed opposite results. H level of FSA (1.27 to $1.47m^2/head$) was suggested to increase productivity because ARA was most affected by H level of space allowance with positive correlation ($R^2=0.523$). The relationship between the FSA and d-SW of fattening pigs was hard to identify because of the low $R^2$ value. However, the farms that provided a relatively large floor space (1.27 to $1.54m^2/head$) during the winter period showed d-SW was significantly and negatively affected by FSA.

Integration of Ayurvedic formulations with iron folic acid in the treatment of nutritional anaemia among school going adolescents of Dehradun District

  • Prakash, Vaidya Balendu;Prakash, Shyam;Sharma, Rajesh;Prakash, Megha;Prakash, Shikha;Parmar, Kiran
    • CELLMED
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    • v.6 no.1
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    • pp.5.1-5.5
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    • 2016
  • Combating anaemia is a global public health challenge of the developing world. Nutritional anaemia is a serious health problem faced by Indian school children. An investigation was taken up to study the effect of non iron containing Ayurvedic preparation Sootshekhar Rasa (SR) plus Sitopaladi Churna (SC) along with iron and folic acid (IFA) for improving nutritional anaemia among adolescent school going students of Dehradun district in Northern India. The blinded, controlled randomized trial comprised of 820 adolescents anaemic students aged 11 - 18 years. The anaemic students were randomly divided into 4 groups, students of group I (control) received starch, group II, III, and IV students received daily dose of (SR 250 mg + SC 400 mg), IFA and (SR 250 mg + SC 400 mg) + IFA, respectively. All the students received treatment for 90days and were followed up for next 180days. At the end of follow-up (day 270), significant increase of haemoglobin (Hb) level from the base line was recorded in all treatment groups. The maximum gain in Hb concentration was noted in group IV (10.1 ± 0.6 g/L), which was significantly higher than any other group. There were 123 drop-outs; however, no major side effect of treatment was noted in any student. We conclude that daily dose of (SR 250 mg + SC 400 mg) along with IFA can produce sustainable improvement of nutritional anaemia in adolescent students.