• Title/Summary/Keyword: Spray Coating

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Improved Characteristics of Carbon Nanotube Transparent Electrode Films Using Acid Treatments (산 처리를 이용한 탄소 나노튜브 투명전극 특성 향상)

  • Jeon, Joo-Hee;Choi, Ji-Hyuk;Moon, Kyeong-Ju;Lee, Tae-Il;Moon, Ho-Jun;Kim, Hyung-Yeol;Myoung, Jae-Min
    • Korean Journal of Materials Research
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    • v.20 no.2
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    • pp.51-54
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    • 2010
  • Transparent conductive films of single wall carbon nanotube (SWCNT) were prepared by spray coating method. The effect of acid treatment on the SWCNT films was investigated. The field emission scanning electron microscope (FESEM) shows that acid treatment can remove dispersing agent. The electrical and optical properties of acid-treated films were enhanced compared with those of as deposited SWCNT films. Nitric acid ($HNO_3$), sulfuric acid ($H_2SO_4$), nitric acid:sulfuric acid (3:1) were used for post treatment. Although all solutions reduced sheet resistance of CNT films, nitric acid can improve electrical characteristics efficiently. During acid treatment, transmittance was increased continuously with time. But the sheet resistance was decreased for the first 20 minutes and then increased again. Post-treated SWCNT films were transparent (85%) in the visible range with sheet resistance of about $162{\Omega}/sq$. In this paper we discuss simple fabrication, which is suitable for different types of large-scale substrates and simple processes to improve properties of SWCNT films.

An Experimental Study on the Fireproof Covering Thickness of High Strength Concrete Members with Spray Coating (뿜칠피복재를 사용한 고강도 콘크리트 부재의 내화피복두께에 관한 실험적 연구)

  • Lee, Tae-Gyu
    • Fire Science and Engineering
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    • v.24 no.4
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    • pp.41-46
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    • 2010
  • High strength concrete (HSC) has been mainly used in large SOC structures. HSC have superior property as well as improvement in durability compared with normal strength concrete. In spite of durability of HSC, explosive spalling in concrete front surface near the source of fire occurs serious problem in structural safety. Therefore, this study is concerned with experimentally investigation of fire resistance at high temperature due to fireproof material covering thickness in addition to concrete cover. From the test result, it was appeared that the use of fireproof material results in good performance for fire resistance and spalling prevention, and the optimal fireproof covering thickness is 1~3mm. On the other hand, the temperature was rapidly increased by explosive spalling within 30 minutes and showed very little rise caused by evaporation heat after then. It was also found that the void channel was remained at high temperature as PP fiber melts at about $200^{\circ}C$, and the pore pressure in concrete was decreased.

Long-term Evaluation of IMZ Implants;Success and Survival Rates (IMZ 임플란트의 장기적 성공률과 실패율)

  • Park, Ji-Eun;Kim, Tae-Gyun;Jung, Ui-Won;Kim, Chang-Sung;Choi, Seong-Ho;Cho, Kyoo-Sung;Kim, Chong-Kwan;Chai, Jung-Kiu
    • Journal of Periodontal and Implant Science
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    • v.35 no.4
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    • pp.1039-1052
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    • 2005
  • IMZ는 "intramobile cylinder implant system" (IMZ)로 독일에서 가장 오래되고 많이 사용되어진 임플란트 중 하나이다. 이 임플란트에 관한 장기적 성공률과 생존률에 대한 연구는 대개 80% 이상을 보고하고 있다. 그러나, 연세대학교 치과병원 치주과에서 식립된 83개의 임플란트에서는 이전의 연구와는 다른 결과를 나타내었다. 1. IMZ 임플란트의 생존률은 67.5% 였다. 2. 변연 치조골 소실에 대한 성공 기준을 적용한 결과 성공률은 49.4%로 나타났다. 3. 발거된 총 27개의 임플란트 중에서 임플란트 주위 골소실을 가지는 경우는 17개, 내부구조 파절은 4개, 식립체 파절은 5개로 보고되었다. 4. 10년 이상 생존된 임플란트에서 변연골 소실의 평균치는 2.82mm였다. IMZ 임플란트는 장기적으로 높은 실패율을 보고하였다. 이는 cylindrical design, titanium plasma flame spray coating, prosthodontic complication 등의 요소에 기인한 것으로 사료된다. 임플란트는 그 형태, 표면 처리 등 여러 가지 요인들에 의해 실패가 나타날 수 있으며 본 연구를 통해 임플란트의 개발 및 선택에 바탕이 될 수 있을 것으로 생각된다.

Numerical Analysis of Deformation Characteristics in the Double-Layer Liner According to Explosive Material Distribution (이중층 라이너에서 폭발 재료 분포에 따른 변형 특성 수치해석)

  • Mun, Sang Ho;Kim, See Jo;Lee, Chang Hee;Lee, Seong
    • Journal of the Korea Institute of Military Science and Technology
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    • v.19 no.5
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    • pp.618-628
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    • 2016
  • The development of new concepts of liners is required in order to effectively neutralize the enemy's attack power concealed in the armored vehicles. A multiple-layer liner is one of possibilities and has a mechanism for explosion after penetrating the target which is known as "Behind Armor Effect." The multiple-layer explosive liner should have sufficient kinetic energy to penetrate the protective structure and explosive material react after target penetration. With this in mind, double-layer liner materials were obtained by cold spray coating methods and these material properties were experimentally characterized and used in this simulation for double-layer liners. In this study, numerical simulations in the three different layer types, i.e., single, A/B, A/B/A in terms of the layer location were verified in terms of finite element mesh sizes and numerical results for the jet tip velocity, kinetic energy, and the corresponding jet deformation characteristics were analysed in detail depending on the structure of layer types.

Development of Drug Eluting Stent for the Treatment of Benign Biliary Stricture by Electro-spray Method (전기분사를 이용한 양성담관 협착 치료용 약물방출 스텐트 개발)

  • Shin, Il-Gyun;Kim, Dong-Gon;Kim, Han-Ki;Kim, Sang-Ho;Jeon, Dong-Min;Suh, Tae-Seok;Jang, Hong-Seok
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.163-168
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    • 2012
  • Recently, along with technology development of endoscopic equipment, the stent technology has been developed for the convenience of operation, shortening of recovery times, and reduction of patient's pain. In this study, paclitaxel-eluting metal stents for treatment of biliary benign stenosis were developed through an electrospray-coating method. Polyether-based polyurethane (PELLETHANE 2363-80AE$^{(R)}$)) and paclitaxel were coated onto the surface of a metallic stent and Pluronic F127 was used as an additive. As a result, physicochemical characterization of paclitaxel via SEM, FTIR, contact angle and XRD techniques revealed the information of solid state of paclitaxel-loaded PU film. The in vitro release profile showed a slower release rate with a higher content of paclitaxel.

AE Application for Fracture Behavior of SiC Reinforced CFRP Composites (SiC 강화 CFRP 복합재의 파괴거동에 관한 음향방출 적용)

  • Ryu, Yeong Rok;Yun, Yu Seong;Kwon, Oh Heon
    • Journal of the Korean Society of Safety
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    • v.31 no.3
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    • pp.16-21
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    • 2016
  • Carbon Fiber Reinforced Plastic(CFRP) composite with a higher specific strength and rigidity is more excellent than conventional metallic materials or other organic polymer of FRP. It has been widely used in vehicles, aerospaces and high technology industries which are associated with nuclear power fields. However, CFRP laminated composite has several disadvantages as like a delamination, matrix brittleness and anisotropic fibers that are the weak points of the crack initiation. In this present work, the reinforced silicon carbide(SiC) particles were added to the interlayer of CFRP laminates in order to mitigate the physical vulnerability affecting the cracking and breaking of the matrix in the CFRP laminated composite because of excellent specific strength and thermal shock resistance characteristics of SiC. The 1wt% of SiC particles were spread into the CFRP prepreg by using a spray coating method. After that, CFRP prepregs were laminated for the specimen. Also, the twill woven type CFRP prepreg was used because it has excellent workability. Thus the mechanical and fracture behaviors of the twill woven CFRP laminated composite reinforced with SiC particles were investigated with the acoustic emission(AE) method under a fracture test. The results show that the SiC particles enhance the mechanical and fracture characteristics of the twill CFRP laminate composite.

Design of Reduced Shear Stress with High-Viscosity Flow Using Characteristics of Thin Film Flow on Solid Surfaces (완전접촉 경계면 위의 박막유동 특성을 이용한 고점도 전단유동에 따른 표면응력 감소 설계)

  • Park, Boo Seong;Kim, Bo Hung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.12
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    • pp.1027-1034
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    • 2014
  • The shear stress on a surface due to the thin film fluid flow is an important issue. In case of a rotating disk, the fluid is delivered to the edge of the disk by centrifugal force, which acts as a body force on the fluid. Wear of a surface is affected by the shear stress acting on the surface and curvature. In this study, we utilize computational fluid dynamics software to model the ratio of curvature and local shear stress on solid surfaces. The key goal of the study is to determine an optimized curvature for the thin film fluid flow on a solid surface in order to minimize the local shear stress affecting the wear of this surface. Our results on the effects of curvature will be utilized for the design of devices that utilize thin film fluid flow on a solid surface, such as rotating-disk spray systems and thin film coating.

Photocurrent Characteristics of Plasma Sprayed TiO2 Composite Coatings according to Additive Transition Metal (전이금속을 첨가한 플라즈마 TiO2 복합 용사피막의 광전류 특성)

  • Ko, Byung-Chun;Ko, Young-Bong;Park, Kyeung-Chaea
    • Journal of Surface Science and Engineering
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    • v.44 no.3
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    • pp.89-94
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    • 2011
  • In this study, the photocurrent characteristics of plasma sprayed $TiO_2$ coatings have been investigated according to additive transition metal (Fe, Mn, Nb powder) and heat treatment conditions. The plasma sprayed $TiO_2$ coatings by heat treatment at $400^{\circ}C$ and 90 min had the higher photocurrent at ultraviolet light, no photocurrent at visible light. The photocurrent of plasma sprayed $TiO_2$ coatings added by Fe, Mn, Nb (named by plasma sprayed $TiO_2$ composite coatings) was lower than that of plasma sprayed $TiO_2$ coatings at ultraviolet light, as was low in intensity ratio of XRD(101)/(110). and the atomic percentage of oxygen by plasma sprayed $TiO_2$ composite coatings was higher than that by plasma sprayed $TiO_2$ coatings. The photocurrent of plasma sprayed $TiO_2$ composite coatings in heat treatment at $400^{\circ}C$ and 90 min was higher than that of plasma sprayed $TiO_2$ coatings in same heat treatment conditions at ultraviolet and visible light, as was high in oxygen affinity by heat treatment.

Characteristics of Al Films Prepared by Oblique Angle Deposition (빗각 증착으로 제조한 Al 박막의 특성)

  • Park, Hye-Sun;Yang, Ji-Hoon;Jung, Jae-Hun;Song, Min-A;Jeong, Jae-In
    • Journal of Surface Science and Engineering
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    • v.45 no.3
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    • pp.111-116
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    • 2012
  • Oblique angle deposition (OAD) is a physical vapor deposition method which utilizes non-normal angles between the substrate and the vaporizing source. It has been known that tilting the substrate changes the properties of the film deposited on it, which was thought to be a result of morphological change of the film. In this study, OAD has been applied to prepare single and multilayer Al films by magnetron sputtering. The magnetron sputtering source of 4 inch diameter was used to deposit the films. Al films have been deposited on Si wafers and cold-rolled steel sheets. The multilayer films were prepared by changing the tilting angle upside down at each layer interval, which means that when the first layer was deposited at an angle of $+45^{\circ}$, the second layer was deposited at an angle of $-45^{\circ}$, and vice versa. The microstructure, surface roughness and reflectance of the films were investigated using a scanning electron microscope, a surface profiler and a spectrophotometer, respectively. The corrosion resistance was measured and compared using the salt spray test. The single layer film prepared at an oblique angle of $60^{\circ}$ prepared at other angles. However, for the multilayer films, the film prepared at an oblique angle of $45^{\circ}$ showed the most compact and featureless structure. The multilayer films were found to exhibit higher corrosion resistance than the single layer films.

The method for total organic carbon analysis employing TiO2 photocatalyst (이산화티타늄 광촉매를 이용한 총유기탄소 분석방법)

  • Park, Buem Keun;Kim, Sung Mi;Lee, Young-Jin;Paik, Jong-Hoo;Shin, Jeong Hee
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.320-325
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    • 2021
  • Biochemical oxygen demand (BOD) and chemical oxygen demand (COD) methods are conventional analytical methods to analyze water quality. Both of these methods are technically indirect measurement methods, require complicated preconditions, and are time-consuming. On the other hand, the total organic carbon (TOC) method is a direct and fast measurement method which is more intuitive and accurate than the BOD and COD methods. However, general TOC analysis methods involve complicated processes and high power consumption owing to the process of phase transition from liquid to gas by a high-temperature heater. Furthermore, periodic consumables are also required for the removal of inorganic carbon (IC). Titanium dioxide (TiO2) is one of the most suitable photocatalysts for simple processes. Its usage involves low power consumption because it only reacts with the organic carbon (OC) without the requirement of any other reagents and extra processes. We investigated a TiO2 photocatalyst-based TOC analysis for simple and affordable products. TiO2-coated fiber substrate maintained under carbon included water was exposed to ultraviolet (UV) radiation of wavelength 365 nm. This method is suitable for the real-time monitoring of water pollution because of its fast reaction time. Its linear property is also sufficient to match the real value.